Methods and systems for producing vinyl acetate may use flammability limit (FL) formulas with improved efficiencies at more than one location in the vinyl acetate production process. Herein, FLs can be used at one or more of four portions of the vinyl acetate production process: the reactor, the process-to-process heat exchangers, the carbon dioxide removal system, and the ethylene recovery system. Such FLs are functions of operating conditions and include at least one interaction term that represents the interrelation of two or more of the operating conditions (e.g., temperature, pressure, and component concentration) on the FL.

Methods and systems for producing vinyl acetate may use flammability limit (FL) formulas with improved efficiencies at more than one location in the vinyl acetate production process. Herein, FLs can be used at one or more of four portions of the vinyl acetate production process: the reactor, the process-to-process heat exchangers, the carbon dioxide removal system, and the ethylene recovery system. Such FLs are functions of operating conditions and include at least one interaction term that represents the interrelation of two or more of the operating conditions (e.g., temperature, pressure, and component concentration) on the FL.

Methods and systems for producing vinyl acetate may use flammability limit (FL) formulas with improved efficiencies at more than one location in the vinyl acetate production process. Herein, FLs can be used at one or more of four portions of the vinyl acetate production process: the reactor, the process-to-process heat exchangers, the carbon dioxide removal system, and the ethylene recovery system. Such FLs are functions of operating conditions and include at least one interaction term that represents the interrelation of two or more of the operating conditions (e.g., temperature, pressure, and component concentration) on the FL.

The invention generally relates to methods of making substituted arenes via direct C—H amination. More specifically, methods of making para- and ortho-substituted arenes via direct C—H amination are disclosed. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

The invention generally relates to methods of making substituted arenes via direct C—H amination. More specifically, methods of making para- and ortho-substituted arenes via direct C—H amination are disclosed. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

The invention generally relates to methods of making substituted arenes via direct C—H amination. More specifically, methods of making para- and ortho-substituted arenes via direct C—H amination are disclosed. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

A fixed-bed multi-tubular reactor for producing an alkenyl acetate by a gas phase catalytic oxidation reaction of a lower olefin, acetic acid and oxygen including a plurality of reaction tubes, a thermometer protection tube inserted into at least one of the plurality of reaction tubes, a thermometer inserted into the thermometer protection tube, and a shield disposed above the reaction tube into which the thermometer protection tube is inserted and attached to the thermometer protection tube, wherein an effective projection region of the shield entirely covers the inlet opening of the reaction tube into which the thermometer protection tube is inserted.

A fixed-bed multi-tubular reactor for producing an alkenyl acetate by a gas phase catalytic oxidation reaction of a lower olefin, acetic acid and oxygen including a plurality of reaction tubes, a thermometer protection tube inserted into at least one of the plurality of reaction tubes, a thermometer inserted into the thermometer protection tube, and a shield disposed above the reaction tube into which the thermometer protection tube is inserted and attached to the thermometer protection tube, wherein an effective projection region of the shield entirely covers the inlet opening of the reaction tube into which the thermometer protection tube is inserted.

A fixed-bed multi-tubular reactor for producing an alkenyl acetate by a gas phase catalytic oxidation reaction of a lower olefin, acetic acid and oxygen including a plurality of reaction tubes, a thermometer protection tube inserted into at least one of the plurality of reaction tubes, a thermometer inserted into the thermometer protection tube, and a shield disposed above the reaction tube into which the thermometer protection tube is inserted and attached to the thermometer protection tube, wherein an effective projection region of the shield entirely covers the inlet opening of the reaction tube into which the thermometer protection tube is inserted.

A fixed-bed multi-tubular reactor for producing an alkenyl acetate by a gas phase catalytic oxidation reaction of a lower olefin, acetic acid and oxygen including a plurality of reaction tubes, a thermometer protection tube inserted into at least one of the plurality of reaction tubes, a thermometer inserted into the thermometer protection tube, and a shield disposed above the reaction tube into which the thermometer protection tube is inserted and attached to the thermometer protection tube, wherein an effective projection region of the shield entirely covers the inlet opening of the reaction tube into which the thermometer protection tube is inserted.