Patent classifications
C07C29/1512
Plasma assisted distributed chemical production
The present development is a process to produce commodity chemicals such as methanol and syngas using an integrated plasma catalysis technology. The method comprises providing a fixed or fluidized bed reactor having a microwave plasma flame and a catalyst bed with a catalyst, wherein the catalyst is an alloyed bimetallic nanowire. In the process, the plasma flame fluidizes the catalyst thereby producing a more effective catalyst than the non-fluidized catalyst. It is anticipated that the reactor can have a throughput capacity of up to 30 Lpm/kW and can be effective for the conversion of CO.sub.2, CH.sub.4, air, water, and combinations thereof, through reactions such as pure CO.sub.2 splitting, reverse water gas shift (RWGS) for CO production, methanol synthesis, and plasma reforming of methane, thereby making a system that would be attractive for small GTL units.
Plasma assisted distributed chemical production
The present development is a process to produce commodity chemicals such as methanol and syngas using an integrated plasma catalysis technology. The method comprises providing a fixed or fluidized bed reactor having a microwave plasma flame and a catalyst bed with a catalyst, wherein the catalyst is an alloyed bimetallic nanowire. In the process, the plasma flame fluidizes the catalyst thereby producing a more effective catalyst than the non-fluidized catalyst. It is anticipated that the reactor can have a throughput capacity of up to 30 Lpm/kW and can be effective for the conversion of CO.sub.2, CH.sub.4, air, water, and combinations thereof, through reactions such as pure CO.sub.2 splitting, reverse water gas shift (RWGS) for CO production, methanol synthesis, and plasma reforming of methane, thereby making a system that would be attractive for small GTL units.
Integrated capture and conversion of CO.SUB.2 .to methane, methanol, or methanol and glycol
A process for producing methane or methanol includes combining a hydrogenation catalyst, hydrogen, and CO.sub.2 with a condensed phase solution comprising an amine under conditions effective to form methane or methanol, and water. A process for coproduction of methanol and a glycol includes combining an epoxide, a hydrogenation catalyst, hydrogen, and CO.sub.2 with a condensed phase solution comprising an amine under conditions effective to form methanol and a glycol.
METHANOL SYNTHESIS
A method for synthesizing methanol from a raw material using a set of process parameters, wherein a mathematical model is provided that is configured for calculating, based on the process parameters and on at least one material property of the raw material, an expected amount of at least one by-product of the synthesizing of the methanol, wherein the following steps are performed at least once in the stated order, applying the mathematical model to current values for the process parameters, and changing a respective set point for at least one of the process parameters such that based on the mathematical model a lower amount of the by-products is expected under condition that at least a predetermined amount of the methanol can be synthesized,
METHOD FOR THE CONTROL OF PRESSURE IN A LOOP FOR THE PREPARATION OF AMMONIA OR METHANOL
A method for the control of pressure in a loop for the preparation of ammonia or methanol by using an anti-surge control valve of a compressor and/or a compressor flow regulation valve for the recirculation of loop recirculation gas at variating flow supply of fresh synthesis gas.
METHOD FOR THE CONTROL OF PRESSURE IN A LOOP FOR THE PREPARATION OF AMMONIA OR METHANOL
A method for the control of pressure in a loop for the preparation of ammonia or methanol by using an anti-surge control valve of a compressor and/or a compressor flow regulation valve for the recirculation of loop recirculation gas at variating flow supply of fresh synthesis gas.
Process of removing heat
The present invention provides an improved process for removing heat from an exothermic reaction. In particular, the present invention provides a process wherein heat can be removed from multiple reaction trains using a common coolant system.
Process and reactor for exothermal reaction
The present disclosure relates to a reactor and a method of operation for an exothermal process being catalyzed by a catalytically active material receiving a reactant gas and providing a product gas, in which said exothermal process has a heat development having a potential for thermally degrading said catalytically active material, and which exothermal process operates at a temperature at which the reactants and at least 80% or all of the products are present as gases, said method comprising the steps of a) directing the reactant gas to a first zone of a material catalytically active in the exothermal process producing an first product gas, and b) directing the first product gas to a second zone of a material catalytically active in the exothermal process producing a product gas, with the option of fully or partially by-passing either said first zone or said second zone, while directing a non-condensing gas stream having a temperature at least 50° C. lower than the product gas to said by-passed zone, wherein the choice of by-passing said zone is made based on the time of operation or a process parameter reflecting the catalytic activity of the zone of catalytically active material which is not by-passed with the associated benefit of reducing the extent of thermal deactivation of the catalytically active material, and thus increasing the overall lifetime of the catalytically active material.
Process of removing heat
The present invention provides an improved process for removing heat from an exothermic reaction. In particular, the present invention provides a process wherein heat can be removed from multiple reaction trains using a common coolant system.
METHOD AND SYSTEM FOR THE PRODUCTION OF METHANOL
A process for preparing methanol by a methanol synthesis reaction of carbon dioxide with hydrogen may involve a distillation step and a condensation step following the synthesis of a crude methanol. A volatile component and water may be separated off from a methanol-containing product stream, and a gas stream containing a volatile component that has been separated off may be discharged at least partially as offgas. At least part of the gas stream that has been separated off may be recirculated into the methanol synthesis reaction. A plant for preparing methanol can store or utilize electric power generated from renewable energy sources and provide facilities for discharging the offgas stream, which can be purified by catalytic after-combustion. Alternatively, the plant can be configured without discharge of an offgas substream, or the offgas streams are so small that they can be released without treatment into the environment at a suitable position.