Provided is a resin molded body production method that enables production of a resin molded body in which mechanical strength is good, anisotropy of physical properties is low, and little warpage is developed. This production method is for a resin molded body containing a thermoplastic resin (A) and a cellulose nanofiber (B), the production method including: a step for preparing a main supply material (a1) containing the thermoplastic resin (A) and the cellulose nanofiber (B) and an auxiliary supply material (a2) that is a product of melting treatment of the main supply material (a1); a resin composition formation step for obtaining a resin composition (b) by melting and mixing of the main supply material (a1) and the auxiliary supply material (a2); and a step for obtaining the resin molded body by molding the resin composition (b).

A ply fibrous product comprises at least one ply selected from a nonwoven ply and a tissue paper ply, wherein the at least one ply selected from a nonwoven ply and a tissue paper ply comprises cellulosic fibers comprising an organic polycarboxylic acid and wherein the organic polycarboxylic acid has at least one carboxyl group covalently bound to the cellulosic fibers and at least one free carboxyl group. Due to the presence of covalent chemical bonds between a carboxyl group of the polycarboxylic acid and hydroxy groups of the cellulosic fibers present in all substrates, the ply fibrous products display a long-lasting acidic pH even after having been rinsed with water. In some embodiments a long-lasting acidic pH may be achieved in the nonwovens treated with an organic polycarboxylic acid even after washing with a washing detergent.

A fibrous cellulose having an excellent resin reinforcing effect, a method for manufacturing the fibrous cellulose, and a resin composition having high strength. The fibrous cellulose is microfiber cellulose having an average fiber diameter of 1 μm or more, and is hydrophobically modified. The method for manufacturing fibrous cellulose includes defibrating raw material fiber to obtain microfiber cellulose with an average fiber diameter of 1 μm or more, and hydrophobically modifying the microfiber cellulose. Further, the resin composition contains the fibrous cellulose and resin.

A fibrous cellulose having an excellent resin reinforcing effect, a method for manufacturing the fibrous cellulose, and a resin composition having high strength. The fibrous cellulose is microfiber cellulose having an average fiber diameter of 1 μm or more, and is hydrophobically modified. The method for manufacturing fibrous cellulose includes defibrating raw material fiber to obtain microfiber cellulose with an average fiber diameter of 1 μm or more, and hydrophobically modifying the microfiber cellulose. Further, the resin composition contains the fibrous cellulose and resin.

A fibrous cellulose has an average fiber width of 0.1 .Math.m or more and has a part or all of hydroxyl groups replaced with carbamate groups, in which a replacement ratio with the carbamate group is 1.0 mmol/g or more, and a fine ratio is 30% or more. A fibrous cellulose composite resin contains a fibrous cellulose and a resin, and the above fibrous cellulose In manufacturing fibrous cellulose, a cellulose raw material and urea or the like are subjected to a heat treatment to replace a part or all of hydroxyl groups of the cellulose raw material with carbamate groups, defibration is performed within a range in which an average fiber width is 0.1 .Math.m or more, the heat treatment is performed such that a replacement ratio with the carbamate group is 1.0 mmol/g or more, and the defibration is performed until a fine ratio reaches 30% or more.

A fibrous cellulose has an average fiber width of 0.1 .Math.m or more and has a part or all of hydroxyl groups replaced with carbamate groups, in which a replacement ratio with the carbamate group is 1.0 mmol/g or more, and a fine ratio is 30% or more. A fibrous cellulose composite resin contains a fibrous cellulose and a resin, and the above fibrous cellulose In manufacturing fibrous cellulose, a cellulose raw material and urea or the like are subjected to a heat treatment to replace a part or all of hydroxyl groups of the cellulose raw material with carbamate groups, defibration is performed within a range in which an average fiber width is 0.1 .Math.m or more, the heat treatment is performed such that a replacement ratio with the carbamate group is 1.0 mmol/g or more, and the defibration is performed until a fine ratio reaches 30% or more.

Provided is a resin molded body production method that enables production of a resin molded body in which mechanical strength is good, anisotropy of physical properties is low, and little warpage is developed. This production method is for a resin molded body containing a thermoplastic resin (A) and a cellulose nanofiber (B), the production method including: a step for preparing a main supply material (a1) containing the thermoplastic resin (A) and the cellulose nanofiber (B) and an auxiliary supply material (a2) that is a product of melting treatment of the main supply material (a1); a resin composition formation step for obtaining a resin composition (b) by melting and mixing of the main supply material (a1) and the auxiliary supply material (a2); and a step for obtaining the resin molded body by molding the resin composition (b).

A method of treating wood with an organic phosphonate salt in a liquid phase to chemically modify its surface and thus provide protection from microorganisms. The organic phosphonate salts are of Formula III

##STR00001##

wherein R1 is a hydrogen radical or an alkyl or aryl radical having 1 to 20 carbon atoms and R2 is a cation selected from the group of NH4+, H+, Li+, Na+, K+, Rb+, Cs+, Fr+, Cu+, Ag+, substituted or unsubstituted ammonium, phosphonium, and sulfonium, methylpyrrolidinium, isothiazolium, isoxazolium, oxazolium, pyrrolium, thiophenium, pyridinium, pyridazinium, pyrimidinium, pyrazinium, imidazolium, pyrazolium, thiazolium, oxazolium, 1-ethyl-3-methylimidazolium, and triazolium, or a mixture thereof, said method preferably comprising using one or more salt compounds having formula III. Products comprising a raw material having been treated according to the method with one or more organic salts of formula III are also disclosed.

A method of treating wood with an organic phosphonate salt in a liquid phase to chemically modify its surface and thus provide protection from microorganisms. The organic phosphonate salts are of Formula III

##STR00001##

wherein R1 is a hydrogen radical or an alkyl or aryl radical having 1 to 20 carbon atoms and R2 is a cation selected from the group of NH4+, H+, Li+, Na+, K+, Rb+, Cs+, Fr+, Cu+, Ag+, substituted or unsubstituted ammonium, phosphonium, and sulfonium, methylpyrrolidinium, isothiazolium, isoxazolium, oxazolium, pyrrolium, thiophenium, pyridinium, pyridazinium, pyrimidinium, pyrazinium, imidazolium, pyrazolium, thiazolium, oxazolium, 1-ethyl-3-methylimidazolium, and triazolium, or a mixture thereof, said method preferably comprising using one or more salt compounds having formula III. Products comprising a raw material having been treated according to the method with one or more organic salts of formula III are also disclosed.

A method for preparing stably dispersed cellulose nanofibers comprises the following steps: 1) mixing cellulose and an organic solvent, the percentage of the cellulose being 1% to 15% in weight; 2) adding an esterification agent into the resultant mixture of step 1), the molar ratio of the esterification agent to the cellulose being from 1:0.1 to 4; and 3) physically breaking the resultant mixture of step 2) until a suspension liquid with stably dispersed cellulose nanofibers of 2-1000 nm in diameter and 10-100 μm in length is obtained, an esterification reaction of hydroxyl group(s) on the surface of cellulose fibers occurring at the time of the breaking. Also disclosed are dispersed cellulose nanofibers with improved compatibility to the matrix than the untreated cellulose and an improved strength of the composite materials.