An antifouling article including a base material, a diamond-like carbon layer and an antifouling coating layer formed of a surface-treating agent on the diamond-like carbon layer. The surface-treating agent includes a group having a carbon-carbon unsaturated bond, a group having a carbon-nitrogen unsaturated bond, or a leaving group.

The invention relates to a method for preparing a vinyl ether polymer by photo-initiated polymerization, which comprises the step of: under a protective atmosphere, performing photo-initiated polymerization on a vinyl ether monomer in the presence of an organic halogenated hydrocarbon and manganese carbonyl under irradiation of light having a wavelength of 365-550 nm at −25° C. to 25° C., to obtain a vinyl ether polymer after the reaction is completed. In the method, a vinyl ether monomer is subjected to cationic polymerization in the presence of manganese carbonyl and an organic halogenated hydrocarbon under visible light, to prepare a vinyl ether polymer with controlled molecular weight and narrow molecular weight distribution.

The invention relates to a method for preparing a vinyl ether polymer by photo-initiated polymerization, which comprises the step of: under a protective atmosphere, performing photo-initiated polymerization on a vinyl ether monomer in the presence of an organic halogenated hydrocarbon and manganese carbonyl under irradiation of light having a wavelength of 365-550 nm at −25° C. to 25° C., to obtain a vinyl ether polymer after the reaction is completed. In the method, a vinyl ether monomer is subjected to cationic polymerization in the presence of manganese carbonyl and an organic halogenated hydrocarbon under visible light, to prepare a vinyl ether polymer with controlled molecular weight and narrow molecular weight distribution.

The present invention relates to compositions comprising at least one (per)fluoropolyether base oil and at least one polymer obtained by the copolymerization of (per)fluoropolyether (PFPE), tetrafluoroethylene (TFE) and at least one non-homopolymerizable olefin.

A water treatment method including a removal step of removing a polymer (I) containing a polymerization unit (I) based on a monomer represented by the following general formula (I) from water containing the polymer (I):

CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m  (I)

wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more. Further, the number average molecular weight of the polymer (I) to 0.3×10.sup.4 or more. Also disclosed is a composition including the polymer (I) containing the polymerization unit (I) based on a monomer represented by general formula (I), and where the composition has a content of the polymer (I) of 250 ppm or less.

Provided in this patent disclosure are two types of novel fluoro-monomers that can be polymerized for the fabrication of ion-exchange fluoropolymers. In addition, new proton-conductive zirconium-perfluorophosphonic acid fluoropolymer membranes that can reduce metal crossovers in redox flow batteries are also provided.

Biomass derived benzoin derivatives, and methods of making and using the same, are described. Benzoin derivatives may be used as visible light photoinitiators.

The lubricating oil composition for a refrigerator according to the present invention is a lubricating oil composition for a refrigerator containing a base oil containing a low-viscosity base oil component having added thereto a polyoxyalkylene glycol compound having a kinetic viscosity at 100° C. that is higher than the low-viscosity base oil component, and the base oil has a kinetic viscosity at 100° C. of 2.4 to 25 mm.sup.2/s and a ratio (Mw/Mn) of a weight average molecular weight (Mw) and a number average molecular weight (Mn) of 1.3 to 13.

The lubricating oil composition for a refrigerator according to the present invention is a lubricating oil composition for a refrigerator containing a base oil containing a low-viscosity base oil component having added thereto a polyoxyalkylene glycol compound having a kinetic viscosity at 100° C. that is higher than the low-viscosity base oil component, and the base oil has a kinetic viscosity at 100° C. of 2.4 to 25 mm.sup.2/s and a ratio (Mw/Mn) of a weight average molecular weight (Mw) and a number average molecular weight (Mn) of 1.3 to 13.

A coating composition which contains a fluorinated polymer having a unit (1) represented by —[CX.sup.1X.sup.2—CY.sup.1(Rf.sup.1—COOM.sup.1)]— and a fluorinated compound represented by CX.sup.3X.sup.4═CY.sup.2(Rf.sup.2—COOM.sup.2), wherein the content of the fluorinated compound is from 0.1 to 8.0 parts by mass per 100 parts by mass of the fluorinated polymer. X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are H, F or Cl, Y.sup.1 and Y.sup.2 are H, F, Cl, a methyl group or a trifluoromethyl group, Rf.sup.1 and Rf.sup.2 are a perfluoroalkylene group which may contain an etheric oxygen atom between carbon-carbon atoms, or an oxyperfluoroalkylene group which may contain an etheric oxygen atom between carbon-carbon atoms, —COOM.sup.1 is —COOH or —COOZ.sup.1, and —COOM.sup.2 is —COOH or —COOZ.sup.2 (wherein Z.sup.1 and Z.sup.2 are an ammonium ion in which the hydrogen atom may be substituted). The coating composition is suitable for forming a thin antireflection coating layer without increasing its refractive index.