Patent classifications
C07C49/04
Processes for the manufacture of secondary fatty alcohols, internal olefins and internal olefin sulfonates
Process P.sup.1 for the manufacture of a secondary fatty alcohol, said process P.sup.1 comprising synthesizing an internal ketone K1 by a process P.sup.0 comprising the decarboxylative ketonization reaction of a fatty acid or the like in a liquid phase with a metal compound as catalyst in a reaction medium, wherein a ketone K.sup.2 at liquid state, which is identical or similar to the internal ketone K.sup.1, is introduced into the reaction medium, and subjecting the internal ketone K.sup.1 to a hydrogenation reaction with hydrogen gas as hydrogenating agent to form the secondary fatty alcohol. Use of the secondary fatty alcohol manufactured by the process P.sup.1 for the manufacture of an internal olefin or of an internal olefin sulfonate.
Processes for the manufacture of secondary fatty alcohols, internal olefins and internal olefin sulfonates
Process P.sup.1 for the manufacture of a secondary fatty alcohol, said process P.sup.1 comprising synthesizing an internal ketone K1 by a process P.sup.0 comprising the decarboxylative ketonization reaction of a fatty acid or the like in a liquid phase with a metal compound as catalyst in a reaction medium, wherein a ketone K.sup.2 at liquid state, which is identical or similar to the internal ketone K.sup.1, is introduced into the reaction medium, and subjecting the internal ketone K.sup.1 to a hydrogenation reaction with hydrogen gas as hydrogenating agent to form the secondary fatty alcohol. Use of the secondary fatty alcohol manufactured by the process P.sup.1 for the manufacture of an internal olefin or of an internal olefin sulfonate.
CHROMIUM-CATALYZED PRODUCTION OF ALCOHOLS FROM HYDROCARBONS IN THE PRESENCE OF OXYGEN
Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and either a supported chromium (VI) catalyst or a supported chromium (II) catalyst are contacted, optionally with UV-visible light irradiation, followed by exposure to an oxidizing atmosphere and then hydrolysis to form a reaction product containing the alcohol compound and/or the carbonyl compound. The presence of oxygen significant increases the amount of alcohol/carbonyl product formed, as well as the formation of oxygenated dimers and trimers of certain hydrocarbon reactants.
CHROMIUM-CATALYZED PRODUCTION OF ALCOHOLS FROM HYDROCARBONS IN THE PRESENCE OF OXYGEN
Processes for converting a hydrocarbon reactant into an alcohol compound and/or a carbonyl compound are disclosed in which the hydrocarbon reactant and either a supported chromium (VI) catalyst or a supported chromium (II) catalyst are contacted, optionally with UV-visible light irradiation, followed by exposure to an oxidizing atmosphere and then hydrolysis to form a reaction product containing the alcohol compound and/or the carbonyl compound. The presence of oxygen significant increases the amount of alcohol/carbonyl product formed, as well as the formation of oxygenated dimers and trimers of certain hydrocarbon reactants.
Chemical liquid purification method and chemical liquid
An object of the present invention is to provide a chemical liquid purification method which makes it possible to obtain a chemical liquid having excellent defect inhibition performance. Another object of the present invention is to provide a chemical liquid. The chemical liquid purification method according to an embodiment of the present invention is a chemical liquid purification method including obtaining a chemical liquid by purifying a substance to be purified containing an organic solvent, in which a content of the stabilizer in the substance to be purified with respect to the total mass of the substance to be purified is equal to or greater than 0.1 mass ppm and less than 100 mass ppm.
Processes for the conversion of mixed oxygenates feedstocks to hydrocarbon fuels
A method for forming a desired hydrocarbon fuel product from a mixed oxygenate feedstock by utilizing chemical processes to form ketones from the oxygenate feed, upgrade the ketones, recycle selected upgraded ketones through the upgrading process to obtain a desired intermediate and hydrogenating the desired intermediate to obtain the desired hydrocarbon fuel product. In various alternative configurations and embodiments this can be accomplished in a number of ways, and originate in a number of different positions and occasions.
Processes for the conversion of mixed oxygenates feedstocks to hydrocarbon fuels
A method for forming a desired hydrocarbon fuel product from a mixed oxygenate feedstock by utilizing chemical processes to form ketones from the oxygenate feed, upgrade the ketones, recycle selected upgraded ketones through the upgrading process to obtain a desired intermediate and hydrogenating the desired intermediate to obtain the desired hydrocarbon fuel product. In various alternative configurations and embodiments this can be accomplished in a number of ways, and originate in a number of different positions and occasions.
CHEMICAL LIQUID PURIFICATION METHOD AND CHEMICAL LIQUID
An object of the present invention is to provide a chemical liquid purification method which makes it possible to obtain a chemical liquid having excellent defect inhibition performance. Another object of the present invention is to provide a chemical liquid. The chemical liquid purification method according to an embodiment of the present invention is a chemical liquid purification method including obtaining a chemical liquid by purifying a substance to be purified containing an organic solvent, in which a content of the stabilizer in the substance to be purified with respect to the total mass of the substance to be purified is equal to or greater than 0.1 mass ppm and less than 100 mass ppm.
RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.
RENEWABLE BASE OIL PRODUCTION ENGAGING METATHESIS
A process is disclosed for producing renewable products, such as a renewable base oil, from a feedstock of biological origin. The process includes subjecting a feedstock containing free fatty acids and fatty acid glycerides, wherein at least one hydrocarbon chain is unsaturated, to esterification reaction in the presence of an alcohol. An ester stream thereby obtained is then subjected to metathesis conditions in the presence of a renewable alkene to obtain a metathesis product. Separation of the metathesis product includes recovery of a fraction containing or consisting essentially of C16 fatty acid esters, which is subjected to ketonisation reaction conditions to produce long chain ketones, which after hydrotreatment meet requirements for a renewable base oil. Ketonisation reaction produces renewable alkene usable in metathesis reaction.