To provide an egg shell-type platinum-loaded alumina catalyst demonstrating excellent performance in terms of catalyst life, an egg shell-type platinum-loaded alumina catalyst includes: an alumina carrier; platinum dispersed and loaded on an outer shell of the alumina carrier; and one or more second components selected from the group consisting of vanadium, chromium, molybdenum, and phosphorus. Preferably, the content of platinum is 0.05 to 5.0 wt % calculated as elemental platinum. The content of each second component preferably is 0.1 to 5.0 wt % calculated as each element. The alumina carrier has a surface area of 150 m.sup.2/g or more, a pore volume of 0.40 cm.sup.3/g or more, and an average pore diameter of 40 to 300 Å, with pores having a pore diameter in a range of ±30 Å from the average pore diameter occupying 60% or more of a total pore volume.

To provide an egg shell-type platinum-loaded alumina catalyst demonstrating excellent performance in terms of catalyst life, an egg shell-type platinum-loaded alumina catalyst includes: an alumina carrier; platinum dispersed and loaded on an outer shell of the alumina carrier; and one or more second components selected from the group consisting of vanadium, chromium, molybdenum, and phosphorus. Preferably, the content of platinum is 0.05 to 5.0 wt % calculated as elemental platinum. The content of each second component preferably is 0.1 to 5.0 wt % calculated as each element. The alumina carrier has a surface area of 150 m.sup.2/g or more, a pore volume of 0.40 cm.sup.3/g or more, and an average pore diameter of 40 to 300 Å, with pores having a pore diameter in a range of ±30 Å from the average pore diameter occupying 60% or more of a total pore volume.

A hydrogen desorption method includes a step of bringing a liquid containing an alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain, a quinone, and an electrolyte into contact with a anode and a step of desorbing hydrogen from the alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain.

A hydrogen desorption method includes a step of bringing a liquid containing an alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain, a quinone, and an electrolyte into contact with a anode and a step of desorbing hydrogen from the alicyclic saturated hydrocarbon having a tertiary carbon atom bearing a saturated hydrocarbon side chain.

Methods of preparing unsaturated compounds or analogs through dehydrogenation of corresponding saturated compounds and/or hydrogenation of aromatic compounds are disclosed.

Methods of preparing unsaturated compounds or analogs through dehydrogenation of corresponding saturated compounds and/or hydrogenation of aromatic compounds are disclosed.

Methods of preparing unsaturated compounds or analogs through dehydrogenation of corresponding saturated compounds and/or hydrogenation of aromatic compounds are disclosed.

Methods and systems for heating a reactor feed in a multi reactor hydrocarbon dehydrogenation process. The methods and systems are advantageously employed for the production of styrene by the catalytic dehydrogenation of ethylbenzene. The catalytic dehydrogenation process employs heating steam operating at a steam to oil ratio of about 1.0 or less and relatively low steam superheater furnace temperature, such that all components exposed to steam in the process (outside of the fired heaters) can be constructed with standard metallurgy.

The subject invention provides synthetic compounds, and compound complexes having catalytic activities towards oxidation or oxygenation, and/or dehydrogenation of various substrates comprising C—H bonds. The catalysts of the subject invention comprise a dinuclear Cu(I)/Cu(II) center that can convert between a resting state and a reactive species. The subject invention also provides methods of using such catalysts for the oxidation of substrates comprising C—H bonds, e.g., hydrocarbons, to synthesize chemicals for use as pharmaceuticals and industrial feedstock.

The subject invention provides synthetic compounds, and compound complexes having catalytic activities towards oxidation or oxygenation, and/or dehydrogenation of various substrates comprising C—H bonds. The catalysts of the subject invention comprise a dinuclear Cu(I)/Cu(II) center that can convert between a resting state and a reactive species. The subject invention also provides methods of using such catalysts for the oxidation of substrates comprising C—H bonds, e.g., hydrocarbons, to synthesize chemicals for use as pharmaceuticals and industrial feedstock.