The present invention provides a maleimide-based copolymer, a method for producing same, and a resin composition obtained using same.

This maleimide-based copolymer contains 40-60 mass % of aromatic vinyl monomer units, 5-20 mass % of vinyl cyanide monomer units, and 35-50 mass % of maleimide monomer units, and is such that a 4 mass % tetrahydrofuran solution of the copolymer has a transmittance of 90% or more for light having a wavelength of 450 nm at an optical path length of 10 mm, and the residual maleimide-based monomer amount is less than 300 ppm. This maleimide-based copolymer preferably further contains 0-10 mass % of unsaturated dicarboxylic acid anhydride monomer units, and preferably has a glass transition temperature of 165° C. or higher.

The present disclosure relates to a thermoplastic resin composition, a method of preparing the same, and a molded article including the same. For example, the present disclosure relates to a thermoplastic resin composition including 35 to 85% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm and 15 to 65% by weight of a polymethacrylate resin (B). The thermoplastic resin composition has an alkyl acrylate coverage value (X) of 70% or more as calculated by Equation 1. The thermoplastic resin composition may have beneficial mechanical properties, such as impact strength, tensile strength, and flexural strength, surface hardness, transparency, and colorability and may be capable of preventing occurrence of whitening during bending due to beneficial non-whitening properties.

The present disclosure relates to a thermoplastic resin composition, a method of preparing the same, and a molded article including the same. For example, the present disclosure relates to a thermoplastic resin composition including 35 to 85% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm and 15 to 65% by weight of a polymethacrylate resin (B). The thermoplastic resin composition has an alkyl acrylate coverage value (X) of 70% or more as calculated by Equation 1. The thermoplastic resin composition may have beneficial mechanical properties, such as impact strength, tensile strength, and flexural strength, surface hardness, transparency, and colorability and may be capable of preventing occurrence of whitening during bending due to beneficial non-whitening properties.

The present disclosure relates to a thermoplastic resin composition, a method of preparing the same, and a molded article including the same. For example, the present disclosure relates to a thermoplastic resin composition including 35 to 85% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm and 15 to 65% by weight of a polymethacrylate resin (B). The thermoplastic resin composition has an alkyl acrylate coverage value (X) of 70% or more as calculated by Equation 1. The thermoplastic resin composition may have beneficial mechanical properties, such as impact strength, tensile strength, and flexural strength, surface hardness, transparency, and colorability and may be capable of preventing occurrence of whitening during bending due to beneficial non-whitening properties.

A binder composition for a non-aqueous secondary battery electrode contains a specific binder component, a plasticizer, and an organic solvent. The binder component includes an insoluble polymer that includes a (meth)acrylic acid ester monomer unit and an ethylenically unsaturated acid monomer unit and a highly soluble polymer that includes, in specific content ratios, a nitrile group-containing monomer unit and either or both of an amide group-containing monomer unit and a (meth)acrylic acid ester monomer unit having an alkyl chain carbon number of not less than 1 and not more than 6.

A binder composition for a non-aqueous secondary battery electrode contains a specific binder component, a plasticizer, and an organic solvent. The binder component includes an insoluble polymer that includes a (meth)acrylic acid ester monomer unit and an ethylenically unsaturated acid monomer unit and a highly soluble polymer that includes, in specific content ratios, a nitrile group-containing monomer unit and either or both of an amide group-containing monomer unit and a (meth)acrylic acid ester monomer unit having an alkyl chain carbon number of not less than 1 and not more than 6.

To provide a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit which has a satisfactory oil resistance. A method for producing a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit includes a step for conducting continuous addition or 10 cycles or more of intermittent portionwise addition of the chloroprene monomer after initiation of a polymerization reaction is provided. A rubber composition using a statistical copolymer according to the invention or a vulcanized molded article containing the rubber composition is excellent in terms of oil resistance, mechanical strength, compression set at a low temperature and flex fatigue resistance.

To provide a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit which has a satisfactory oil resistance. A method for producing a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit includes a step for conducting continuous addition or 10 cycles or more of intermittent portionwise addition of the chloroprene monomer after initiation of a polymerization reaction is provided. A rubber composition using a statistical copolymer according to the invention or a vulcanized molded article containing the rubber composition is excellent in terms of oil resistance, mechanical strength, compression set at a low temperature and flex fatigue resistance.

Some embodiments of the disclosure provides polyacrylonitrile (PAN) and a preparation method and use thereof. The method includes the following steps. Mixing raw materials for polymerization to obtain a suspension comprising the PAN. The raw materials include an acrylonitrile monomer, a first auxiliary monomer, a second auxiliary monomer, a polymerization medium, an initiator, a chain transfer agent, and a settling agent. Removing unreacted monomers and unreacted polymerization medium in the suspension to obtain the PAN. After subsequent removal of monomers, removal of a polymerization medium, washing, and drying, a PAN powder is obtained. In some embodiments, the preparation method of the PAN has a wide adjustable range of a PAN copolymerization composition, a low viscosity of a polymerization system, a high concentration of a polymerized monomer, and a strong anti-scaling ability.

Some embodiments of the disclosure provides polyacrylonitrile (PAN) and a preparation method and use thereof. The method includes the following steps. Mixing raw materials for polymerization to obtain a suspension comprising the PAN. The raw materials include an acrylonitrile monomer, a first auxiliary monomer, a second auxiliary monomer, a polymerization medium, an initiator, a chain transfer agent, and a settling agent. Removing unreacted monomers and unreacted polymerization medium in the suspension to obtain the PAN. After subsequent removal of monomers, removal of a polymerization medium, washing, and drying, a PAN powder is obtained. In some embodiments, the preparation method of the PAN has a wide adjustable range of a PAN copolymerization composition, a low viscosity of a polymerization system, a high concentration of a polymerized monomer, and a strong anti-scaling ability.