A method for processing pentanes obtained from a DIB unit is disclosed. The process can include separating a first stream containing pentanes obtained from a DIB unit, in a separation column to obtain a second stream comprising iso-pentane and a third stream comprising n-pentane and neo-pentane; and subjecting the third stream to a butane isomerization unit producing a fourth stream containing iso-pentane, n-pentane, and neo-pentane.

A method for processing pentanes obtained from a DIB unit is disclosed. The process can include separating a first stream containing pentanes obtained from a DIB unit, in a separation column to obtain a second stream comprising iso-pentane and a third stream comprising n-pentane and neo-pentane; and subjecting the third stream to a butane isomerization unit producing a fourth stream containing iso-pentane, n-pentane, and neo-pentane.

A dividing wall column is used in an alkylation process flow scheme to fractionate an alkylate reactor effluent to produce an iso-butane-rich stream as a recycle feed for the alkylation reactor while also separating iso-butane, normal butane and alkylate as separate product streams depending on the reactor effluent composition. In an optional embodiment, the scheme may contain propane.

A hydrogenolysis bimetallic supported catalyst comprising a first metal, a second metal, and a zeolitic support; wherein the first metal and the second metal are different; and wherein the first metal and the second metal can each independently be selected from the group consisting of iridium (Ir), platinum (Pt), rhodium (Rh), ruthenium (Ru), palladium (Pd), molybdenum (Mo), tungsten (W), nickel (Ni), and cobalt (Co).

A hydrogenolysis bimetallic supported catalyst comprising a first metal, a second metal, and a zeolitic support; wherein the first metal and the second metal are different; and wherein the first metal and the second metal can each independently be selected from the group consisting of iridium (Ir), platinum (Pt), rhodium (Rh), ruthenium (Ru), palladium (Pd), molybdenum (Mo), tungsten (W), nickel (Ni), and cobalt (Co).

A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.

A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.

Provided is a method for preparing 1-butene and propylene including: supplying a C4 mixture stream to a first hydrogenation reactor to convert 1,3-butadiene into 1-butene; supplying a discharge stream from the first hydrogenation reactor to a first distillation column, supplying a lower discharge stream from the first distillation column including 2-butene and n-butane to a metathesis reactor, and supplying an upper discharge stream from the first distillation column including 1-butene and i-butane to a second distillation column; recovering an upper discharge stream the second distillation column including i-butane and recovering 1-butene from a lower discharge stream from the second distillation column; and producing propylene in the metathesis reactor, supplying a discharge stream from the metathesis reactor to a purification unit to recover propylene, and recycling an unreacted material to the metathesis reactor.

Provided is a method for preparing 1-butene and propylene including: supplying a C4 mixture stream to a first hydrogenation reactor to convert 1,3-butadiene into 1-butene; supplying a discharge stream from the first hydrogenation reactor to a first distillation column, supplying a lower discharge stream from the first distillation column including 2-butene and n-butane to a metathesis reactor, and supplying an upper discharge stream from the first distillation column including 1-butene and i-butane to a second distillation column; recovering an upper discharge stream the second distillation column including i-butane and recovering 1-butene from a lower discharge stream from the second distillation column; and producing propylene in the metathesis reactor, supplying a discharge stream from the metathesis reactor to a purification unit to recover propylene, and recycling an unreacted material to the metathesis reactor.

Systems and methods for producing propylene using an MTBE synthesis raffinate are disclosed. An MTBE synthesis raffinate stream first passes through a molecular sieve to separate n-butane and isobutane from the rest of C.sub.4 hydrocarbons of the MTBE synthesis raffinate. The 1-butene in the rest of C.sub.4 hydrocarbons of the MTBE synthesis raffinate is then isomerized to form 2-butene. Therefore, the concentration of 2-butene in the subsequent propylene production process increases due to the separation of n-butane and isobutane and the isomerization of 1-butene, resulting in an improved reaction rate and reaction efficiency for propylene production.