Patent classifications
C08F10/02
CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.
CIRCULAR ECONOMY FOR PLASTIC WASTE TO POLYETHYLENE AND LUBRICATING OIL VIA CRUDE AND ISOMERIZATION DEWAXING UNITS
Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. In one embodiment, the process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. The naphtha/diesel fraction is passed to a crude unit distillation column in a refinery where a straight run naphtha (C.sub.5-C.sub.8) fraction or a propane/butane (C.sub.3-C.sub.4) fraction is recovered. The straight run naphtha fraction (C.sub.5-C.sub.8) or the propane/butane (C.sub.3-C.sub.4) fraction is passed to a steam cracker for ethylene production. The heavy fraction from the pyrolysis unit can also be passed to an isomerization dewaxing unit to produce a base oil.
HEATED GAS STREAM FOR REDUCING OLIGOMER AND WAX BUILD UP IN RECYCLE COOLERS
The present invention relates to a process for reducing low molecular weight oligomers and wax build-up in one or more recycle coolers in a high pressure polymerization process by means of a gas stream, which is heated and/or free of wax, introduced into the one or more recycle coolers and the use of a heated gas stream for removing low molecular weight oligomers and wax build-up in one or more recycle coolers in a high pressure polymerization process.
HEATED GAS STREAM FOR REDUCING OLIGOMER AND WAX BUILD UP IN RECYCLE COOLERS
The present invention relates to a process for reducing low molecular weight oligomers and wax build-up in one or more recycle coolers in a high pressure polymerization process by means of a gas stream, which is heated and/or free of wax, introduced into the one or more recycle coolers and the use of a heated gas stream for removing low molecular weight oligomers and wax build-up in one or more recycle coolers in a high pressure polymerization process.
HEATED GAS STREAM FOR REDUCING OLIGOMER AND WAX BUILD UP IN RECYCLE COOLERS
The present invention relates to a process for reducing low molecular weight oligomers and wax build-up in one or more recycle coolers in a high pressure polymerization process by means of a gas stream, which is heated and/or free of wax, introduced into the one or more recycle coolers and the use of a heated gas stream for removing low molecular weight oligomers and wax build-up in one or more recycle coolers in a high pressure polymerization process.
METHOD FOR RECYCLING POLYVINYL CHLORIDE (PVC) TO PRODUCE HIGH DENSITY POLYETHYLENE (HDPE)
Disclosed herein is a process to convert PVC plastic into a dechlorinated polymer, such as high density polyethylene, while substantially avoiding carbonization. The process also facilitates Cl recovery and/or reintroducing the dechlorinated plastic into product streams. In some embodiments, the process comprises heating a mixture of PVC and a catalyst and/or a base in a solvent, optionally in the presence of hydrogen gas.
METHOD FOR RECYCLING POLYVINYL CHLORIDE (PVC) TO PRODUCE HIGH DENSITY POLYETHYLENE (HDPE)
Disclosed herein is a process to convert PVC plastic into a dechlorinated polymer, such as high density polyethylene, while substantially avoiding carbonization. The process also facilitates Cl recovery and/or reintroducing the dechlorinated plastic into product streams. In some embodiments, the process comprises heating a mixture of PVC and a catalyst and/or a base in a solvent, optionally in the presence of hydrogen gas.
Deactivation methods for active components from gas phase polyolefin polymerization processes
Provided herein are methods and systems for at least partially deactivating at least one component of a reactor effluent from gas phase polyolefin polymerization processes utilizing at least one glycol.
Deactivation methods for active components from gas phase polyolefin polymerization processes
Provided herein are methods and systems for at least partially deactivating at least one component of a reactor effluent from gas phase polyolefin polymerization processes utilizing at least one glycol.
Cable jacket composition
The present invention relates to a cable jacket composition comprising a multimodal olefin copolymer, wherein said olefin copolymer has a density of 0.935-0.960 g/cm3 and MFR2 of 1.5-10.0 g/10 min and comprises a bimodal polymer mixture of a low molecular weight homo- or copolymer and a high molecular weight copolymer wherein the composition has ESCR of at least 2000 hours and wherein the numerical values of cable wear index and composition MFR2 (g/10 min) follow the correlation: Wear index<15.500+0.900*composition MFR2. The invention further relates to the process for preparing said composition and its use as outer jacket layer for a cable, preferably a communication cable, most preferably a fiber optic cable.