Patent classifications
C07F9/5345
Fluorescent rare earth complex and security medium using the same
The embodiments provide a fluorescent rare earth complex having strong emission intensity and excellent durability, and also provide a security medium using the complex. The rare earth complex according to the embodiment comprises a rare earth ion, a diphosphine dioxide ligand and a β-diketone ligand wherein two phosphorus atoms contained in the diphosphine dioxide ligand individually have substituents different from each other.
RARE EARTH COMPLEX
Disclosed is a rare earth complex including: one or a plurality of rare earth ions; and a ligand forming a coordinate bond with the rare earth ions. At least a part of the rare earth ions are at least one kind selected from the group consisting of lutetium(III) ions, yttrium(III) ions, and gadolinium(III) ions. The ligand includes a residue obtained by removing one or more hydrogen atoms from a fluorescent condensed polycyclic aromatic compound.
RARE EARTH COMPLEX, RARE EARTH COMPLEX SOLUTION, LUMINESCENT MOLDED ARTICLE, METHOD FOR PRODUCING LUMINESCENT PRODUCT, LUMINESCENT SHEET, AND VINYL GREENHOUSE FOR AGRICULTURE
Disclosed is a rare earth complex having a rare earth ion and a phosphine oxide ligand that is coordinated with the rare earth ion and is represented by the following formula (I):
##STR00001## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 each independently represent an alkyl group which may have a substituent.
ANTI-CANCER GOLD COMPOUNDS
A compound according to Formula (I), or a pharmaceutically acceptable salt thereof:
##STR00001##
wherein R.sup.1 and R.sup.2 are each independently selected from optionally substituted C.sub.1-6-alkyl and optionally substituted aryl; R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are each independently selected from the group consisting of H, halo, optionally substituted C.sub.1-6-alkyl, and optionally substituted C.sub.1-6 alkoxy; and R.sup.7 is a phosphorus containing moiety, wherein a phosphorus atom is bonded to Au.
FLUORESCENT RARE EARTH COMPLEX AND SECURITY MEDIUM USING THE SAME
The embodiments provide a fluorescent rare earth complex having strong emission intensity and excellent durability, and also provide a security medium using the complex. The rare earth complex according to the embodiment comprises a rare earth ion, a diphosphine dioxide ligand and a β-diketone ligand wherein two phosphorus atoms contained in the diphosphine dioxide ligand individually have substituents different from each other.
Fluorescent Particles, Inspection Device Using Fluorescent Particles For Visualizing and Inspecting Motion/Movement Of Fluid In Locations Where Fluid Is Present, And Inspection Method Using Fluorescent Particles For Visualizing and Inspecting Motion/Movement Of Fluid In Locations Where Fluid Is Present
[Problem] To provide: fluorescent particles that are used to create a fluorescent material for coating an object in the vicinity of a fluid, that move regularly in the fluid while suppressing halation generated by the objects, and that enable the motion/movement of the fluid to be sharply visualized; an inspection device; and an inspection method.
[Solution] Substantially spherical fluorescent particles comprising a mixture containing at least one fluorescent material and a synthetic resin, wherein: the fluorescent material is excited by any purple visible light and UV rays having a wave-length of 290-405 nm, and emits visible light having a peak wavelength within the range of 410-620 nm; and the fluorescent particles have diameters of 100 nm to 1 mm and are distinguishable from bubbles and/or foreign bodies in the fluid when irradiated with the light.
RARE EARTH COMPOUND, PHOSPHINE OXIDE COMPOUND, AND LUMINESCENT BODY
A rare earth compound including: one or a plurality of rare earth ions; and a ligand coordinated with the rare earth ion and having a condensed polycyclic aromatic group. At least part of the rare earth ions is a terbium(III) ion. The condensed polycyclic aromatic group is a residue formed by removing a hydrogen atom bonded to a condensed aromatic ring in formula (1) below from a condensed polycyclic aromatic compound represented by the following formula (1). Also disclosed is a luminescent body including the rare earth compound.
##STR00001##
PHOSPHINE OXIDE GROUP-CONTAINED TRANSITION METAL COMPLEX, AND POLYMER, MIXTURE, COMPOSITION, AND ORGANIC ELECTRONIC DEVICE THEREOF
A phosphine oxide group-contained transition metal complex represented by chemical formula (1), and a polymer, a mixture, a composition, and an organic electronic device.
PHOSPHINE OXIDE COMPOUND, RARE EARTH COMPLEX, AND LIGHT-EMITTING MATERIAL
A phosphine oxide compound represented by the following formula (I) and a rare earth complex containing the same are disclosed:
##STR00001## wherein n represents an integer of 3 or more, Ar.sup.1 represents an n-valent aromatic group, L represents a divalent linker group, and Ar.sup.2 and Ar.sup.3 each independently represent a monovalent aromatic groups.
FLUORESCENT RARE EARTH COMPLEX AND SECURITY MEDIUM USING THE SAME
The embodiments provide a fluorescent rare earth complex having strong emission intensity and excellent durability, and also provide a security medium using the complex. The rare earth complex according to the embodiment comprises a rare earth ion, a diphosphine dioxide ligand and a -diketone ligand wherein two phosphorus atoms contained in the diphosphine dioxide ligand individually have substituents different from each other.