A polymer comprising recurring units derived from organic unsaturated planar ring monomers. The recurring units are stacked, linked to one another by linkers, and are capable of undergoing oxidation and/or reduction, and the polymer is electrically conducting.

A method of storing gas comprises providing a recipient for receiving the gas and providing a porous gas storage material. The gas storage material comprises a cross-linked polymeric framework and a plurality of pores for gas sorption. The cross-linked polymeric framework comprises aromatic ring-containing monomeric units comprising at least two aromatic rings. The aromatic ring-containing monomeric units are linked by covalent cross-linking between aromatic rings to form a stable, rigid nanoporous material for storing the gas at pressures significantly greater than the atmospheric pressure, for example in excess of 100 bar. A possible application is the storage and transportation of compressed natural gas.

A method of storing gas comprises providing a recipient for receiving the gas and providing a porous gas storage material. The gas storage material comprises a cross-linked polymeric framework and a plurality of pores for gas sorption. The cross-linked polymeric framework comprises aromatic ring-containing monomeric units comprising at least two aromatic rings. The aromatic ring-containing monomeric units are linked by covalent cross-linking between aromatic rings to form a stable, rigid nanoporous material for storing the gas at pressures significantly greater than the atmospheric pressure, for example in excess of 100 bar. A possible application is the storage and transportation of compressed natural gas.

The polymer proppant and method for producing the same relate to oil and gas production technology using materials of high-molecular weight compounds with higher requirements for physical and mechanical properties. The proppant is used as propping granules utilized in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant whose material provides a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The polymer proppant represents microspheres of metathesis-radically cross-linked mixture of oligocyclopentadienes.

The polymer proppant and method for producing the same relate to oil and gas production technology using materials of high-molecular weight compounds with higher requirements for physical and mechanical properties. The proppant is used as propping granules utilized in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant whose material provides a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The polymer proppant represents microspheres of metathesis-radically cross-linked mixture of oligocyclopentadienes.

Disclosed herein are copolymers formed by cationic polymerization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.

Disclosed herein are copolymers formed by cationic polymerization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.

A topochemical approach for creating elongated C—C bonds with a bond length of 1.57˜1.70 Å between monomers in the solid state; and topochemically prepared highly crystalline polymers.

A topochemical approach for creating elongated C—C bonds with a bond length of 1.57˜1.70 Å between monomers in the solid state; and topochemically prepared highly crystalline polymers.

The disclosure relates to methods for producing poly(cyclohexadiene) homopolymers (PCHD). The PCHD is formed by polymerizing a 1,3-cyclohexadiene monomer in the presence of a catalyst, in a hydrocarbon solvent, and at a temperature of −100° C. to 120° C. The catalyst is selected from the group consisting of a Bronsted acid, a Lewis acid, and combinations thereof. PCHD produced under these conditions has good solubility in non-polar solvents, and a number average molecular weight of 300 to 5,000 Dalton; a weight average molecular weight of 5,000 to 15,000 Delton; and a polydispersity index of 3.0 to 8.0. The PCHD is useful for producing crosslinked materials having good physical properties. The crosslinked materials can be combined with a rubbery polymer to produce compositions valuable for further downstream uses.