The present invention is directed to a benzoxazine-functionalized diene-based elastomer comprising polymer chains including repeat units which include conjugated diolefin monomers, such as 1,3-butadiene and isoprene. Additionally, said elastomer comprises at least one benzoxazine connected to a polymer chain via a spacer, wherein the spacer has a length ranging from 3 to 8 atoms. A further aspect of the present invention is directed to a rubber composition comprising such an elastomer, an article of manufacture comprising this rubber composition, and a method of making said benzoxazine-functionalized diene-based elastomer.

The present invention is directed to a benzoxazine-functionalized diene-based elastomer comprising polymer chains including repeat units which include conjugated diolefin monomers, such as 1,3-butadiene and isoprene. Additionally, said elastomer comprises at least one benzoxazine connected to a polymer chain via a spacer, wherein the spacer has a length ranging from 3 to 8 atoms. A further aspect of the present invention is directed to a rubber composition comprising such an elastomer, an article of manufacture comprising this rubber composition, and a method of making said benzoxazine-functionalized diene-based elastomer.

A polybenzoxazine sulfide has repeating units including at least one unit corresponding to formula (I) or (II): ##STR00001##
in which the two oxazine rings are connected together via a central aromatic group, the benzene ring of which bears one, two, three or four groups of formula —S.sub.x—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon-based group including 1 to 10 carbon atoms and optionally a heteroatom chosen from O, S, N and P. Such a polybenzoxazine can be used as an adhesive layer on metal, in particular for the adhesive bonding of a metallic substrate, in particular made of carbon steel, to rubber.

A polybenzoxazine sulfide has repeating units including at least one unit corresponding to formula (I) or (II): ##STR00001##
in which the two oxazine rings are connected together via a central aromatic group, the benzene ring of which bears one, two, three or four groups of formula —S.sub.x—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon-based group including 1 to 10 carbon atoms and optionally a heteroatom chosen from O, S, N and P. Such a polybenzoxazine can be used as an adhesive layer on metal, in particular for the adhesive bonding of a metallic substrate, in particular made of carbon steel, to rubber.

This invention relates to a process for preparing succinic acid and succinate ester from a succinic acid salt in fermentation broth. In the first stage of this invention, renewable carbon resources are utilized to produce succinic acid through biological fermentation. The succinic acid salt in the fermentation process is subjected to double displacement reaction with a strong acid leading to release of succinic acid. Succinic acid is recovered by fractional crystallization integrated with simulated moving bed chromatography to produce succinic acid and succinate ester.

The invention discloses functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers containing dicyclopentadiene, a method of producing the same and use thereof. The cured products of the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention exhibit low dielectric constant, low dissipation, and high glass transition temperature. As the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention have number-average molecular weight ranging from 2500 to 6000 g/mol, the substrate made of theses functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers can pass the pressure cook test. Besides, the low dissipation factor characteristic the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention can only be demonstrated at number-average molecular weight higher than 2500 g/mol.

The invention discloses functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers containing dicyclopentadiene, a method of producing the same and use thereof. The cured products of the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention exhibit low dielectric constant, low dissipation, and high glass transition temperature. As the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention have number-average molecular weight ranging from 2500 to 6000 g/mol, the substrate made of theses functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers can pass the pressure cook test. Besides, the low dissipation factor characteristic the functionalized poly(2,6-dimethyl phenylene oxide oxide) oligomers of the invention can only be demonstrated at number-average molecular weight higher than 2500 g/mol.

Provided are a modified conjugated diene-based polymer comprising a conjugated diene-based monomer-derived repeating unit; and a chain extender-derived part which is linked to both terminals of the conjugated diene based monomer-derived repeating unit, respectively, includes one or more urethane groups in a molecular chain, and has different functional groups at both terminals, wherein one of the functional groups is an alkyne group, wherein a terminal of the chain extender-derived part which is not linked to both terminals of the conjugated diene based monomer-derived repeating unit is an alkyne group, a manufacturing method thereof, a binder composition for a solid propellant comprising the same, a modified conjugated diene based binder for a solid propellant, and a manufacturing method thereof.

Provided are a modified conjugated diene-based polymer comprising a conjugated diene-based monomer-derived repeating unit; and a chain extender-derived part which is linked to both terminals of the conjugated diene based monomer-derived repeating unit, respectively, includes one or more urethane groups in a molecular chain, and has different functional groups at both terminals, wherein one of the functional groups is an alkyne group, wherein a terminal of the chain extender-derived part which is not linked to both terminals of the conjugated diene based monomer-derived repeating unit is an alkyne group, a manufacturing method thereof, a binder composition for a solid propellant comprising the same, a modified conjugated diene based binder for a solid propellant, and a manufacturing method thereof.

The present invention relates to n-type conjugated polymers and blends, which is made from aromatic diketone with active methylene or an enolic transformation product thereof, and is obtained directly by polymerization reaction in the presence of an oxidant. The reaction described does not require precious metal catalysis and is insensitive to a reaction atmosphere. A process is simple and inexpensive and suitable for commercial applications. Meanwhile, the modulation of the conductivity of the n-type conjugated polymers can be achieved by ionic modification. The n-type conjugated polymers can be applied to an organic optoelectronic device to achieve an excellent photovoltaic effect.