A method for manufacturing a fluorine-free water repellent includes: mixing a paraffin, an inorganic nanopowder and a first reactive monomer to form a first mixture, in which the first reactive monomer includes a structure represented by formula (A), formula (B) or a combination thereof, the formula (A) is

##STR00001##

wherein X.sub.1 is a benzene, and the formula (B) is

##STR00002##

wherein X.sub.2 is CH.sub.3 or H and X.sub.3 is an alkyl group having 18 or more carbon atoms; mixing an emulsifier, a cosolvent and water to form a second mixture; mixing the first mixture and the second mixture to form a pre-emulsion; and adding an initiator and a second reactive monomer into the pre-emulsion, in which the first reactive monomer and the second reactive monomer are polymerized to form a water repellent, wherein the second reactive monomer is vinylidene chloride.

A method for manufacturing a fluorine-free water repellent includes: mixing a paraffin, an inorganic nanopowder and a first reactive monomer to form a first mixture, in which the first reactive monomer includes a structure represented by formula (A), formula (B) or a combination thereof, the formula (A) is

##STR00001##

wherein X.sub.1 is a benzene, and the formula (B) is

##STR00002##

wherein X.sub.2 is CH.sub.3 or H and X.sub.3 is an alkyl group having 18 or more carbon atoms; mixing an emulsifier, a cosolvent and water to form a second mixture; mixing the first mixture and the second mixture to form a pre-emulsion; and adding an initiator and a second reactive monomer into the pre-emulsion, in which the first reactive monomer and the second reactive monomer are polymerized to form a water repellent, wherein the second reactive monomer is vinylidene chloride.

The present invention aims to provide an ionomer that can exhibit high oxygen permeability, especially under both low- and high-humidified conditions, and high power generation durability. The high oxygen permeable ionomer includes a specific repeating unit A and repeating unit B and has an equivalent weight of 250 to 930 and a glass transition temperature of 100 C. to 130 C.

The present invention aims to provide an ionomer that can exhibit high oxygen permeability, especially under both low-and high-humidified conditions, and high power generation durability. The high oxygen permeable ionomer includes a specific repeating unit A and repeating unit B and has an equivalent weight of 250 to 930 and a glass transition temperature of 100 C. to 130 C.

A method of producing a fluorine-containing compound is a method of producing a compound (30) having partial structure (3) by an insertion reaction of compound (20) into compound (10) that has partial structure (1), in the presence of an ionic catalyst formed from a specific monovalent anion and a counter cation. In the formulas, * represents a bonding site, and X.sup.1 and R.sup.1 to R.sup.4 each independently represents a hydrogen atom, a fluorine atom, a chlorine atom, or an organic group having a carbon number of 1 to 20 which may have a substituent. ##STR00001##