C07D317/16

Direct synthesis of cyclic carbonates using choline chloride as catalyst under mild conditions

A method for direct synthesis of cyclic carbonates is achieved by reacting at least one epoxide with carbon dioxide in the presence of a choline catalyst, such as choline chloride, under mild conditions such as a temperature between about 25 C. to 150 C. and a pressure of from about atmospheric to 75 psi (0.52 MPa), in a cyclic carbonate solvent. The choline catalyst may be the only catalyst used, and a co-catalyst or hydrogen bond donor is not necessary. The concentration of choline catalyst in the solvent ranges from about 0.5 mol % to about 10 mol %, based on the epoxide.

FLUORORESIN

A fluororesin that includes a residue unit represented by formula (1), and a terminal group represented by formula (2); and a fluororesin that includes a residue unit represented by formula (1) and has a transmittance of 50% or more measured at an optical path length of 10 mm and a wavelength of 275 nm when dissolved in perfluorohexane to produce a 10 wt % perfluorohexane solution. In formula (1): Rf.sub.1, Rf.sub.2, Rf.sub.3, and Rf.sub.4 each independently represent one selected from the group consisting of fluorine atoms, C1-7 linear perfluoroalkyl groups, C3-7 branched perfluoroalkyl groups, or C3-7 cyclic perfluoroalkyl groups; the perfluoroalkyl groups may have an etheric oxygen atom; Rf.sub.1, Rf.sub.2, Rf.sub.3, and Rf.sub.4 may bond to each other to form a ring having 4 to 8 carbon atoms; and the ring may include an etheric oxygen atom. In formula (2), i is an integer of 3-20.

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ELECTROLYTE AND BATTERY CELL, BATTERY, AND ELECTRICAL DEVICE CONTAINING SAME

An electrolyte containing a solvent including at least one compounds of formula I, wherein A.sub.1 is an oxygen atom or a single bond, A.sub.2 is a single bond or CHR.sub.4, R.sub.1 and R.sub.2 are each independently a hydrogen atom, C1-6 alkyls or a C1-6 fluoroalkyls, R.sub.3 and R.sub.4 are each independently a hydrogen atom, a fluorine atom, C1-6 alkyls or C1-6 fluoroalkyls, A1 and A2 cannot both be single bonds simultaneously, and only one of R.sub.1 to R.sub.4 includes a fluorine atom is described. The electrolyte can make a metal negative electrode secondary battery have good cycling performance and good discharge capacity retention at low temperature.

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ELECTROLYTE AND BATTERY CELL, BATTERY, AND ELECTRICAL DEVICE CONTAINING SAME

An electrolyte containing a solvent including at least one compounds of formula I, wherein A.sub.1 is an oxygen atom or a single bond, A.sub.2 is a single bond or CHR.sub.4, R.sub.1 and R.sub.2 are each independently a hydrogen atom, C1-6 alkyls or a C1-6 fluoroalkyls, R.sub.3 and R.sub.4 are each independently a hydrogen atom, a fluorine atom, C1-6 alkyls or C1-6 fluoroalkyls, A1 and A2 cannot both be single bonds simultaneously, and only one of R.sub.1 to R.sub.4 includes a fluorine atom is described. The electrolyte can make a metal negative electrode secondary battery have good cycling performance and good discharge capacity retention at low temperature.

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CONTINUOUS RECTIFICATION APPARATUS FOR PRODUCING ELECTRONIC-GRADE PROPYLENE CARBONATE

Provided is a continuous rectification apparatus for producing electronic-grade propylene carbonate, including a light component removal column and a heavy component removal column. The light component removal column is connected to a first feeding pipe. The top of the light component removal column is connected to a first condensing box. The first condensing box is connected to a first reflux tank. The first reflux tank is connected to a first conveying pump. The first conveying pump is connected to a first reflux pipe. The bottom of the light component removal column is connected to a feeding pump. The feeding pump is connected to a second feeding pipe. The second feeding pipe is connected to the heavy component removal column. The top of the heavy component removal column is connected to a second condensing box. The second condensing box is connected to one side of a second reflux tank.

METHODS FOR TOTAL SYNTHESIS OF RESOLVIN E1
20180297925 · 2018-10-18 ·

Methods for total chemical synthesis of Resolvin E1 (RvE1) include Wittig reaction of two compounds having hydroxyl protecting group in the presence of a strong base, removal of the hydroxyl-protecting groups with a deprotecting reagent to produce a compound having an ester group, and hydrolysis of the ester group to obtain RvE1

METHODS FOR TOTAL SYNTHESIS OF RESOLVIN E1
20180297925 · 2018-10-18 ·

Methods for total chemical synthesis of Resolvin E1 (RvE1) include Wittig reaction of two compounds having hydroxyl protecting group in the presence of a strong base, removal of the hydroxyl-protecting groups with a deprotecting reagent to produce a compound having an ester group, and hydrolysis of the ester group to obtain RvE1

SALT AND PHOTORESIST COMPOSITION CONTAINING THE SAME

A salt represented by the formula (I).

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wherein Z.sup.+, Q.sup.1, Q.sup.2, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, Z, X.sup.1, X.sup.2, X.sup.a, X.sup.b, L.sup.1, L.sup.2, L.sup.3 and L.sup.4 are defined in the specification.

Piperidine derivative, liquid crystal composition and liquid crystal display device

To provide a compound having an effect for preventing photolysis of a liquid crystal composition, and having a high solubility in the liquid crystal composition, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. The compound is represented by formula (1), the liquid crystal composition contains the compound, and the liquid crystal display device includes the composition. ##STR00001## In formula (1), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or alkyl having 1 to 4 carbons; ring A.sup.1 and ring A.sup.2 are independently 1,4-cyclohexylene, 1,4-phenylene or the like; Z.sup.1, Z.sup.2 and Z.sup.3 are independently a single bond, alkylene or the like; and n is 0, 1 or 2.

Piperidine derivative, liquid crystal composition and liquid crystal display device

To provide a compound having an effect for preventing photolysis of a liquid crystal composition, and having a high solubility in the liquid crystal composition, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. The compound is represented by formula (1), the liquid crystal composition contains the compound, and the liquid crystal display device includes the composition. ##STR00001## In formula (1), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or alkyl having 1 to 4 carbons; ring A.sup.1 and ring A.sup.2 are independently 1,4-cyclohexylene, 1,4-phenylene or the like; Z.sup.1, Z.sup.2 and Z.sup.3 are independently a single bond, alkylene or the like; and n is 0, 1 or 2.