Patent classifications
C07C303/24
PROCESS FOR SULFONATION OF 2-AMINOETHANOL HYDROGEN SULFATE ESTER TO PRODUCE TAURINE
A process comprises continuously adding a first stream and a second stream to a sulfonation vessel, wherein the first stream comprises aminoethanol sulfate ester (AES) and the second stream comprises an aqueous solution of sodium sulfite (Na.sub.2SO.sub.3). The process comprises continuously mixing the AES and the aqueous solution of Na.sub.2SO.sub.3 in the sulfonation vessel, thus producing a mixture. The process comprises continuously subjecting the mixture to heat in the presence of an inert gas, thus converting the AES to the taurine via sulfonation. In an aspect, the AES has a residence time of no more than four hours in the sulfonation vessel. In an aspect the heating step is conducted at a temperature of at least 115° C. and a pressure of at least 200 psi.
PROCESS FOR SULFONATION OF 2-AMINOETHANOL HYDROGEN SULFATE ESTER TO PRODUCE TAURINE
A process comprises continuously adding a first stream and a second stream to a sulfonation vessel, wherein the first stream comprises aminoethanol sulfate ester (AES) and the second stream comprises an aqueous solution of sodium sulfite (Na.sub.2SO.sub.3). The process comprises continuously mixing the AES and the aqueous solution of Na.sub.2SO.sub.3 in the sulfonation vessel, thus producing a mixture. The process comprises continuously subjecting the mixture to heat in the presence of an inert gas, thus converting the AES to the taurine via sulfonation. In an aspect, the AES has a residence time of no more than four hours in the sulfonation vessel. In an aspect the heating step is conducted at a temperature of at least 115° C. and a pressure of at least 200 psi.
PROCESS FOR SULFONATION OF 2-AMINOETHANOL HYDROGEN SULFATE ESTER TO PRODUCE TAURINE
A process comprises continuously adding a first stream and a second stream to a sulfonation vessel, wherein the first stream comprises aminoethanol sulfate ester (AES) and the second stream comprises an aqueous solution of sodium sulfite (Na.sub.2SO.sub.3). The process comprises continuously mixing the AES and the aqueous solution of Na.sub.2SO.sub.3 in the sulfonation vessel, thus producing a mixture. The process comprises continuously subjecting the mixture to heat in the presence of an inert gas, thus converting the AES to the taurine via sulfonation. In an aspect, the AES has a residence time of no more than four hours in the sulfonation vessel. In an aspect the heating step is conducted at a temperature of at least 115° C. and a pressure of at least 200 psi.
Cyclic process for the production of taurine from monoethanolamine
A method is disclosed for the production of taurine in high yield by a cyclic process of reacting monoethanolamine, sulfuric acid, and ammonium sulfite in the presence of additives to inhibit the hydrolysis of 2-aminoethyl hydrogen sulfate intermediate. The cyclic process is economical and little waste is generated.
Cyclic process for the production of taurine from monoethanolamine
A method is disclosed for the production of taurine in high yield by a cyclic process of reacting monoethanolamine, sulfuric acid, and ammonium sulfite in the presence of additives to inhibit the hydrolysis of 2-aminoethyl hydrogen sulfate intermediate. The cyclic process is economical and little waste is generated.
Cyclic process for the production of taurine from monoethanolamine
A method is disclosed for the production of taurine in high yield by a cyclic process of reacting monoethanolamine, sulfuric acid, and ammonium sulfite in the presence of additives to inhibit the hydrolysis of 2-aminoethyl hydrogen sulfate intermediate. The cyclic process is economical and little waste is generated.
PROCESS FOR MAKING BIOBASED PRODUCTS FROM SUGARS
An integrated, co-product capable process is provided for producing taurine in particular with optionally one or both of monoethanolamine and diethanolamine from one or more sugars, comprising pyrolyzing one or more sugars to produce a crude pyrolysis product mixture including glycolaldehyde and formaldehyde; optionally removing formaldehyde from the crude pyrolysis product mixture, then combining the crude pyrolysis product mixture with an aminating agent in the presence of hydrogen and further in the presence of a catalyst to produce at least monoethanolamine from the crude pyrolysis product mixture; optionally recovering diethanolamine from the crude reductive amination product, sulfating at least a portion to all of the monoethanolamine product to produce 2-aminoethyl hydrogen sulfate ester; and sulfonating the 2-aminoethyl hydrogen sulfate ester to produce taurine.
PROCESS FOR MAKING BIOBASED PRODUCTS FROM SUGARS
An integrated, co-product capable process is provided for producing taurine in particular with optionally one or both of monoethanolamine and diethanolamine from one or more sugars, comprising pyrolyzing one or more sugars to produce a crude pyrolysis product mixture including glycolaldehyde and formaldehyde; optionally removing formaldehyde from the crude pyrolysis product mixture, then combining the crude pyrolysis product mixture with an aminating agent in the presence of hydrogen and further in the presence of a catalyst to produce at least monoethanolamine from the crude pyrolysis product mixture; optionally recovering diethanolamine from the crude reductive amination product, sulfating at least a portion to all of the monoethanolamine product to produce 2-aminoethyl hydrogen sulfate ester; and sulfonating the 2-aminoethyl hydrogen sulfate ester to produce taurine.
HIGHER SECONDARY ALCOHOL ALKOXYLATE PRECURSOR, HIGHER SECONDARY ALCOHOL ALKOXYLATE ADDUCT AND HIGHER SECONDARY ALKYL ETHER SULFATE ESTER SALT, AND METHODS FOR PRODUCING THESE
A higher secondary alcohol alkoxylate precursor is obtained by reacting a long-chain olefin with a (poly)alkylene glycol. The precursor has a content of (poly)alkylene glycol of 0.2% by mass or lower with respect to the total mass of the higher secondary alcohol alkoxylate; a higher secondary alcohol alkoxylate adduct which is an alkylene oxide adduct of the higher secondary alcohol alkoxylate precursor; and a higher secondary alkyl ether sulfate ester salt which is a sulfated product of the higher secondary alcohol alkoxylate precursor or the higher secondary alcohol alkoxylate adduct.
HIGHER SECONDARY ALCOHOL ALKOXYLATE PRECURSOR, HIGHER SECONDARY ALCOHOL ALKOXYLATE ADDUCT AND HIGHER SECONDARY ALKYL ETHER SULFATE ESTER SALT, AND METHODS FOR PRODUCING THESE
A higher secondary alcohol alkoxylate precursor is obtained by reacting a long-chain olefin with a (poly)alkylene glycol. The precursor has a content of (poly)alkylene glycol of 0.2% by mass or lower with respect to the total mass of the higher secondary alcohol alkoxylate; a higher secondary alcohol alkoxylate adduct which is an alkylene oxide adduct of the higher secondary alcohol alkoxylate precursor; and a higher secondary alkyl ether sulfate ester salt which is a sulfated product of the higher secondary alcohol alkoxylate precursor or the higher secondary alcohol alkoxylate adduct.