The present disclosure, in general, relates to portable/transportable apparatuses, methods, and systems for generating and delivering sulfur trioxide on-site or near an item to be treated. The present disclosure also relates to portable/transportable apparatuses, methods, and systems or extracting hydrocarbons from deposits containing a clathrate hydrate such as methane hydrates.

The present disclosure, in general, relates to portable/transportable apparatuses, methods, and systems for generating and delivering sulfur trioxide on-site or near an item to be treated. The present disclosure also relates to portable/transportable apparatuses, methods, and systems or extracting hydrocarbons from deposits containing a clathrate hydrate such as methane hydrates.

A process (100) for the production of linear alpha-olefins is proposed, wherein ethylene is subjected to catalytic oligomerization (1) in a feed mixture to obtain a product mixture containing alpha-olefins with different chain length and side compounds. In a primary fractionation (2), a primary fraction is formed using at least part of the product mixture, and in a secondary fractionation (4), a secondary fraction is formed using at least part of the primary fraction. The primary fractionation (2) and the secondary fractionation (4) are carried out such that the primary fraction and the secondary fraction predominantly contain one of the alpha-olefins and are low in or free of other alpha-olefins, that the primary fraction contains one or more of the side compounds, and that the secondary fraction is depleted relative to the primary fraction in the one or more side compounds. In an intermediate step (3) between the primary fractionation (2) and the secondary fractionation (4), to which at least part of the primary fraction is subjected, the one or more side compounds are at least partly converted to one or more secondary compounds, and the one or more secondary compounds are at least partly separated in the secondary fractionation (4). The intermediate step (3) is carried out in such a way that not more than 0.8% of the alpha-olefin predominantly contained in the primary fraction or the part thereof subjected to the intermediate step is reacted. The intermediate step is carried out in the presence of 30 wt.-ppm to 200 wt.-ppm of water as reaction moderator and using a strongly acidic ion exchange resin.

A process (100) for the production of linear alpha-olefins is proposed, wherein ethylene is subjected to catalytic oligomerization (1) in a feed mixture to obtain a product mixture containing alpha-olefins with different chain length and side compounds. In a primary fractionation (2), a primary fraction is formed using at least part of the product mixture, and in a secondary fractionation (4), a secondary fraction is formed using at least part of the primary fraction. The primary fractionation (2) and the secondary fractionation (4) are carried out such that the primary fraction and the secondary fraction predominantly contain one of the alpha-olefins and are low in or free of other alpha-olefins, that the primary fraction contains one or more of the side compounds, and that the secondary fraction is depleted relative to the primary fraction in the one or more side compounds. In an intermediate step (3) between the primary fractionation (2) and the secondary fractionation (4), to which at least part of the primary fraction is subjected, the one or more side compounds are at least partly converted to one or more secondary compounds, and the one or more secondary compounds are at least partly separated in the secondary fractionation (4). The intermediate step (3) is carried out in such a way that not more than 0.8% of the alpha-olefin predominantly contained in the primary fraction or the part thereof subjected to the intermediate step is reacted. The intermediate step is carried out in the presence of 30 wt.-ppm to 200 wt.-ppm of water as reaction moderator and using a strongly acidic ion exchange resin.

A process (100) for the production of linear alpha-olefins is proposed, wherein ethylene is subjected to catalytic oligomerization (1) in a feed mixture to obtain a product mixture containing alpha-olefins with different chain length and side compounds. In a primary fractionation (2), a primary fraction is formed using at least part of the product mixture, and in a secondary fractionation (4), a secondary fraction is formed using at least part of the primary fraction. The primary fractionation (2) and the secondary fractionation (4) are carried out such that the primary fraction and the secondary fraction predominantly contain one of the alpha-olefins and are low in or free of other alpha-olefins, that the primary fraction contains one or more of the side compounds, and that the secondary fraction is depleted relative to the primary fraction in the one or more side compounds. In an intermediate step (3) between the primary fractionation (2) and the secondary fractionation (4), to which at least part of the primary fraction is subjected, the one or more side compounds are at least partly converted to one or more secondary compounds, and the one or more secondary compounds are at least partly separated in the secondary fractionation (4). The intermediate step (3) is carried out in such a way that not more than 0.8% of the alpha-olefin predominantly contained in the primary fraction or the part thereof subjected to the intermediate step is reacted. The intermediate step is carried out in the presence of 30 wt.-ppm to 200 wt.-ppm of water as reaction moderator and using a strongly acidic ion exchange resin.

The present invention relates to a method for the purification of alkanes, especially methane, wherein an alkane comprising impurities, especially methane, is reacted with an active compound, optionally in the presence of sulfur trioxide, whereby the impurities are removed. The present invention furthermore relates to the use of the active compound and sulfur trioxide in the purification of alkanes, especially methane.

The present invention relates to a method for the purification of alkanes, especially methane, wherein an alkane comprising impurities, especially methane, is reacted with an active compound, optionally in the presence of sulfur trioxide, whereby the impurities are removed. The present invention furthermore relates to the use of the active compound and sulfur trioxide in the purification of alkanes, especially methane.

The present invention relates to a method for the purification of alkanes, especially methane, wherein an alkane comprising impurities, especially methane, is reacted with an active compound, optionally in the presence of sulfur trioxide, whereby the impurities are removed. The present invention furthermore relates to the use of the active compound and sulfur trioxide in the purification of alkanes, especially methane.

A process for preparing a purified benzene composition from a crude hydrocarbon stream containing at least 10% by volume of benzene is provided. The process comprises subjecting the crude hydrocarbon stream and a further recycled benzene containing stream to a solvent-based extraction so as to produce a benzene enriched aromatic stream and a benzene depleted non-aromatic stream, subjecting the benzene enriched aromatic stream to a hydrodesulfurization so as to obtain a desulfurized aromatic stream, subjecting the desulfurized aromatic stream to a distillation producing a purified benzene stream and a further benzene containing stream having a benzene concentration of between less than 100% by weight and the azeotropic benzene concentration, and at least partially recycling the further benzene containing stream.

A process for preparing a purified benzene composition from a crude hydrocarbon stream containing at least 10% by volume of benzene is provided. The process comprises subjecting the crude hydrocarbon stream and a further recycled benzene containing stream to a solvent-based extraction so as to produce a benzene enriched aromatic stream and a benzene depleted non-aromatic stream, subjecting the benzene enriched aromatic stream to a hydrodesulfurization so as to obtain a desulfurized aromatic stream, subjecting the desulfurized aromatic stream to a distillation producing a purified benzene stream and a further benzene containing stream having a benzene concentration of between less than 100% by weight and the azeotropic benzene concentration, and at least partially recycling the further benzene containing stream.