In an embodiment, the present disclosure pertains to a method of changing the glass transition temperature of a polymer. In some embodiments, the polymer includes at least one hydrazone-containing compound. In general, the methods of the present disclosure include one or more of the following steps of: (1) applying light to the polymer; and (2) thereby changing the glass transition temperature of the polymer. In another embodiment, the present disclosure pertains to a polymer having a light-adjustable glass transition temperature. In some embodiments, the polymer includes at least one hydrazone-containing compound.

In an embodiment, the present disclosure pertains to a method of changing the glass transition temperature of a polymer. In some embodiments, the polymer includes at least one hydrazone-containing compound. In general, the methods of the present disclosure include one or more of the following steps of: (1) applying light to the polymer; and (2) thereby changing the glass transition temperature of the polymer. In another embodiment, the present disclosure pertains to a polymer having a light-adjustable glass transition temperature. In some embodiments, the polymer includes at least one hydrazone-containing compound.

Provided are a photocurable material composition providing a cured product, which achieves both of a heat deflection temperature of 70° C. or more measured by Method A of JIS K 7191-1 and a Charpy impact strength of 6 kJ/m.sup.2 or more measured in conformity with JIS K 7111-1, after UV irradiation, and a cured product thereof. The photocurable material composition includes: 50 parts by weight to 65 parts by weight of a bifunctional urethane (meth)acrylate having (meth)acryloyl groups at both terminals thereof; 15 parts by weight to 25 parts by weight of a compound represented by the formula (4); and 10 parts by weight to 30 parts by weight of at least one of a compound represented by the formula (5) or a compound represented by the formula (6).

Provided are a photocurable material composition providing a cured product, which achieves both of a heat deflection temperature of 70° C. or more measured by Method A of JIS K 7191-1 and a Charpy impact strength of 6 kJ/m.sup.2 or more measured in conformity with JIS K 7111-1, after UV irradiation, and a cured product thereof. The photocurable material composition includes: 50 parts by weight to 65 parts by weight of a bifunctional urethane (meth)acrylate having (meth)acryloyl groups at both terminals thereof; 15 parts by weight to 25 parts by weight of a compound represented by the formula (4); and 10 parts by weight to 30 parts by weight of at least one of a compound represented by the formula (5) or a compound represented by the formula (6).

In an embodiment, the present disclosure pertains to a method of changing the glass transition temperature of a polymer. In some embodiments, the polymer includes at least one hydrazone-containing compound. In general, the methods of the present disclosure include one or more of the following steps of: (1) applying light to the polymer; and (2) thereby changing the glass transition temperature of the polymer. In another embodiment, the present disclosure pertains to a polymer having a light-adjustable glass transition temperature. In some embodiments, the polymer includes at least one hydrazone-containing compound.

In an embodiment, the present disclosure pertains to a method of changing the glass transition temperature of a polymer. In some embodiments, the polymer includes at least one hydrazone-containing compound. In general, the methods of the present disclosure include one or more of the following steps of: (1) applying light to the polymer; and (2) thereby changing the glass transition temperature of the polymer. In another embodiment, the present disclosure pertains to a polymer having a light-adjustable glass transition temperature. In some embodiments, the polymer includes at least one hydrazone-containing compound.

The invention relates to a photo-curable liquid resin composition for 3D printing, its preparation process and use, and also to a method of forming a 3D-printed object by using the composition. By using the inventive composition for 3D printing, the improvement of the flexibility and elasticity of the cured composition can be achieved.

The invention relates to a photo-curable liquid resin composition for 3D printing, its preparation process and use, and also to a method of forming a 3D-printed object by using the composition. By using the inventive composition for 3D printing, the improvement of the flexibility and elasticity of the cured composition can be achieved.

The present invention relates to a new photo-initiating composition for red and near infrared-induced photopolymerization, method of using same in photopolymerization reactions and polymers obtained by such method.

The present invention relates to a new photo-initiating composition for red and near infrared-induced photopolymerization, method of using same in photopolymerization reactions and polymers obtained by such method.