C07C31/12

METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID, AND METHOD FOR PRODUCING METHYL METHACRYLATE

There is provided a method for producing isobutylene, in which isobutylene is produced from isobutanol with a high selectivity while suppressing a decrease in the isobutanol conversion rate under pressure. In the method for producing isobutylene according to the present invention, a raw material gas containing isobutanol is brought into contact with a catalyst to produce isobutylene from isobutanol, the method including bringing the raw material gas containing isobutanol into contact with a catalyst at a linear velocity of 1.20 cm/s or more under a pressure of 120 kPa or more in terms of absolute pressure to produce isobutylene from isobutanol.

METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID, AND METHOD FOR PRODUCING METHYL METHACRYLATE

There is provided a method for producing isobutylene, in which isobutylene is produced from isobutanol with a high selectivity while suppressing a decrease in the isobutanol conversion rate under pressure. In the method for producing isobutylene according to the present invention, a raw material gas containing isobutanol is brought into contact with a catalyst to produce isobutylene from isobutanol, the method including bringing the raw material gas containing isobutanol into contact with a catalyst at a linear velocity of 1.20 cm/s or more under a pressure of 120 kPa or more in terms of absolute pressure to produce isobutylene from isobutanol.

Method of producing a fuel additive with a hydration unit

A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.

Method of producing a fuel additive with a hydration unit

A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.

Use of nanoporous carbon membranes for separating aqueous/organic mixtures

The invention relates to the extraction of organic compounds from mixtures of said compounds with water, using a nanoporous carbon membrane. The invention can be used in any field where it is desired to separate an organic compound of interest from water, such as the drying of alcohols or alkanes.

Use of nanoporous carbon membranes for separating aqueous/organic mixtures

The invention relates to the extraction of organic compounds from mixtures of said compounds with water, using a nanoporous carbon membrane. The invention can be used in any field where it is desired to separate an organic compound of interest from water, such as the drying of alcohols or alkanes.

CATALYST, METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID, AND METHOD FOR PRODUCING METHYL METHACRYLATE

There is provided a catalyst that enables the production of isobutylene with a high selectivity in the production of isobutylene by dehydration of isobutanol. The catalyst according to the present invention contains at least one metal selected from Group 6 to Group 14 metal elements in Period 4 to Period 6 of the periodic table, in alumina which includes alumina consisting of one or more crystal phases of a monoclinic crystal phase, a tetragonal crystal phase, and a cubic crystal phase.

CATALYST, METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID, AND METHOD FOR PRODUCING METHYL METHACRYLATE

There is provided a catalyst that enables the production of isobutylene with a high selectivity in the production of isobutylene by dehydration of isobutanol. The catalyst according to the present invention contains at least one metal selected from Group 6 to Group 14 metal elements in Period 4 to Period 6 of the periodic table, in alumina which includes alumina consisting of one or more crystal phases of a monoclinic crystal phase, a tetragonal crystal phase, and a cubic crystal phase.

CATALYST, METHOD FOR PRODUCING ISOBUTYLENE, METHOD FOR PRODUCING METHACRYLIC ACID, AND METHOD FOR PRODUCING METHYL METHACRYLATE

There is provided a catalyst that enables the production of isobutylene with a high selectivity in the production of isobutylene by dehydration of isobutanol. The catalyst according to the present invention contains at least one metal selected from Group 6 to Group 14 metal elements in Period 4 to Period 6 of the periodic table, in alumina which includes alumina consisting of one or more crystal phases of a monoclinic crystal phase, a tetragonal crystal phase, and a cubic crystal phase.

CHROMIUM-CATALYZED PRODUCTION OF ALCOHOLS FROM HYDROCARBONS IN THE PRESENCE OF OXYGEN

Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and either a supported chromium (VI) catalyst or a supported chromium (II) catalyst are contacted, optionally with UV-visible light irradiation, followed by exposure to an oxidizing atmosphere and then hydrolysis to form a reaction product containing the alcohol compound and/or the carbonyl compound. The presence of oxygen significant increases the amount of alcohol/carbonyl product formed, as well as the formation of oxygenated dimers and trimers of certain hydrocarbon reactants.