The present invention relates to multifunctional bisacylphosphine oxides, which are useful as photoinitiators, and to compositions comprising said photoinitiators. The invention also relates to a process for photocuring and to articles of manufacture prepared by said process.

The invention relates to a hydrogel based on vinyl caprolactam, with or without additional monomers, and at least two crosslinkers. The invention also relates to a method for obtaining said material and to the use thereof to culture cells/engineer cell monolayers, as well as supports for cell culture and transplant.

The present disclosure is to provide a photopolymer composition including a polymer matrix or a precursor thereof including a reaction product of a reactive isocyanate compound having a hydrogen bonding functional group capable of forming multiple hydrogen bonds and at least one isocyanate group, and a polyol having at least two hydroxyl groups; a photoreactive monomer; and a photoinitiator, a hologram recording medium produced from the photopolymer composition, an optical element including the photopolymer composition and a holographic recording method using the photopolymer composition.

The present disclosure is to provide a photopolymer composition including a polymer matrix or a precursor thereof including a reaction product of a reactive isocyanate compound having a hydrogen bonding functional group capable of forming multiple hydrogen bonds and at least one isocyanate group, and a polyol having at least two hydroxyl groups; a photoreactive monomer; and a photoinitiator, a hologram recording medium produced from the photopolymer composition, an optical element including the photopolymer composition and a holographic recording method using the photopolymer composition.

Provided are: a radical polymerization initiator which has excellent sensitivity and solubility in water; a composition containing the same; a cured product of the composition; a method of producing the cured product; and a compound. The radical polymerization initiator contains a compound represented by Formula (A) below (wherein Z.sup.1 represents a direct bond or the like; Z.sup.2 represents —C(R.sup.102).sub.2— or the like; R.sup.1 to R.sup.8 each represent a hydrogen atom or the like, or a group containing a salt-forming group, which is represented by Formula (B1) below (wherein L.sub.1 represents a direct bond or the like, B represents an acidic group salt or the like, b represents 1 to 10, and the asterisk (*) represents a binding site), at least one of R.sup.1 to R.sup.8 is the group containing a salt-forming group; R.sup.101 and the like each represent a hydrogen atom or the like; one or more hydrogen atoms in the alkyl group and the like used as R.sup.1 to R.sup.8 and the like are optionally substituted with an ethylenically unsaturated group or the like; one or more methylene groups in R.sup.1 to R.sup.8 and the like are optionally substituted with a double bond or the like; adjacent groups such as R.sup.1 and R.sup.2 are optionally bound together to, form a ring and optionally form a fused ring with a benzene ring in Formula (A); and represents a hydrogen atom or the like). ##STR00001##

Provided are: a radical polymerization initiator which has excellent sensitivity and solubility in water; a composition containing the same; a cured product of the composition; a method of producing the cured product; and a compound. The radical polymerization initiator contains a compound represented by Formula (A) below (wherein Z.sup.1 represents a direct bond or the like; Z.sup.2 represents —C(R.sup.102).sub.2— or the like; R.sup.1 to R.sup.8 each represent a hydrogen atom or the like, or a group containing a salt-forming group, which is represented by Formula (B1) below (wherein L.sub.1 represents a direct bond or the like, B represents an acidic group salt or the like, b represents 1 to 10, and the asterisk (*) represents a binding site), at least one of R.sup.1 to R.sup.8 is the group containing a salt-forming group; R.sup.101 and the like each represent a hydrogen atom or the like; one or more hydrogen atoms in the alkyl group and the like used as R.sup.1 to R.sup.8 and the like are optionally substituted with an ethylenically unsaturated group or the like; one or more methylene groups in R.sup.1 to R.sup.8 and the like are optionally substituted with a double bond or the like; adjacent groups such as R.sup.1 and R.sup.2 are optionally bound together to, form a ring and optionally form a fused ring with a benzene ring in Formula (A); and represents a hydrogen atom or the like). ##STR00001##

The present invention particularly relates to synthesizing photo-initiators having poly-oligo-silsesquioxane (POSS) structure and realizing photo-polymerization by using these photo-initiators and simultaneous and in-situ synthesis of Ag nano-particles in polymer matrix comprising POSS structure and obtaining wrinkled surfaces as a result of self-arranging thereof.

The present invention particularly relates to synthesizing photo-initiators having poly-oligo-silsesquioxane (POSS) structure and realizing photo-polymerization by using these photo-initiators and simultaneous and in-situ synthesis of Ag nano-particles in polymer matrix comprising POSS structure and obtaining wrinkled surfaces as a result of self-arranging thereof.

The present invention provides a process for the preparation of mono- and bisacylphosphanes based on formula (I):

##STR00001##

as well as for their corresponding oxides or sulfides. The present invention further relates to photoinitiators obtainable by said process.

The present invention provides a process for the preparation of mono- and bisacylphosphanes based on formula (I):

##STR00001##

as well as for their corresponding oxides or sulfides. The present invention further relates to photoinitiators obtainable by said process.