Patent classifications
C07C51/50
Method of isolating lipids from a lipids containing biomass
The current invention relates to a method of isolating polyunsaturated fatty acids containing lipids from a lipids containing biomass. The method involves providing a suspension of cells with a PUFAs-containing lipid; optionally lysing the cells; concentrating the suspension; adding base equivalents to the suspension based on the total dry matter present; feeding a continuous reactor with the suspension; and separating the lipids-containing light phase from the water and cell debris-containing heavy phase.
Method of isolating lipids from a lipids containing biomass
The current invention relates to a method of isolating polyunsaturated fatty acids containing lipids from a lipids containing biomass. The method involves providing a suspension of cells with a PUFAs-containing lipid; optionally lysing the cells; concentrating the suspension; adding base equivalents to the suspension based on the total dry matter present; feeding a continuous reactor with the suspension; and separating the lipids-containing light phase from the water and cell debris-containing heavy phase.
COMPOSITION FOR THE IMMEDIATE TERMINATION OF A FREE-RADICAL POLYMERIZATION AND USES THEREOF
The invention relates to a composition for the immediate termination of a free-radical polymerization, the use thereof for the stabilization of free-radically polymerizable monomers against free-radical polymerization and a method for the immediate termination of free-radical polymerizations.
COMPOSITION FOR THE IMMEDIATE TERMINATION OF A FREE-RADICAL POLYMERIZATION AND USES THEREOF
The invention relates to a composition for the immediate termination of a free-radical polymerization, the use thereof for the stabilization of free-radically polymerizable monomers against free-radical polymerization and a method for the immediate termination of free-radical polymerizations.
PROCESS FOR INHIBITING THE UNDESIRED FREE-RADICAL POLYMERIZATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with protoanemonine in an amount that results in a protoanemonine content in the range from 0.5 to 100 ppmw based on the weight of the acrylic acid present in P, and a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 0.5 to 100 ppmw of protoanemonine, in each case based on the weight of the acrylic acid present in P.
PROCESS FOR INHIBITING THE UNDESIRED FREE-RADICAL POLYMERIZATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with protoanemonine in an amount that results in a protoanemonine content in the range from 0.5 to 100 ppmw based on the weight of the acrylic acid present in P, and a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 0.5 to 100 ppmw of protoanemonine, in each case based on the weight of the acrylic acid present in P.
PROCESS FOR INHIBITING THE UNDESIRED FREE-RADICAL POLYMERIZATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with protoanemonine in an amount that results in a protoanemonine content in the range from 0.5 to 100 ppmw based on the weight of the acrylic acid present in P, and a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 0.5 to 100 ppmw of protoanemonine, in each case based on the weight of the acrylic acid present in P.
Method for preparing 4,4′-dihydroxy-[1,1′-biphenyl-3,3′-dicarboxylic acid]
The present invention relates to a method for preparing 4,4′-dihydroxy-[1,1′-biphenyl-3,3′-dicarboxylic acid], the method comprising a step for preparing a compound represented by chemical formula 1 by reacting a compound represented by chemical formula 2 with a base according to reaction formula 1. [reaction formula 1] [chemical formula 1] [chemical formula 2] According to the present invention, because use of additional carbon dioxide is unnecessary during the reaction, internal pressure is lowered during same, the reaction can be carried out at a lower temperature, the yield from the synthesis is notably improved as hardening of the resulting substance is absent, and H.sub.4dobpdc can be synthesized in large amounts as an additional process for obtaining pure ligands is unnecessary.
Method for preparing 4,4′-dihydroxy-[1,1′-biphenyl-3,3′-dicarboxylic acid]
The present invention relates to a method for preparing 4,4′-dihydroxy-[1,1′-biphenyl-3,3′-dicarboxylic acid], the method comprising a step for preparing a compound represented by chemical formula 1 by reacting a compound represented by chemical formula 2 with a base according to reaction formula 1. [reaction formula 1] [chemical formula 1] [chemical formula 2] According to the present invention, because use of additional carbon dioxide is unnecessary during the reaction, internal pressure is lowered during same, the reaction can be carried out at a lower temperature, the yield from the synthesis is notably improved as hardening of the resulting substance is absent, and H.sub.4dobpdc can be synthesized in large amounts as an additional process for obtaining pure ligands is unnecessary.
Water-based extraction and purification processes for cannabinoid acids
The present invention relates to methods of extracting cannabinoid acids from cannabis plant material by combining the plant material with an aqueous solution having a high pH to solubilize cannabinoid acid anions, followed by precipitation of the cannabinoid acids at low pH and filtration. The method provides yields of up to 97%, while high pH purification of ethanol extracted oils yielded purities up to 86%.