Patent classifications
C08F20/56
FLOW CELL AND METHODS
An example of a flow cell includes a substrate and a pattern of two different silanes on at least a portion of a surface of the substrate. A first polymer is attached to a first of the two different silanes and a second polymer is attached to a second of the two different silanes. The first and second polymers respectively include a first functional group and a second functional group of a functional group pair, the functional group pair being selected from the group consisting of an activated ester functional group and an azide functional group, a tetrazine functional group and an activated ester functional group, and a tetrazine functional group and an azide functional group. A first primer set is grafted to the first polymer and a second primer set is grafted to the second polymer. The first and second primer sets are different.
FLOW CELL AND METHODS
An example of a flow cell includes a substrate and a pattern of two different silanes on at least a portion of a surface of the substrate. A first polymer is attached to a first of the two different silanes and a second polymer is attached to a second of the two different silanes. The first and second polymers respectively include a first functional group and a second functional group of a functional group pair, the functional group pair being selected from the group consisting of an activated ester functional group and an azide functional group, a tetrazine functional group and an activated ester functional group, and a tetrazine functional group and an azide functional group. A first primer set is grafted to the first polymer and a second primer set is grafted to the second polymer. The first and second primer sets are different.
Method of preparing superabsorbent polymer
A method of preparing a superabsorbent polymer, which enables the preparation of the superabsorbent polymer exhibiting an improved absorption rate while maintaining excellent absorption performances is provided. The method of preparing the superabsorbent polymer includes carrying out a crosslinking polymerization of a water-soluble ethylene-based unsaturated monomer having acidic groups which are at least partially neutralized, in the presence of an internal crosslinking agent having a predetermined chemical structure to form a water-containing gel polymer, gel-pulverizing the water-containing gel polymer, drying, pulverizing, and size-sorting the gel-pulverized water-containing gel polymer to form a base polymer powder, and carrying out a surface crosslinking of the base polymer powder by a heat treatment in the presence of a surface crosslinking agent, wherein the gel-pulverizing is carried out by extruding the water-containing gel polymer through a porous plate having a plurality of holes using a screw extruder mounted inside a cylindrical pulverizer under a condition that a chopping index is 28 (/s) or more.
CARBON NANOTUBE DISPERSION
This invention provides a carbon nanotube dispersion that contains carbon nanotubes, a dispersant, a solvent, and a polymer which has a partial structure represented by formula (P1) on a side chain.
##STR00001##
(In the formula, L represents —O— or —NH—, R represents an alkylene group having 1-20 carbon atoms, T represents a substituted or unsubstituted amino group, a nitrogen-containing heteroaryl group having 2-20 carbon atoms, or a nitrogen-containing aliphatic heterocyclic group having 2-20 carbon atoms, and * represents a bond.)
POLYELECTROLYTE HYDROGEL COATING WITH STRONG SUBSTRATE BINDING PERFORMANCE AND METHOD OF MANUFACTURING THE SAME
A polyelectrolyte hydrogel coating with strong substrate binding performance and a method of manufacturing the same are provided. The method includes: 1) activating a substrate by applying oxygen plasma; and 2) dissolving a polycationic polymer, a polymeric monomer, a silane coupling agent and an initiator to obtain a precursor solution, vacuumizing the precursor solution to remove air bubbles, applying the vacuumized precursor solution to a surface of the substrate activated by the oxygen plasma, and performing an in-situ polymerization and curing process under nitrogen or rare gas atmosphere. The polymeric monomer includes at least one of: acrylamide, acrylic acid, hydroxyethyl methacrylamide, 2-acrylamido-2-methyl-1-propanesulfonic acid, polyethylene glycol (diol) diacrylate, 2-methacryloxyethylphosphocholine, 3-[[2-(Methacryloyloxy)ethyl]dimethylammonio]propane-1-sulfonate, and 3-[[2-(methacryloyloxy)ethyl]dimethylammonium] propionate. The silane coupling agent has a carbon-carbon double bond functional group.
POLYELECTROLYTE HYDROGEL COATING WITH STRONG SUBSTRATE BINDING PERFORMANCE AND METHOD OF MANUFACTURING THE SAME
A polyelectrolyte hydrogel coating with strong substrate binding performance and a method of manufacturing the same are provided. The method includes: 1) activating a substrate by applying oxygen plasma; and 2) dissolving a polycationic polymer, a polymeric monomer, a silane coupling agent and an initiator to obtain a precursor solution, vacuumizing the precursor solution to remove air bubbles, applying the vacuumized precursor solution to a surface of the substrate activated by the oxygen plasma, and performing an in-situ polymerization and curing process under nitrogen or rare gas atmosphere. The polymeric monomer includes at least one of: acrylamide, acrylic acid, hydroxyethyl methacrylamide, 2-acrylamido-2-methyl-1-propanesulfonic acid, polyethylene glycol (diol) diacrylate, 2-methacryloxyethylphosphocholine, 3-[[2-(Methacryloyloxy)ethyl]dimethylammonio]propane-1-sulfonate, and 3-[[2-(methacryloyloxy)ethyl]dimethylammonium] propionate. The silane coupling agent has a carbon-carbon double bond functional group.
Device and methods for determination of molecular weight distributions of polymers and distributions of other polymer properties without physical separation
Devices and methods for determining the cumulative distribution of a polymer property in a reactor without physical separation of reaction subcomponents. The device includes a means of measuring an instantaneous property of the polymers being produced in a reaction vessel a plurality of times during a polymerization reaction as well as a means of determining the corresponding change in polymer concentration in the reaction vessel between measurements of the instantaneous polymer property The device also includes a means of computing a statistical distribution appropriate to the polymer characteristic and applying the statistical distribution to a recently measured instantaneous value of the polymer property so as to have an instantaneous distribution of the polymer property and a means of adding together the instantaneous distributions of the polymer property in order to obtain the cumulative distribution of the polymer property in the reactor.
Device and methods for determination of molecular weight distributions of polymers and distributions of other polymer properties without physical separation
Devices and methods for determining the cumulative distribution of a polymer property in a reactor without physical separation of reaction subcomponents. The device includes a means of measuring an instantaneous property of the polymers being produced in a reaction vessel a plurality of times during a polymerization reaction as well as a means of determining the corresponding change in polymer concentration in the reaction vessel between measurements of the instantaneous polymer property The device also includes a means of computing a statistical distribution appropriate to the polymer characteristic and applying the statistical distribution to a recently measured instantaneous value of the polymer property so as to have an instantaneous distribution of the polymer property and a means of adding together the instantaneous distributions of the polymer property in order to obtain the cumulative distribution of the polymer property in the reactor.
LIQUID CHLORIDE SALT-BASED POLYMER SUSPENSION FLUIDS WITH POLYETHYLENE GLYCOL DISPERSANTS AND APPLICATION TO DRAG REDUCTION
Aqueous suspensions are presented that are stable against settling without additional mixing in which the suspensions comprise a water soluble polymer that is anionic or non-ionic comprising a blend of water with at least about 32 weight percent chloride salt with a counter ion A.sup.+a with 2≤a, from about 1 wt % to about 10 wt % particulate polyethylene glycol having an average molecular weight from about 1600 g/mol to about 50,000 g/mol, and from about 10 wt % to about 50 wt % of the water soluble polymer that is not a poly ether. The suspension has chlorides in a sufficient amount to inhibit hydration of the suspended water soluble polymer and the particulate polyethylene glycol. The aqueous suspension can be formed by adding a powder of polyethylene glycol to a high salt solution and then adding the high molecular weight polymer. The aqueous suspensions can be useful as friction reducing agents in flowing liquids, such as for hydraulic fracture.
LIQUID CHLORIDE SALT-BASED POLYMER SUSPENSION FLUIDS WITH POLYETHYLENE GLYCOL DISPERSANTS AND APPLICATION TO DRAG REDUCTION
Aqueous suspensions are presented that are stable against settling without additional mixing in which the suspensions comprise a water soluble polymer that is anionic or non-ionic comprising a blend of water with at least about 32 weight percent chloride salt with a counter ion A.sup.+a with 2≤a, from about 1 wt % to about 10 wt % particulate polyethylene glycol having an average molecular weight from about 1600 g/mol to about 50,000 g/mol, and from about 10 wt % to about 50 wt % of the water soluble polymer that is not a poly ether. The suspension has chlorides in a sufficient amount to inhibit hydration of the suspended water soluble polymer and the particulate polyethylene glycol. The aqueous suspension can be formed by adding a powder of polyethylene glycol to a high salt solution and then adding the high molecular weight polymer. The aqueous suspensions can be useful as friction reducing agents in flowing liquids, such as for hydraulic fracture.