An integrated process for making propene oxide and an alkyl tert-butyl ether comprises dehydrogenating a feed stream comprising iso-butane to provide a stream comprising iso-butene and hydrogen and separating this stream into a stream consisting essentially of hydrogen and a stream comprising iso-butene; reacting a part or all of the stream comprising iso-butene with an alkanol in the presence of a solid acid catalyst to provide an alkyl tert-butyl ether; reacting a part or all of the stream consisting essentially of hydrogen with oxygen, providing a stream comprising hydrogen peroxide; and reacting a part or all of the stream comprising hydrogen peroxide with propene in the presence of an epoxidation catalyst to provide propene oxide.

An integrated process for making propene oxide and an alkyl tert-butyl ether comprises dehydrogenating a feed stream comprising iso-butane to provide a stream comprising iso-butene and hydrogen and separating this stream into a stream consisting essentially of hydrogen and a stream comprising iso-butene; reacting a part or all of the stream comprising iso-butene with an alkanol in the presence of a solid acid catalyst to provide an alkyl tert-butyl ether; reacting a part or all of the stream consisting essentially of hydrogen with oxygen, providing a stream comprising hydrogen peroxide; and reacting a part or all of the stream comprising hydrogen peroxide with propene in the presence of an epoxidation catalyst to provide propene oxide.

Plasticizers are purified by contact with a coalescing filter to effect removal of ions, metals, monohydric alcohols, and polyhydric alcohols. The resulting purified plasticizer compositions are suitable for use in PVC due to their low levels of impurities that reduce PVC utility.

Plasticizers are purified by contact with a coalescing filter to effect removal of ions, metals, monohydric alcohols, and polyhydric alcohols. The resulting purified plasticizer compositions are suitable for use in PVC due to their low levels of impurities that reduce PVC utility.

In accordance with one or more embodiments of the present disclosure, a process includes introducing a mixture comprising polypropylene carbonate (PPC) polyol, carbon dioxide, propylene oxide, and at least one dibasic ester to a quenching vessel to separate the PPC polyol from the carbon dioxide and the propylene oxide; introducing additional dibasic ester to the separation vessel, thereby separating the carbon dioxide from the propylene oxide and the dibasic ester such that a mixture of propylene oxide and the dibasic ester is formed; and introducing the mixture of propylene oxide and the dibasic ester to a recovery vessel, wherein the propylene oxide is separated from the dibasic ester in the recovery vessel.

In accordance with one or more embodiments of the present disclosure, a process includes introducing a mixture comprising polypropylene carbonate (PPC) polyol, carbon dioxide, propylene oxide, and at least one dibasic ester to a quenching vessel to separate the PPC polyol from the carbon dioxide and the propylene oxide; introducing additional dibasic ester to the separation vessel, thereby separating the carbon dioxide from the propylene oxide and the dibasic ester such that a mixture of propylene oxide and the dibasic ester is formed; and introducing the mixture of propylene oxide and the dibasic ester to a recovery vessel, wherein the propylene oxide is separated from the dibasic ester in the recovery vessel.

The invention relates to a process for removing 5poly(propylene oxide) from propylene oxide, comprising: a) sending a stream comprising propylene oxide and poly(propylene oxide) to a filtration screen having openings with an average diameter of at most 50 μm; and b) sending the filtrate stream resulting from step a) to a membrane 10 having an average pore size of from 0 to 30 nm and recovering a permeate stream from the membrane as a purified propylene oxide stream.

The invention relates to a process for removing 5poly(propylene oxide) from propylene oxide, comprising: a) sending a stream comprising propylene oxide and poly(propylene oxide) to a filtration screen having openings with an average diameter of at most 50 μm; and b) sending the filtrate stream resulting from step a) to a membrane 10 having an average pore size of from 0 to 30 nm and recovering a permeate stream from the membrane as a purified propylene oxide stream.

A method for producing epoxyalkane includes the step of separating, in a separation column, a stream containing epoxyalkane, extractant, and diol. The separation column operates under conditions so as to enable the extractant and the diol to form an azeotrope, and a stream containing extractant and binary azeotrope is extracted from the side-draw of the separation column to liquid-liquid separation. The method can be used for the industrial production of epoxyalkane.

A method for producing epoxyalkane includes the step of separating, in a separation column, a stream containing epoxyalkane, extractant, and diol. The separation column operates under conditions so as to enable the extractant and the diol to form an azeotrope, and a stream containing extractant and binary azeotrope is extracted from the side-draw of the separation column to liquid-liquid separation. The method can be used for the industrial production of epoxyalkane.