Patent classifications
C07C4/16
METHOD OF PRODUCING AROMATIC HYDROCARBONS
Method of producing aromatic hydrocarbons including: supplying a raw material stream to a C6 separation column, supplying an upper discharge stream from the C6 separation column to a first gasoline hydrogenation unit, and supplying a lower discharge stream from the C6 separation column to a C7 separation column; supplying an upper discharge stream from the C7 separation column to a hydrodealkylation reaction unit and supplying a lower discharge stream from the C7 separation column to a C8 separation column; separating benzene from discharged streams from the first gasoline hydrogenation unit and the hydrodealkylation reaction unit; removing a lower discharge stream from the C8 separation column and supplying an upper discharge stream from the C8 separation column to a second extractive distillation column; and separating styrene from a lower discharge stream of the second extractive distillation column and separating xylene from an upper discharge stream of the second extractive distillation column.
METHOD OF PRODUCING AROMATIC HYDROCARBONS
Method of producing aromatic hydrocarbons including: supplying a raw material stream to a C6 separation column, supplying an upper discharge stream from the C6 separation column to a first gasoline hydrogenation unit, and supplying a lower discharge stream from the C6 separation column to a C7 separation column; supplying an upper discharge stream from the C7 separation column to a hydrodealkylation reaction unit and supplying a lower discharge stream from the C7 separation column to a C8 separation column; separating benzene from discharged streams from the first gasoline hydrogenation unit and the hydrodealkylation reaction unit; removing a lower discharge stream from the C8 separation column and supplying an upper discharge stream from the C8 separation column to a second extractive distillation column; and separating styrene from a lower discharge stream of the second extractive distillation column and separating xylene from an upper discharge stream of the second extractive distillation column.
Transalkylation/disproportionation or thermal hydrodealkylation hydrocarbon processing methods and systems employing an increased ethylbenzene feed content
Methods and apparatus for processing hydrocarbons are provided. In one example, a method for processing hydrocarbons includes the step of providing feed stream including toluene, ethylbenzene, mixed xylenes, and C.sub.9 hydrocarbons. Ethylbenzene is present in the feed stream in an amount of at least about 20% by weight of total C.sub.8 aromatic hydrocarbons present in the feed stream. The method further includes the step of subjecting the feed stream to ethylbenzene conversion to form a benzene-containing product stream that includes benzene.
Transalkylation/disproportionation or thermal hydrodealkylation hydrocarbon processing methods and systems employing an increased ethylbenzene feed content
Methods and apparatus for processing hydrocarbons are provided. In one example, a method for processing hydrocarbons includes the step of providing feed stream including toluene, ethylbenzene, mixed xylenes, and C.sub.9 hydrocarbons. Ethylbenzene is present in the feed stream in an amount of at least about 20% by weight of total C.sub.8 aromatic hydrocarbons present in the feed stream. The method further includes the step of subjecting the feed stream to ethylbenzene conversion to form a benzene-containing product stream that includes benzene.
Transalkylation/disproportionation or thermal hydrodealkylation hydrocarbon processing methods and systems employing an increased ethylbenzene feed content
Methods and apparatus for processing hydrocarbons are provided. In one example, a method for processing hydrocarbons includes the step of providing feed stream including toluene, ethylbenzene, mixed xylenes, and C.sub.9 hydrocarbons. Ethylbenzene is present in the feed stream in an amount of at least about 20% by weight of total C.sub.8 aromatic hydrocarbons present in the feed stream. The method further includes the step of subjecting the feed stream to ethylbenzene conversion to form a benzene-containing product stream that includes benzene.
PROCESS FOR INTERCONVERSION OF OLEFINS WITH MODIFIED BETA ZEOLITE
Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.
PROCESS FOR INTERCONVERSION OF OLEFINS WITH MODIFIED BETA ZEOLITE
Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.
Process for interconversion of olefins with modified beta zeolite
Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.
Process for interconversion of olefins with modified beta zeolite
Methods for interconverting olefins in an olefin-rich hydrocarbon stream include contacting the olefin-rich hydrocarbon stream with a catalyst system in an olefin interconversion unit to produce an interconverted effluent comprising ethylene and propylene. The contacting may be conducted at a reaction temperature from 450° C. to 750° C., a reaction pressure from 1 bar to 5 bar, and a residence time from 0.5 seconds to 1000 seconds. The catalyst system includes a framework-substituted beta zeolite. The framework-substituted beta zeolite has a *BEA aluminosilicate framework that has been modified by substituting a portion of framework aluminum atoms of the *BEA aluminosilicate framework with beta-zeolite Al-substitution atoms independently selected from the group consisting of titanium atoms, zirconium atoms, hafnium atoms, and combinations thereof.
Method and system for producing benzene
A method (100) is proposed for the manufacture of benzene, in which a first feedstock mixture is formed, which contains alkylated aromatics and hydrogen, and in which the alkylated aromatics contained in the first feedstock mixture are partially converted with the hydrogen contained in the first feedstock mixture to the benzene through hydrodealkylation (33), thereby obtaining a first product mixture, wherein the first product mixture contains the benzene, the unconverted alkylated aromatics, alkanes with one to three carbon atoms formed in the conversion of the alkylated aromatics to the benzene, and the unconverted hydrogen, and wherein at least a part of the alkanes with one to three carbon atoms and of the hydrogen are separated from the first product mixture, thereby obtaining a light-gas fraction. It is proposed that the hydrogen contained in the first feedstock mixture is provided at least in part with the use of a low-temperature separation (18), to which at least a part of a second product mixture is supplied, wherein the second product mixture is formed at least in part through steam cracking (11) of a second feedstock mixture, and that the light-gas fraction is also supplied at least in part to the low-temperature separation (18). A corresponding plant also forms the subject matter of the invention.