Disclosed is a method for treating the product stream from a polyester methanolysis depolymerization process wherein the product stream includes dimethyl terephthalate and one or more side species selected from the group consisting of dimethyl phthalate, dimethyl isophthalate, bisphenol-A, an adipic acid diester and colorants. The method includes a) hydrogenating said dimethyl terephthalate to form one or more of dimethyl 1,4-cyclohexanedicarboxylate and 1,4-cyclohexanedimethanol; and (b) hydrogenating one or more of said one or more side species of said product stream. A method for depolymerization of polyester is also described.

Disclosed is a method for treating the product stream from a polyester methanolysis depolymerization process wherein the product stream includes dimethyl terephthalate and one or more side species selected from the group consisting of dimethyl phthalate, dimethyl isophthalate, bisphenol-A, an adipic acid diester and colorants. The method includes a) hydrogenating said dimethyl terephthalate to form one or more of dimethyl 1,4-cyclohexanedicarboxylate and 1,4-cyclohexanedimethanol; and (b) hydrogenating one or more of said one or more side species of said product stream. A method for depolymerization of polyester is also described.

The invention provides a process for the separation of a diol from a product stream. The process includes the steps of: i) separating the product stream comprising three or more C2 to C6 diols, C3 to C6 sugar alcohols, and C4 to C6 polyhydric alcohols with at least 3 hydroxyl groups in the molecule, and a catalyst, to produce a first stream comprising the three or more C2 to C6 diols; ii) separating the first stream comprising the three or more C2 to C6 diols into a) a second stream comprising a first diol and unsaturated hydrocarbons and/or one or more compounds with a carbonyl group and b) a third stream comprising two or more diols; iii) hydrogenating the second stream comprising a first diol and unsaturated hydrocarbons and/or one or more compounds with a carbonyl group to provide a purified diol stream.

The invention provides a process for the separation of a diol from a product stream. The process includes the steps of: i) separating the product stream comprising three or more C2 to C6 diols, C3 to C6 sugar alcohols, and C4 to C6 polyhydric alcohols with at least 3 hydroxyl groups in the molecule, and a catalyst, to produce a first stream comprising the three or more C2 to C6 diols; ii) separating the first stream comprising the three or more C2 to C6 diols into a) a second stream comprising a first diol and unsaturated hydrocarbons and/or one or more compounds with a carbonyl group and b) a third stream comprising two or more diols; iii) hydrogenating the second stream comprising a first diol and unsaturated hydrocarbons and/or one or more compounds with a carbonyl group to provide a purified diol stream.

The invention relates to a process for the preparation of a deuterated ethanol from ethanol, D.sub.2O, a ruthenium catalyst, and a co-solvent.

The invention relates to a process for the preparation of a deuterated ethanol from ethanol, D.sub.2O, a ruthenium catalyst, and a co-solvent.

The invention relates to a process for the preparation of a deuterated ethanol from an acetic acid, an acetate, or an amide by reaction with D.sub.2 in the presence of a transition metal catalyst.

The present invention provides a method for increasing the UV transmittance of ethylene glycol. The method uses an ethylene glycol solution and hydrogen as raw materials, and uses an alloy catalyst comprising nickel, one or more rare-earth elements, tin, and aluminum, the contents thereof in parts by weight being 10-90, 1-5, 1-60, and 5-9, respectively. The method of the present invention uses an inexpensive, stable-in-aqueous-phase, carrier-free alloy as a catalyst, and continuously adds hydrogen to reduce unsaturated impurities in ethylene glycol. In application of the method of the present invention in continuous industrial-scale production, the use of this type of alloy catalyst could be especially significant for the achievement of long-term system stability and control of production costs.

The present invention provides a method for increasing the UV transmittance of ethylene glycol. The method uses an ethylene glycol solution and hydrogen as raw materials, and uses an alloy catalyst comprising nickel, one or more rare-earth elements, tin, and aluminum, the contents thereof in parts by weight being 10-90, 1-5, 1-60, and 5-9, respectively. The method of the present invention uses an inexpensive, stable-in-aqueous-phase, carrier-free alloy as a catalyst, and continuously adds hydrogen to reduce unsaturated impurities in ethylene glycol. In application of the method of the present invention in continuous industrial-scale production, the use of this type of alloy catalyst could be especially significant for the achievement of long-term system stability and control of production costs.

The present invention provides a method for increasing the UV transmittance of ethylene glycol. The method uses an ethylene glycol solution and hydrogen as raw materials, and uses an alloy catalyst comprising nickel, one or more rare-earth elements, tin, and aluminum, the contents thereof in parts by weight being 10-90, 1-5, 1-60, and 5-9, respectively. The method of the present invention uses an inexpensive, stable-in-aqueous-phase, carrier-free alloy as a catalyst, and continuously adds hydrogen to reduce unsaturated impurities in ethylene glycol. In application of the method of the present invention in continuous industrial-scale production, the use of this type of alloy catalyst could be especially significant for the achievement of long-term system stability and control of production costs.