Patent classifications
C08F116/06
WATER-SOLUBLE FILM, AND CHEMICAL AGENTS-ENCLOSING PACKAGING CAPSULE MATERIAL HAVING SAME
Provided is a water-soluble film for molding a packaging capsule which is capable of enclosing chemical agents especially a detergent, has a robust property that prevents leakage of the detergent through suitable thickness and strength and an easy-processing property that keeps robustness not to make a drawn portion break in mold-processing such as deep drawing, further has a soluble resistance that does not make the chemical agent elute within 30 seconds in water at 20° C. and a complete-solubility property within a short period of time in dish-washing and clothes-washing, also has sufficient solubility and complete-solubility properties for film portions around the perimeter edge pasted with a water-soluble film for a top, and exhibits a strong-sealing property to have a temporal stability.
A water-soluble film comprises one or more kinds of anion-group-modified polyvinyl alcohols including repeating units from a fatty acid vinyl ester comonomer and anion-group-containing repeating units, in which a degree of saponification thereof is set from 91 mol% or more to 99 mol% or less and a degree of modification by anion groups is set from 1.0 mol% or more to 6.0 mol% or less so that an amount of anion-group modification is set from 1.0 mol% or more to 3.5 mo%l or less to a total amount of the anion-group-modified polyvinyl alcohols, and are formed by including less than 45 parts by mass of a plasticizer per 100 parts by mass of a total amount of the anion-group-modified polyvinyl alcohols, and have a tensile modulus of 100 MPa or less.
WATER-SOLUBLE FILM, AND CHEMICAL AGENTS-ENCLOSING PACKAGING CAPSULE MATERIAL HAVING SAME
Provided is a water-soluble film for molding a packaging capsule which is capable of enclosing chemical agents especially a detergent, has a robust property that prevents leakage of the detergent through suitable thickness and strength and an easy-processing property that keeps robustness not to make a drawn portion break in mold-processing such as deep drawing, further has a soluble resistance that does not make the chemical agent elute within 30 seconds in water at 20° C. and a complete-solubility property within a short period of time in dish-washing and clothes-washing, also has sufficient solubility and complete-solubility properties for film portions around the perimeter edge pasted with a water-soluble film for a top, and exhibits a strong-sealing property to have a temporal stability.
A water-soluble film comprises one or more kinds of anion-group-modified polyvinyl alcohols including repeating units from a fatty acid vinyl ester comonomer and anion-group-containing repeating units, in which a degree of saponification thereof is set from 91 mol% or more to 99 mol% or less and a degree of modification by anion groups is set from 1.0 mol% or more to 6.0 mol% or less so that an amount of anion-group modification is set from 1.0 mol% or more to 3.5 mo%l or less to a total amount of the anion-group-modified polyvinyl alcohols, and are formed by including less than 45 parts by mass of a plasticizer per 100 parts by mass of a total amount of the anion-group-modified polyvinyl alcohols, and have a tensile modulus of 100 MPa or less.
Radiopaque polymers
A hydrophilic polymer comprising pendent groups of the formula I: Wherein: W is independently selected from —OH, —COOH, —SO.sub.3H, —OPO.sub.3H, —O—(C.sub.1-4alkyl), —O—(C.sub.1-4alkyl)OH, —O—(C.sub.1-4alkyl)R.sup.2, —O—(C.sub.2H.sub.5O).sub.qR.sup.1—(C═O)—O—C.sub.1-4alkyl and —O—(C═O)C.sub.1-4alkyl; or a group —BZ; wherein —OH, COOH, O—PO.sub.3H and SO.sub.3H maybe in the form of a pharmaceutically acceptable salt; wherein: B is a bond, or a straight branched alkanediyl, oxyalkylene, alkylene oxaalkylene, or alkylene (oligooxalkylene) group, optionally containing one or more fluorine substituents; and Z is an ammonium, phosphonium, or sulphonium phosphate or phosphonate ester zwitterionic group; X is either a bond or a linking group having 1 to 8 carbons and optionally 1 to 4 heteroatoms selected from O, N and S; G is a coupling group through which the group of the formula I is coupled to the polymer and is selected from ether, ester, amide, carbonate, carbamate, 1,3 dioxolone, and 1,3 dioxane; R.sup.1 is H or C.sub.1-4 alkyl; R.sup.2 is —COOH, —SO.sub.3H, or —OPO.sub.3H.sub.2 q is an integer from 1 to 4; n is an integer from 1 to 4; p is an integer from 1 to 3; and n+p is from 2 to 5; and wherein —COOH, —OPO.sub.3H.sub.2 and —SO.sub.3H as well as phenolic —OH maybe in the form of a pharmaceutically acceptable salt.
Radiopaque polymers
A hydrophilic polymer comprising pendent groups of the formula I: Wherein: W is independently selected from —OH, —COOH, —SO.sub.3H, —OPO.sub.3H, —O—(C.sub.1-4alkyl), —O—(C.sub.1-4alkyl)OH, —O—(C.sub.1-4alkyl)R.sup.2, —O—(C.sub.2H.sub.5O).sub.qR.sup.1—(C═O)—O—C.sub.1-4alkyl and —O—(C═O)C.sub.1-4alkyl; or a group —BZ; wherein —OH, COOH, O—PO.sub.3H and SO.sub.3H maybe in the form of a pharmaceutically acceptable salt; wherein: B is a bond, or a straight branched alkanediyl, oxyalkylene, alkylene oxaalkylene, or alkylene (oligooxalkylene) group, optionally containing one or more fluorine substituents; and Z is an ammonium, phosphonium, or sulphonium phosphate or phosphonate ester zwitterionic group; X is either a bond or a linking group having 1 to 8 carbons and optionally 1 to 4 heteroatoms selected from O, N and S; G is a coupling group through which the group of the formula I is coupled to the polymer and is selected from ether, ester, amide, carbonate, carbamate, 1,3 dioxolone, and 1,3 dioxane; R.sup.1 is H or C.sub.1-4 alkyl; R.sup.2 is —COOH, —SO.sub.3H, or —OPO.sub.3H.sub.2 q is an integer from 1 to 4; n is an integer from 1 to 4; p is an integer from 1 to 3; and n+p is from 2 to 5; and wherein —COOH, —OPO.sub.3H.sub.2 and —SO.sub.3H as well as phenolic —OH maybe in the form of a pharmaceutically acceptable salt.
ACETOACETYL GROUP-CONTAINING POLYVINYL ALCOHOL RESIN, AND METHOD FOR PRODUCING ACETOACETYL GROUP-CONTAINING POLYVINYL ALCOHOL RESIN
An acetoacetyl group-containing polyvinyl alcohol resin having little variation in acetoacetyl group content depending on particle size range. The acetoacetyl group-containing polyvinyl alcohol resin is a particulate acetoacetyl group-containing polyvinyl alcohol resin having an acetoacetyl group content distribution such that a ratio between the highest and the lowest acetoacetyl group content determined for a particle diameter range of less than 105 μm, a particle diameter range of not less than 105 μm and less than 177 μm, a particle diameter range of not less than 177 μm and less than 600 μm, and a particle diameter range of not less than 600 μm ((highest acetoacetyl group content)/(lowest acetoacetyl group content)) is less than 1.2.
ACETOACETYL GROUP-CONTAINING POLYVINYL ALCOHOL RESIN, AND METHOD FOR PRODUCING ACETOACETYL GROUP-CONTAINING POLYVINYL ALCOHOL RESIN
An acetoacetyl group-containing polyvinyl alcohol resin having little variation in acetoacetyl group content depending on particle size range. The acetoacetyl group-containing polyvinyl alcohol resin is a particulate acetoacetyl group-containing polyvinyl alcohol resin having an acetoacetyl group content distribution such that a ratio between the highest and the lowest acetoacetyl group content determined for a particle diameter range of less than 105 μm, a particle diameter range of not less than 105 μm and less than 177 μm, a particle diameter range of not less than 177 μm and less than 600 μm, and a particle diameter range of not less than 600 μm ((highest acetoacetyl group content)/(lowest acetoacetyl group content)) is less than 1.2.
CARBAZATE-ACTIVATED POLYVINYL ALCOHOL (PVAC) AS A POLYMER-BASED ANTITUMORAL AGENT
The present invention provides a polymer comprising a carbazate-modified polyvinyl alcohol (PVAC) according to Formula I for use in preventing, alleviating, and/or treating cancer, and a method for producing said compound.
CARBAZATE-ACTIVATED POLYVINYL ALCOHOL (PVAC) AS A POLYMER-BASED ANTITUMORAL AGENT
The present invention provides a polymer comprising a carbazate-modified polyvinyl alcohol (PVAC) according to Formula I for use in preventing, alleviating, and/or treating cancer, and a method for producing said compound.
Binder for Secondary Battery, Negative Electrode for Secondary Battery Including the Same, and Lithium Secondary Battery Including the Same
Provided are a binder for a secondary battery, a negative electrode including the same, and a secondary battery including the same. More particularly, the binder for a secondary battery including a crosslinked product of a copolymer with a silane-based crosslinking agent according to the present invention may have excellent thermal resistance and mechanical properties and effectively improve a binding force, and the negative electrode for a secondary battery and the secondary battery including the same may effectively suppress expansion of a negative electrode to improve charge/discharge cycle characteristics and performance of the secondary battery.
Binder for Secondary Battery, Negative Electrode for Secondary Battery Including the Same, and Lithium Secondary Battery Including the Same
Provided are a binder for a secondary battery, a negative electrode including the same, and a secondary battery including the same. More particularly, the binder for a secondary battery including a crosslinked product of a copolymer with a silane-based crosslinking agent according to the present invention may have excellent thermal resistance and mechanical properties and effectively improve a binding force, and the negative electrode for a secondary battery and the secondary battery including the same may effectively suppress expansion of a negative electrode to improve charge/discharge cycle characteristics and performance of the secondary battery.