Patent classifications
C07C51/21
FORMIC ACID PRODUCTION METHOD AND FORMIC ACID PRODUCTION SYSTEM
The purpose of the present invention is to provide a formic acid production method and a formic acid production system with high production efficiency and in low cost. It is a formic acid production method comprising: preparing a mixed solution by mixing a solution containing an organic substance with a metal oxide powder having a photocatalyst function; and producing a formic acid by irradiating a light to the mixed solution. Also, it is a formic acid production system comprising: a raw material charging unit into which a solution containing an organic substance and a metal oxide powder having a photocatalyst function are charged; an artificial photosynthesis reaction unit for reacting a mixed solution of the organic substance and the metal oxide powder by irradiating a sunlight or a light to the mixed solution; and a formic acid recovery unit for recovering a formic acid from the mixed solution after an artificial photosynthesis reaction.
FORMIC ACID PRODUCTION METHOD AND FORMIC ACID PRODUCTION SYSTEM
The purpose of the present invention is to provide a formic acid production method and a formic acid production system with high production efficiency and in low cost. It is a formic acid production method comprising: preparing a mixed solution by mixing a solution containing an organic substance with a metal oxide powder having a photocatalyst function; and producing a formic acid by irradiating a light to the mixed solution. Also, it is a formic acid production system comprising: a raw material charging unit into which a solution containing an organic substance and a metal oxide powder having a photocatalyst function are charged; an artificial photosynthesis reaction unit for reacting a mixed solution of the organic substance and the metal oxide powder by irradiating a sunlight or a light to the mixed solution; and a formic acid recovery unit for recovering a formic acid from the mixed solution after an artificial photosynthesis reaction.
Molybdenum-vanadium-niobium-ceria-based catalyst for oxidative dehydrogenation of alkanes and/or alkene oxidation
The invention relates to a catalyst which comprises: a) a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium; and b) ceria particles having a crystallite size greater than 15 nanometers (nm); wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Further, the invention relates to a process for preparing a catalyst, which comprises mixing a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium with ceria particles having a crystallite size greater than 15 nanometers (nm), wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Still further, the invention relates to an alkane oxidative dehydrogenation and/or alkene oxidation process wherein such catalyst is used.
Molybdenum-vanadium-niobium-ceria-based catalyst for oxidative dehydrogenation of alkanes and/or alkene oxidation
The invention relates to a catalyst which comprises: a) a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium; and b) ceria particles having a crystallite size greater than 15 nanometers (nm); wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Further, the invention relates to a process for preparing a catalyst, which comprises mixing a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium with ceria particles having a crystallite size greater than 15 nanometers (nm), wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Still further, the invention relates to an alkane oxidative dehydrogenation and/or alkene oxidation process wherein such catalyst is used.
Method for producing oxide catalyst, and method for producing unsaturated nitrile and unsaturated acid
The present invention provides a method for producing an oxide catalyst containing antimony, comprising a step (A) of obtaining the oxide catalyst using antimony particles containing a diantimony trioxide as a source of the antimony, wherein an abundance of a pentavalent antimony in a surface layer of the antimony particle to be measured in XPS analysis is less than 70 atom %, and the antimony particle has an average particle size of 1.2 μm or less.
Method for producing oxide catalyst, and method for producing unsaturated nitrile and unsaturated acid
The present invention provides a method for producing an oxide catalyst containing antimony, comprising a step (A) of obtaining the oxide catalyst using antimony particles containing a diantimony trioxide as a source of the antimony, wherein an abundance of a pentavalent antimony in a surface layer of the antimony particle to be measured in XPS analysis is less than 70 atom %, and the antimony particle has an average particle size of 1.2 μm or less.
Biocatalytic methods to convert cyclohexane oxidation process waste streams to useful products
The invention relates to methods for enriching monomer content in a cycloalkane oxidation process mixed organic waste stream. In particular, the methods involve combining a biocatalyst with a mixed organic waste stream from a cycloalkane oxidation process, and enzymatically converting dimeric and/or oligomeric components of said waste stream into monomeric components. The methods may enrich the content of diacids, adipic acid, and/or other α,ω-difunctional C6 alkanes in the mixed organic waste stream. Additionally, the treated mixed organic waste streams may have improved burning efficiency.
Biocatalytic methods to convert cyclohexane oxidation process waste streams to useful products
The invention relates to methods for enriching monomer content in a cycloalkane oxidation process mixed organic waste stream. In particular, the methods involve combining a biocatalyst with a mixed organic waste stream from a cycloalkane oxidation process, and enzymatically converting dimeric and/or oligomeric components of said waste stream into monomeric components. The methods may enrich the content of diacids, adipic acid, and/or other α,ω-difunctional C6 alkanes in the mixed organic waste stream. Additionally, the treated mixed organic waste streams may have improved burning efficiency.
A Process for the Production of Oxidized Wood Products
The present invention relates to a process for the production of oxidized wood products, comprising step a) reacting chips of one or more wood products in a basic solution at a pH between 8 and 14 under an oxygen atmosphere at a pressure of at least 0.1 MPa, or at least 0.9 MPa. A copper catalyst may be used in the process.
A Process for the Production of Oxidized Wood Products
The present invention relates to a process for the production of oxidized wood products, comprising step a) reacting chips of one or more wood products in a basic solution at a pH between 8 and 14 under an oxygen atmosphere at a pressure of at least 0.1 MPa, or at least 0.9 MPa. A copper catalyst may be used in the process.