In an embodiment, the present disclosure pertains to a method of changing the glass transition temperature of a polymer. In some embodiments, the polymer includes at least one hydrazone-containing compound. In general, the methods of the present disclosure include one or more of the following steps of: (1) applying light to the polymer; and (2) thereby changing the glass transition temperature of the polymer. In another embodiment, the present disclosure pertains to a polymer having a light-adjustable glass transition temperature. In some embodiments, the polymer includes at least one hydrazone-containing compound.

In an embodiment, the present disclosure pertains to a method of changing the glass transition temperature of a polymer. In some embodiments, the polymer includes at least one hydrazone-containing compound. In general, the methods of the present disclosure include one or more of the following steps of: (1) applying light to the polymer; and (2) thereby changing the glass transition temperature of the polymer. In another embodiment, the present disclosure pertains to a polymer having a light-adjustable glass transition temperature. In some embodiments, the polymer includes at least one hydrazone-containing compound.

Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

A copolymer is formed by reacting (A) aromatic monomer, an oligomer thereof, or a polymer thereof, with (B) aliphatic monomer, an oligomer thereof, or a polymer thereof. The aromatic monomer has a chemical structure of

##STR00001##

in which each of R.sup.1 is independently H or CH.sub.3, and n=1-4. R.sup.2 is a single bond, —O—,

##STR00002##

Each of R.sup.3 is independently

##STR00003##

A copolymer is formed by reacting (A) aromatic monomer, an oligomer thereof, or a polymer thereof, with (B) aliphatic monomer, an oligomer thereof, or a polymer thereof. The aromatic monomer has a chemical structure of

##STR00001##

in which each of R.sup.1 is independently H or CH.sub.3, and n=1-4. R.sup.2 is a single bond, —O—,

##STR00002##

Each of R.sup.3 is independently

##STR00003##

Dental composite composition including a glass ceramic and a curable organic material is described in which the glass ceramic includes a crystal phase having an average grain size of 50 to 400 nm, and the dental composite composition is provided as a dental prosthetic material exhibiting superior transparency and mechanical properties comparing to conventional composite products containing micro-sized crystal grains and also has excellent aesthetics and processability required for prosthetic materials for same-day dental prosthetic service.

Dental composite composition including a glass ceramic and a curable organic material is described in which the glass ceramic includes a crystal phase having an average grain size of 50 to 400 nm, and the dental composite composition is provided as a dental prosthetic material exhibiting superior transparency and mechanical properties comparing to conventional composite products containing micro-sized crystal grains and also has excellent aesthetics and processability required for prosthetic materials for same-day dental prosthetic service.

An article includes a polymer. The polymer includes a product of a crosslinking reaction including at least one cross-linker selected from the group consisting of: a) di-acrylates, tri-acrylates, and tetra-acrylates; b) modified tri-acrylates and tetra-acrylates; c) silanes and siloxanes; and d) triazinane-triones.

An article includes a polymer. The polymer includes a product of a crosslinking reaction including at least one cross-linker selected from the group consisting of: a) di-acrylates, tri-acrylates, and tetra-acrylates; b) modified tri-acrylates and tetra-acrylates; c) silanes and siloxanes; and d) triazinane-triones.