Process and reaction system for the preparation of methanol. The process comprises the steps of (a) providing a fresh methanol synthesis gas containing hydrogen, carbon monoxide and carbon dioxide; (b)) introducing and reacting the fresh methanol synthesis gas stream in a first methanol reaction unit in presence of a methanol catalyst and obtaining a first effluent stream containing methanol and unconverted synthesis gas; (c) providing a recycle gas stream containing the unconverted methanol synthesis gas contained in the first effluent stream and unconverted methanol synthesis gas from a second methanol reaction unit; (d) introducing and reacting the recycle gas stream in the second methanol reaction unit in presence of a methanol catalyst; (e) withdrawing a second effluent stream containing methanol and the unconverted methanol synthesis gas from the second methanol reaction unit; (f)) combining the first and a part of the second effluent stream; (g) cooling and separating the combined effluent into a methanol-containing liquid stream and the recycle stream; and (h) withdrawing the remaining part of the second effluent stream a purge gas stream,wherein the remaining part of he second effluent stream is withdrawn as a purge gas stream prior to combining the first and second effluent stream.

Process and reaction system for the preparation of methanol. The process comprises the steps of (a) providing a fresh methanol synthesis gas containing hydrogen, carbon monoxide and carbon dioxide; (b)) introducing and reacting the fresh methanol synthesis gas stream in a first methanol reaction unit in presence of a methanol catalyst and obtaining a first effluent stream containing methanol and unconverted synthesis gas; (c) providing a recycle gas stream containing the unconverted methanol synthesis gas contained in the first effluent stream and unconverted methanol synthesis gas from a second methanol reaction unit; (d) introducing and reacting the recycle gas stream in the second methanol reaction unit in presence of a methanol catalyst; (e) withdrawing a second effluent stream containing methanol and the unconverted methanol synthesis gas from the second methanol reaction unit; (f)) combining the first and a part of the second effluent stream; (g) cooling and separating the combined effluent into a methanol-containing liquid stream and the recycle stream; and (h) withdrawing the remaining part of the second effluent stream a purge gas stream,wherein the remaining part of he second effluent stream is withdrawn as a purge gas stream prior to combining the first and second effluent stream.

Process and reaction system for the preparation of methanol. The process comprises the steps of (a) providing a fresh methanol synthesis gas containing hydrogen, carbon monoxide and carbon dioxide; (b)) introducing and reacting the fresh methanol synthesis gas stream in a first methanol reaction unit in presence of a methanol catalyst and obtaining a first effluent stream containing methanol and unconverted synthesis gas; (c) providing a recycle gas stream containing the unconverted methanol synthesis gas contained in the first effluent stream and unconverted methanol synthesis gas from a second methanol reaction unit; (d) introducing and reacting the recycle gas stream in the second methanol reaction unit in presence of a methanol catalyst; (e) withdrawing a second effluent stream containing methanol and the unconverted methanol synthesis gas from the second methanol reaction unit; (f)) combining the first and a part of the second effluent stream; (g) cooling and separating the combined effluent into a methanol-containing liquid stream and the recycle stream; and (h) withdrawing the remaining part of the second effluent stream a purge gas stream,wherein the remaining part of he second effluent stream is withdrawn as a purge gas stream prior to combining the first and second effluent stream.

The present invention provides a process for purifying a monoterpene or sesquiterpene having a purity greater than about 98.5% (w/w). The process comprises the steps of derivatizing the monoterpene (or sesquiterpene) to produce a monoterpene (or sesquiterpene) derivative, separating the monoterpene (or sesquiterpene) derivative, and releasing the monoterpene (or sesquiterpene) from the derivative. Also encompassed by the scope of the present invention is a pharmaceutical composition comprising a monoterpene (or sesquiterpene) having a purity greater than about 98.5% (w/w). The purified monoterpene can be used to treat a disease such as cancer. The present monoterpene (or sesquiterpene) may be administered alone, or may be co-administered with radiation or other therapeutic agents, such as chemotherapeutic agents.

The present invention provides a process for purifying a monoterpene or sesquiterpene having a purity greater than about 98.5% (w/w). The process comprises the steps of derivatizing the monoterpene (or sesquiterpene) to produce a monoterpene (or sesquiterpene) derivative, separating the monoterpene (or sesquiterpene) derivative, and releasing the monoterpene (or sesquiterpene) from the derivative. Also encompassed by the scope of the present invention is a pharmaceutical composition comprising a monoterpene (or sesquiterpene) having a purity greater than about 98.5% (w/w). The purified monoterpene can be used to treat a disease such as cancer. The present monoterpene (or sesquiterpene) may be administered alone, or may be co-administered with radiation or other therapeutic agents, such as chemotherapeutic agents.

The present invention provides to a process for recovery of an organic compound (i.e. Ethanol, propanol, butanol, Acetone, iso-propyl alcohol) from a fermented broth which is produced from different fermentation technologies. The present invention particularly relates to an integrated process for ethanol separation from the fermentation broth using integrated vapor compressing unit (turbofans), evaporator (falling film) and a broth stripper column (vacuum distillation system). The process is operated under low temperature for the separation and recovery of the organic compound (particularly ethanol) from the fermented broth containing live microbes typically below or at 50° C. to ensure the activity of the microbes in the broth recycle. Again, the activity of the microbes is further ensured by maintaining the residence time of the microbe containing broth outside the Fermentor is less than or equal to 10 minutes.

The present invention provides to a process for recovery of an organic compound (i.e. Ethanol, propanol, butanol, Acetone, iso-propyl alcohol) from a fermented broth which is produced from different fermentation technologies. The present invention particularly relates to an integrated process for ethanol separation from the fermentation broth using integrated vapor compressing unit (turbofans), evaporator (falling film) and a broth stripper column (vacuum distillation system). The process is operated under low temperature for the separation and recovery of the organic compound (particularly ethanol) from the fermented broth containing live microbes typically below or at 50° C. to ensure the activity of the microbes in the broth recycle. Again, the activity of the microbes is further ensured by maintaining the residence time of the microbe containing broth outside the Fermentor is less than or equal to 10 minutes.

The present invention provides to a process for recovery of an organic compound (i.e. Ethanol, propanol, butanol, Acetone, iso-propyl alcohol) from a fermented broth which is produced from different fermentation technologies. The present invention particularly relates to an integrated process for ethanol separation from the fermentation broth using integrated vapor compressing unit (turbofans), evaporator (falling film) and a broth stripper column (vacuum distillation system). The process is operated under low temperature for the separation and recovery of the organic compound (particularly ethanol) from the fermented broth containing live microbes typically below or at 50° C. to ensure the activity of the microbes in the broth recycle. Again, the activity of the microbes is further ensured by maintaining the residence time of the microbe containing broth outside the Fermentor is less than or equal to 10 minutes.

Syngas is produced by a steam reforming unit with at least one of a bayonet reactor for reforming steam and a hydrocarbon, a recuperative burner, and a regenerative burner such that the steam reforming unit produces little or no steam in excess of the steam reforming process requirements. The syngas is then converted to methanol in a methanol synthesis unit. Compressors for the synthesis unit are driven by higher efficiency drivers than are possible using the low temperature steam conventionally exported from a steam reforming unit.

Syngas is produced by a steam reforming unit with at least one of a bayonet reactor for reforming steam and a hydrocarbon, a recuperative burner, and a regenerative burner such that the steam reforming unit produces little or no steam in excess of the steam reforming process requirements. The syngas is then converted to methanol in a methanol synthesis unit. Compressors for the synthesis unit are driven by higher efficiency drivers than are possible using the low temperature steam conventionally exported from a steam reforming unit.