C07F9/5463

ORGANIC IODINE REMOVER AND ORGANIC IODINE REMOVING APPARATUS

An organic iodine remover is a remover for removing organic iodine and is a substance composed of a cation and an anion, and the cation (for example, a phosphonium cation, an ammonium cation, or a sulfonium cation) has a molecular structure in which an electron donating group (for example, a phosphino group, an amino group, a sulfanyl group, a hydroxy group, or an alkoxy group) is bonded to a phosphorus atom, a nitrogen atom or a sulfur atom. An organic iodine removing apparatus includes: a vessel into which the organic iodine remover for removing the organic iodine is charged; and introduction pipes through which a fluid containing organic iodine is introduced into the organic iodine remover.

X-Ray Scintillators, Metal Halide Hybrids, Devices, and Methods
20230132026 · 2023-04-27 ·

Methods of scintillation, scintillation devices, and metal halide hybrids that may be used as X-ray scintillators. The metal halide hybrids may include organic metal halide hybrids, inorganic metal halide hybrids, or organic-inorganic metal halide hybrids. The metal halide hybrids may have a 0D structure. The metal halide hybrids may be in the form of one or more discrete crystals.

IONIC LIQUIDS CONTAINING QUATERNARY AMMONIUM AND PHOSPHONIUM CATIONS, AND THEIR USE AS ENVIRONMENTALLY FRIENDLY LUBRICANT ADDITIVES
20220033423 · 2022-02-03 ·

An ionic liquid composition having the following generic structural formula:

##STR00001##

wherein Z is N or P, and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from hydrogen atom and hydrocarbon groups having one to four carbon atoms with optional interconnection to form a cyclic group that includes Z, and wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are all hydrocarbon groups when Z is P, and X.sup.− is a phosphorus-containing or carboxylate anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base lubricant, wherein the ionic liquid is dissolved in the base lubricant. Further described are methods for applying the ionic liquid or lubricant composition onto a mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.

Ionic liquids containing quaternary ammonium and phosphonium cations, and their use as environmentally friendly lubricant additives
11760766 · 2023-09-19 · ·

An ionic liquid composition having the following generic structural formula: ##STR00001##
wherein Z is N or P, and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from hydrogen atom and hydrocarbon groups having one to four carbon atoms with optional interconnection to form a cyclic group that includes Z, and wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are all hydrocarbon groups when Z is P, and X.sup.− is a phosphorus-containing or carboxylate anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base lubricant, wherein the ionic liquid is dissolved in the base lubricant. Further described are methods for applying the ionic liquid or lubricant composition onto a mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.

A GOLD(III) COMPLEX, A CONJUGATE OF THE GOLD(III) COMPLEX, A PHARMACEUTICAL COMPOSITION COMPRISING THE GOLD(III) COMPLEX AND USES AND A PROCESS FOR PREPARING THE GOLD(III) COMPLEX

A gold(III) complex, a conjugate of the gold(iII) complex, a pharmaceutical composition comprising the gold(III) complex and uses and a process for preparing the gold(III) complex. The complex comprises a group of (ŜC)-cyclometallated gold(III) complexes containing a 1,1-dithio ligand, which exhibit antibacterial activity against multiresistant microorganisms or against biofilm activity or biofilm disruption. The gold(III) complex has efficacy against a variety of microorganisms and low toxicity.

RESIN COMPOSITION, CURED PRODUCT THEREOF, FIBRE-REINFORCED PLASTIC, AND FIBRE-REINFORCED PLASTIC FLAMEPROOFING METHOD

Provided is a resin composition that is capable of producing a cured product having excellent environmental suitability, high strength, and excellent flame retardancy, and that is suitably usable as a matrix resin for fiber-reinforced plastics. A resin composition contains (A) an epoxy resin, (B) a cyanate resin, (C) an aromatic amine curing agent that is liquid at 25° C., and (D) a phosphorus-containing compound represented by formula (1). Preferably, in formula (1), R.sup.1 and R.sup.2 each independently represent an alkyl group or an aryl group, and X and Y are an oxygen atom.

Gold(III) complex, a conjugate of the gold(III) complex, a pharmaceutical composition comprising the gold(III) complex and uses and a process for preparing the gold(III) complex

A gold(III) complex, a conjugate of the gold(iII) complex, a pharmaceutical composition comprising the gold(III) complex and uses and a process for preparing the gold(III) complex. The complex comprises a group of (S{circumflex over ()}C)-cyclometallated gold(III) complexes containing a 1,1-dithio ligand, which exhibit antibacterial activity against multiresistant microorganisms or against biofilm activity or biofilm disruption. The gold(III) complex has efficacy against a variety of microorganisms and low toxicity.

Polymerization of silyl- and fluoro-containing monomers

Condensation of fluoro-substituted and silyl-substituted monomers provides polymers suitable for use, e.g., as engineering polymers. A monomer composition is condensed in the presence of a bifluoride or poly(hydrogen fluoride) fluoride salt. The monomer composition contains a compound of formula F-X-F and a compound of formula (R.sup.1).sub.3SiZSi(R.sup.1).sub.3, and forms an alternating X-Z polymer chain and a silyl fluoride byproduct. X has the formula -A(-R.sup.2-A)n-; each A is SO.sub.2, C(O), or Het; R.sup.2 is an organic moiety; n is 0 or 1; Het is an aromatic nitrogen heterocycle; Z has the formula -L-R.sup.3-L-; each L is O, S, or N(R.sup.4); and each R.sup.3 is an organic moiety, and R.sup.4 comprises H or an organic moiety.

Resin composition, cured product thereof, fibre-reinforced plastic, and fibre-reinforced plastic flameproofing method

Provided is a resin composition that is capable of producing a cured product having excellent environmental suitability, high strength, and excellent flame retardancy, and that is suitably usable as a matrix resin for fiber-reinforced plastics. A resin composition contains (A) an epoxy resin, (B) a cyanate resin, (C) an aromatic amine curing agent that is liquid at 25 C., and (D) a phosphorus-containing compound represented by formula (1). Preferably, in formula (1), R.sup.1 and R.sup.2 each independently represent an alkyl group or an aryl group, and X and Y are an oxygen atom.

Acid-resistant base and/or radical generator, and curable resin composition containing said base and/or radical generator

The present invention relates to a compound represented by the general formula (A), a base- and/or radical-generating agent comprising the compound, and so on. ##STR00001##
In the formula, four pieces of R.sup.1 each independently represents a hydrogen atom or a fluorine atom; four pieces of R.sup.2 each independently represent a fluorine atom or a trifluoromethyl group; R.sup.3, R.sup.6, R.sup.7 and R.sup.10 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms; R.sup.4 and R.sup.5 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, or R.sup.4 and R.sup.5 are bonded to each other to represent an alkylene group having 2 to 4 carbon atoms; and R.sup.8 and R.sup.9 each independently represent a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, or an aryl group having 6 to 14 carbon atoms and optionally having a substituent selected from the group consisting of an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkylthio group having 1 to 6 carbon atoms, a dialkylamino group having 2 to 12 carbon atoms, a halogen atom, and a nitro group, or R.sup.8 and R.sup.9 are bonded to each other to represent an alkylene group having 2 to 4 carbon atoms; provided that two or three of the eight groups R.sup.3 to R.sup.10 are each a hydrogen atom, and, in a case where two of the eight groups are each a hydrogen atom, then three to six of the remaining groups are each an alkyl group having 1 to 12 carbon atoms, and, in a case where three of the eight groups are each a hydrogen atom, then four or five of the remaining groups are each an alkyl group having 1 to 12 carbon atoms.