A method for producing an iodine-containing compound includes reacting a halogen-containing organic iodine compound and a compound containing a reactive carbon-carbon double bond in the presence of a compound of Formula (21) or Formula (22). Each of R.sup.21, R.sup.23 and R.sup.24 represents a hydrogen atom, an iodine atom, or an organic group having from 1 to 20 carbon atoms; R.sup.22 represents a hydrogen atom, an iodine atom, an organic group having from 1 to 20 carbon atoms, or a boron-containing group; R.sup.25 represents a hydrogen atom, an iodine atom, an organic group having from 1 to 20 carbon atoms, or a silicon-containing group; and each of A.sup.1 and A.sup.2 represents a hydrogen atom, a chlorine atom, a bromine atom, or an iodine atom.

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The invention relates to alkenyl(perfluoroalkyl)phosphinic acids, to the preparation and intermediates thereof, to the use thereof as monomers for the preparation of oligomers and/or polymers, to the corresponding oligomers/polymers, to the corresponding support materials comprising the oligomers/polymers, and to the use thereof as ion exchangers, as catalysts or extraction medium and corresponding salts thereof.

Described herein is method of making branched perfluorinated compounds, specifically (CF.sub.3).sub.2CFCF(CF.sub.3)OCF(CF.sub.3)C(═O)F and (CF.sub.3).sub.2CFCF(CF.sub.3)OCF═CF.sub.2. Also disclosed herein is a fluoropolymer derived from the branched perfluorovinyl ether monomer and methods of making the fluoropolymer.

Provided is a water repellent oil repellent agent composition capable of producing an article having excellent oil repellency. A water repellent oil repellent agent composition containing a fluorine-containing polymer comprising a unit based on a monomer (a) shown below and a unit based on a monomer (b) shown below.

Monomer (a): a compound represented by CH.sub.2═CH—[CH.sub.2CH.sub.2].sub.p—[CF.sub.2CF.sub.2].sub.q—[OCF.sub.2CF(CF.sub.3)].sub.r—O—C.sub.3F.sub.7
In the formula, p represents an integer of 0 to 4, q represents an integer of 1 to 4, and r represents an integer of 1 to 4.
Monomer (b): another monomer that is copolymerizable with the monomer (a).

A process for the preparation of perhaloacyl peroxides from perhaloacyl halides which is performed in the presence of a hydrofluoroether as the solvent.

The invention relates to alkenyl(perfluoroalkyl)phosphinic acids, to the preparation and intermediates thereof, to the use thereof as monomers for the preparation of oligomers and/or polymers, to the corresponding oligomers/polymers, to the corresponding support materials comprising the oligomers/polymers, and to the use thereof as ion exchangers, as catalysts or extraction medium and corresponding salts thereof.

The invention relates to alkenyl(perfluoroalkyl)phosphinic acids, to the preparation and intermediates thereof, to the use thereof as monomers for the preparation of oligomers and/or polymers, to the corresponding oligomers/polymers, to the corresponding support materials comprising the oligomers/polymers, and to the use thereof as ion exchangers, as catalysts or extraction medium and corresponding salts thereof.

The present invention provides a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell; wherein the core comprises from 5 to 90 weight percent structural units of a fluoroalkylated monomer, and 2) less than 0.09 weight percent structural units of a phosphorus acid monomer; and wherein the shell comprises from 0.1 to 5 weight percent of itaconic acid or a phosphorus acid monomer, based on the weight of the shell. The present invention addresses a need in the art by providing a way of selectively concentrating fluoroalkyl functionality into polymer particles with acorn morphology, thereby providing an improvement in dirt pick-up resistance of the subsequent coating.

The present disclosure relates to a passivation layer comprising a photocrosslinked fluoropolymer and a process for forming the layer. Passivation layers comprising the crosslinked fluoropolymer have low dielectric constants, low water absorptivity and are able to be photoimaged so as to provide the very fine features needed for modern electronic equipment.

The present invention provides a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell; wherein the core comprises from 5 to 90 weight percent structural units of a fluoroalkylated monomer, and 2) less than 0.09 weight percent structural units of a phosphorus acid monomer; and wherein the shell comprises from 0.1 to 5 weight percent of itaconic acid or a phosphorus acid monomer, based on the weight of the shell. The present invention addresses a need in the art by providing a way of selectively concentrating fluoroalkyl functionality into polymer particles with acorn morphology, thereby providing an improvement in dirt pick-up resistance of the subsequent coating.