An acrylic rubber including: a polymer composition of: 70 to 99.9% by weight of a bonding unit derived from at least one (meth) acrylic acid ester selected from (meth) acrylic acid alkyl ester and (meth) acrylic acid alkoxyalkyl ester; 0.1 to 10% by weight of a bonding unit derived from a monomer containing a reactive group; and 0 to 20% by weight of a bonding unit derived from other monomer, wherein ash content is 0.15% by weight or less, total amount of sodium and sulfur in the ash is 60% by weight or more, a ratio of sodium to sulfur by weight ratio is in the range of 0.5 to 2.5, ratio of Z-average molecular weight to weight average molecular weight is 1.3 or more, and weight average molecular weight is in the range of 1,000,000 to 5,000,000.

An acrylic rubber including: a polymer composition of: 70 to 99.9% by weight of a bonding unit derived from at least one (meth) acrylic acid ester selected from (meth) acrylic acid alkyl ester and (meth) acrylic acid alkoxyalkyl ester; 0.1 to 10% by weight of a bonding unit derived from a monomer containing a reactive group; and 0 to 20% by weight of a bonding unit derived from other monomer, wherein ash content is 0.15% by weight or less, total amount of sodium and sulfur in the ash is 60% by weight or more, a ratio of sodium to sulfur by weight ratio is in the range of 0.5 to 2.5, ratio of Z-average molecular weight to weight average molecular weight is 1.3 or more, and weight average molecular weight is in the range of 1,000,000 to 5,000,000.

An acrylic rubber composition comprising 5 to 15 parts by weight of a plasticizer having a solubility parameter SP value (by Small's method) of 8.5 to 10.5 based on 100 parts by weight of super cold resistant grade acrylic rubber having a glass transition point Tg of −42° C. or less, wherein the acrylic rubber composition can give a vulcanizate with the TR10 value, which is an index of cold resistance, of −42° C. or less both initially and after oil dipping. In the acrylic rubber composition, first, the ratio of an acrylate monomer that constitutes acrylic rubber is adjusted, thereby the low temperature characteristics can be maintained even in an oil contact environment. This intentionally reduces the oil resistance of the vulcanized rubber molded product, thereby increasing the amount of oil swelling into the vulcanized rubber molded product and improving the flexibility in a low temperature environment.

An acrylic rubber composition comprising 5 to 15 parts by weight of a plasticizer having a solubility parameter SP value (by Small's method) of 8.5 to 10.5 based on 100 parts by weight of super cold resistant grade acrylic rubber having a glass transition point Tg of −42° C. or less, wherein the acrylic rubber composition can give a vulcanizate with the TR10 value, which is an index of cold resistance, of −42° C. or less both initially and after oil dipping. In the acrylic rubber composition, first, the ratio of an acrylate monomer that constitutes acrylic rubber is adjusted, thereby the low temperature characteristics can be maintained even in an oil contact environment. This intentionally reduces the oil resistance of the vulcanized rubber molded product, thereby increasing the amount of oil swelling into the vulcanized rubber molded product and improving the flexibility in a low temperature environment.

An acrylic rubber sheet excellent in storage stability and processability, a method for producing the same, an acrylic rubber bale obtained by laminating the sheets, a mixture obtained by mixing the acrylic rubber sheet and the acrylic rubber bale, a method for producing the mixture and a rubber cross-linking product obtained by cross-linking the mixture. The acrylic rubber sheet comprises, an acrylic rubber mainly composed of a (meth) acrylic acid ester and having a weight average molecular weight (Mw) of 100,000 to 5,000,000 and a ratio (Mz/Mw) of a Z-average molecular weight (Mz) and a weight average molecular weight (Mw) is 1.3 or more, and the acrylic rubber sheet contains a phenolic anti-aging agent, and a gel amount is 50 wt % or less. The acrylic rubber sheet is extremely excellent in storage stability and processability and the sheet can be easily produced by the claimed method.

An acrylic rubber sheet excellent in storage stability and processability, a method for producing the same, an acrylic rubber bale obtained by laminating the sheets, a mixture obtained by mixing the acrylic rubber sheet and the acrylic rubber bale, a method for producing the mixture and a rubber cross-linking product obtained by cross-linking the mixture. The acrylic rubber sheet comprises, an acrylic rubber mainly composed of a (meth) acrylic acid ester and having a weight average molecular weight (Mw) of 100,000 to 5,000,000 and a ratio (Mz/Mw) of a Z-average molecular weight (Mz) and a weight average molecular weight (Mw) is 1.3 or more, and the acrylic rubber sheet contains a phenolic anti-aging agent, and a gel amount is 50 wt % or less. The acrylic rubber sheet is extremely excellent in storage stability and processability and the sheet can be easily produced by the claimed method.

Disclosed are methods for preparing a thin film composite membrane by subjecting a solution comprising one or more zwitterionic copolymers to an electrospraying process, thereby preparing the thin film composite membrane.

An acryl-based copolymer composition is provided. The acryl-based copolymer composition includes an acryl-based copolymer, an aggregation inducing agent, and an aggregating agent, wherein the acryl-based copolymer includes a (meth)acrylic acid alkyl ester monomer-derived repeating unit, a (meth)acrylic acid alkoxy alkyl ester monomer-derived repeating unit, and a crosslinkable monomer-derived repeating unit. The aggregation inducing agent includes a siloxane-based monomer-derived repeating unit and an ether-based monomer-derived repeating unit, and the aggregating agent includes a monovalent ionic metal salt.

An acryl-based copolymer composition is provided. The acryl-based copolymer composition includes an acryl-based copolymer, an aggregation inducing agent, and an aggregating agent, wherein the acryl-based copolymer includes a (meth)acrylic acid alkyl ester monomer-derived repeating unit, a (meth)acrylic acid alkoxy alkyl ester monomer-derived repeating unit, and a crosslinkable monomer-derived repeating unit. The aggregation inducing agent includes a siloxane-based monomer-derived repeating unit and an ether-based monomer-derived repeating unit, and the aggregating agent includes a monovalent ionic metal salt.

An acrylic rubber that is a copolymer in which 1 to 4 wt. % of a reactive halogen group-containing vinyl monomer is copolymerized as a crosslinkable comonomer, wherein 45 to 65 wt. % of n-butyl acrylate, 10 to 35 wt. % of 2-methoxyethyl acrylate and 8 to 30 wt. % of ethoxyethoxyethyl acrylate are copolymerized in 100 wt. % of comonomers other than the crosslinkable comonomer. This ethoxyethoxyethyl acrylate-copolymerized acrylic rubber can suppress the reduction of oil resistance while improving cold resistance represented by a TR-10 value, and by compounding it with a vulcanizing agent corresponding to the crosslinkable group thereof, a crosslinkable composition is formed.