Patent classifications
C07C33/04
Method for producing asymmetric conjugated diyne compound and method for producing Z,Z-conjugated diene compound using the same
Provided are a method for efficiently producing an asymmetric conjugated diyne from an inexpensive and safe alternative compound to hydroxylamine hydrochloride and a method for producing a Z,Z-conjugated diene compound from the asymmetric conjugated diyne compound thus obtained. More specifically, provided is a method for producing an asymmetric conjugated diyne compound comprising a step of subjecting a terminal alkyne compound (1): HC≡C—Z.sup.1—Y.sup.1 to a coupling reaction with an alkynyl halide (2): Y.sup.2—Z.sup.2—C≡C—X by using sodium borohydride in water and an organic solvent in the presence of a copper catalyst and a base to obtain the asymmetric conjugated diyne compound (3): Y.sup.2—Z.sup.2—C≡C—C≡C—Z.sup.1—Y.sup.1. In addition, provided is a method for producing a Z,Z-conjugated diene compound by reducing the resulting asymmetric conjugated diyne compound, or the like.
Method for producing asymmetric conjugated diyne compound and method for producing Z,Z-conjugated diene compound using the same
Provided are a method for efficiently producing an asymmetric conjugated diyne from an inexpensive and safe alternative compound to hydroxylamine hydrochloride and a method for producing a Z,Z-conjugated diene compound from the asymmetric conjugated diyne compound thus obtained. More specifically, provided is a method for producing an asymmetric conjugated diyne compound comprising a step of subjecting a terminal alkyne compound (1): HC≡C—Z.sup.1—Y.sup.1 to a coupling reaction with an alkynyl halide (2): Y.sup.2—Z.sup.2—C≡C—X by using sodium borohydride in water and an organic solvent in the presence of a copper catalyst and a base to obtain the asymmetric conjugated diyne compound (3): Y.sup.2—Z.sup.2—C≡C—C≡C—Z.sup.1—Y.sup.1. In addition, provided is a method for producing a Z,Z-conjugated diene compound by reducing the resulting asymmetric conjugated diyne compound, or the like.
METHODS AND COMPOSITIONS OF USING VISCOELASTIC SURFACTANTS AS DIVERSION AGENTS
A wellbore fluid may include a gemini surfactant, a zwitterionic surfactant, an activator, and an aqueous base fluid. The gemini surfactant may have a structure represented by formula (I):
##STR00001##
where R.sup.1 is a C.sub.1-C.sub.10 hydrocarbon group, m and o are each, independently, an integer ranging from 1 to 4, and n is an integer ranging from 8 to 12.
Methods and compositions of using viscoelastic surfactants as diversion agents
A wellbore fluid may include a gemini surfactant, a zwitterionic surfactant, an activator, and an aqueous base fluid. The gemini surfactant may have a structure represented by formula (I): ##STR00001## where R.sup.1 is a C.sub.1-C.sub.10 hydrocarbon group, m and o are each, independently, an integer ranging from 1 to 4, and n is an integer ranging from 8 to 12.
Methods and compositions of using viscoelastic surfactants as diversion agents
A wellbore fluid may include a gemini surfactant, a zwitterionic surfactant, an activator, and an aqueous base fluid. The gemini surfactant may have a structure represented by formula (I): ##STR00001## where R.sup.1 is a C.sub.1-C.sub.10 hydrocarbon group, m and o are each, independently, an integer ranging from 1 to 4, and n is an integer ranging from 8 to 12.
Linker compounds, methods of producing the same and uses thereof
The present disclosure provides a bifunctional linker for coupling at least one functional moiety, preferably a bis-allyl propionic acid (BAPA), to a polymer-containing matrix. Also disclosed by the present disclosure are anhydrides of the bifunctional linker, processes for preparing the bifunctional linker and such anhydride, as well as surfaces, such as cellulose containing matrices, coupled with the bifunctional linker, at times, the latter carrying a functional agent.
Linker compounds, methods of producing the same and uses thereof
The present disclosure provides a bifunctional linker for coupling at least one functional moiety, preferably a bis-allyl propionic acid (BAPA), to a polymer-containing matrix. Also disclosed by the present disclosure are anhydrides of the bifunctional linker, processes for preparing the bifunctional linker and such anhydride, as well as surfaces, such as cellulose containing matrices, coupled with the bifunctional linker, at times, the latter carrying a functional agent.
LINKER COMPOUNDS, METHODS OF PRODUCING THE SAME AND USES THEREOF
The present disclosure provides a bifunctional linker for coupling at least one functional moiety, preferably a bis-allyl propionic acid (BAPA), to a polymer-containing matrix. Also disclosed by the present disclosure are anhydrides of the bifunctional linker, processes for preparing the bifunctional linker and such anhydride, as well as surfaces, such as cellulose containing matrices, coupled with the bifunctional linker, at times, the latter carrying a functional agent.
Chain multiyne compound, preparation method and application thereof
The present invention relates to fields of organic chemistry and organometallic chemistry. The present invention discloses a chain multiyne compound, a preparation method thereof and an application in synthesizing a fused-ring metallacyclic compound. A structure of the chain multiyne compound in the present invention is shown as Formula I below. The present invention also provides a preparation method of the chain multiyne compound and an application thereof in a synthesis of a fused-ring metallacyclic compound. The chain multiyne compound disclosed in the present invention has multiple functional groups and the structure of the chain multiyne compound is adjustable. The chain multiyne compound can also be used to synthesize the fused-ring metallacyclic compound efficiently. The preparation method of the chain multiyne compound disclosed in the present invention is simple, which can be used to prepare the chain multiyne compound rapidly and efficiently. ##STR00001##
Chain multiyne compound, preparation method and application thereof
The present invention relates to fields of organic chemistry and organometallic chemistry. The present invention discloses a chain multiyne compound, a preparation method thereof and an application in synthesizing a fused-ring metallacyclic compound. A structure of the chain multiyne compound in the present invention is shown as Formula I below. The present invention also provides a preparation method of the chain multiyne compound and an application thereof in a synthesis of a fused-ring metallacyclic compound. The chain multiyne compound disclosed in the present invention has multiple functional groups and the structure of the chain multiyne compound is adjustable. The chain multiyne compound can also be used to synthesize the fused-ring metallacyclic compound efficiently. The preparation method of the chain multiyne compound disclosed in the present invention is simple, which can be used to prepare the chain multiyne compound rapidly and efficiently. ##STR00001##