The present disclosure relates to a modified conjugated diene-based polymer, a method for preparing the same and a rubber composition comprising the same, and the modified conjugated diene-based polymer has narrow molecular weight distribution, and includes S atoms in the specific content in the polymer, a derived unit from an N-containing aromatic hydrocarbon compound, a derived unit from an S-containing aromatic hydrocarbon compound or an S-containing heterocyclic compound.

The present disclosure relates to a modified conjugated diene-based polymer, a method for preparing the same and a rubber composition comprising the same, and the modified conjugated diene-based polymer has narrow molecular weight distribution, and includes S atoms in the specific content in the polymer, a derived unit from an N-containing aromatic hydrocarbon compound, a derived unit from an S-containing aromatic hydrocarbon compound or an S-containing heterocyclic compound.

A process for manufacturing a masterbatch comprises the following steps: (a) bringing at least one initial polymer comprising at least one carbon-carbon unsaturation into contact with at least one 1,3-dipolar grafting agent bearing at least one nitrile oxide dipole in the presence of at least one organophosphorus additive selected from the group consisting of phosphoric acid triesters, phosphonates, phosphinates, phosphine oxides and the mixtures of these compounds, and (b) recovering the masterbatch obtained in the preceding step. The masterbatch and compositions containing it and also tires comprising such compositions are also disclosed.

A tire having excellent wet grip performance and low rolling resistance is provided. This tire is a tire obtained by using a rubber composition that includes a rubber component containing a rubber having an isoprene structure and an aminoalkoxysilane-modified styrene-butadiene rubber having an amount of bonded styrene of 15% or less; a filler containing a silica having a nitrogen adsorption specific surface area (BET method) of 130 m.sup.2/g or more and less than 330 m.sup.2/g, the amount of the filler being 40 to 125 parts by mass with respect to 100 parts by mass of the rubber component; and a hydrogenated resin having a softening point of higher than 110° C. and having a weight average molecular weight as converted to polystyrene of 200 to 1200 g/mol, the amount of the hydrogenated resin being 5 to 50 parts by mass per 100 parts by mass of the rubber component.

A tire having excellent wet grip performance and low rolling resistance is provided. This tire is a tire obtained by using a rubber composition that includes a rubber component containing a rubber having an isoprene structure and an aminoalkoxysilane-modified styrene-butadiene rubber having an amount of bonded styrene of 15% or less; a filler containing a silica having a nitrogen adsorption specific surface area (BET method) of 130 m.sup.2/g or more and less than 330 m.sup.2/g, the amount of the filler being 40 to 125 parts by mass with respect to 100 parts by mass of the rubber component; and a hydrogenated resin having a softening point of higher than 110° C. and having a weight average molecular weight as converted to polystyrene of 200 to 1200 g/mol, the amount of the hydrogenated resin being 5 to 50 parts by mass per 100 parts by mass of the rubber component.

The present invention relates to a modified conjugated diene-based polymer having excellent wet skid resistance and abrasion resistance in a balanced way, and a rubber composition comprising the same, and the modified conjugated diene-based polymer is characterized in including: a repeating unit derived from a conjugated diene-based monomer; and a functional group derived from a modifier, wherein, if measured by differential scanning calorimetry (DSC) through controlling the microstructure of the polymer, a difference between a glass transition onset temperature (T.sub.g-on) and a glass transition offset temperature (T.sub.g-off), which arise glass transition, is 10° C. to 30° C., thereby having excellent wet skid resistance and running resistance in a balanced way and improved effects of abrasion resistance, simultaneously.

The present invention relates to a modified conjugated diene-based polymer having excellent wet skid resistance and abrasion resistance in a balanced way, and a rubber composition comprising the same, and the modified conjugated diene-based polymer is characterized in including: a repeating unit derived from a conjugated diene-based monomer; and a functional group derived from a modifier, wherein, if measured by differential scanning calorimetry (DSC) through controlling the microstructure of the polymer, a difference between a glass transition onset temperature (T.sub.g-on) and a glass transition offset temperature (T.sub.g-off), which arise glass transition, is 10° C. to 30° C., thereby having excellent wet skid resistance and running resistance in a balanced way and improved effects of abrasion resistance, simultaneously.

A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.

A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.

As a method for producing a copolymer with a high oil absorption rate by separating a solvent from a copolymer solution containing a copolymer in a simple manner with a less energy consumption, the present invention relates to a production method for obtaining a copolymer by separating a solvent from a copolymer solution, the method including the following Steps A to C. Step A: a step of regulating a solid component concentration (Ts) of the copolymer solution to a range of (5≦Ts≦60) in terms of a mass %, Step B: a step of heating the copolymer (P) solution obtained in the Step A such that a temperature T (° C.) is in a specified range, and Step C: a step of discharging the copolymer solution heated in the Step B from a specified nozzle at a linear velocity of 1 to 100 m/sec to separate the solvent in an inert gas stream at 0 to 200° C.