Patent classifications
C08F236/18
Method for producing statistical copolymer containing chloroprene monomer unit and unsaturated nitrile monomer unit, statistical copolymer, latex and use of same
To provide a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit which has a satisfactory oil resistance. A method for producing a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit includes a step for conducting continuous addition or 10 cycles or more of intermittent portionwise addition of the chloroprene monomer after initiation of a polymerization reaction is provided. A rubber composition using a statistical copolymer according to the invention or a vulcanized molded article containing the rubber composition is excellent in terms of oil resistance, mechanical strength, compression set at a low temperature and flex fatigue resistance.
Method for producing statistical copolymer containing chloroprene monomer unit and unsaturated nitrile monomer unit, statistical copolymer, latex and use of same
To provide a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit which has a satisfactory oil resistance. A method for producing a statistical copolymer containing a chloroprene monomer unit and an unsaturated nitrile monomer unit includes a step for conducting continuous addition or 10 cycles or more of intermittent portionwise addition of the chloroprene monomer after initiation of a polymerization reaction is provided. A rubber composition using a statistical copolymer according to the invention or a vulcanized molded article containing the rubber composition is excellent in terms of oil resistance, mechanical strength, compression set at a low temperature and flex fatigue resistance.
Chloroprene rubber latex adhesive composition
Provided is a chloroprene rubber latex adhesive composition superior in initial adhesive strength and normal adhesive strength and also in thermal creep resistance with adherend. A chloroprene rubber latex adhesive composition includes a carboxy-modified chloroprene-based copolymer latex (A) containing a copolymer of chloroprene monomer and an ethylenic unsaturated carboxylic acid and a polyvinylalcohol, a chloroprene-based polymer latex (B) containing a chloroprene homopolymer or a copolymer of chloroprene monomer and other monomer and a rosin acid metal salt and a chlorinated polyolefin resin emulsion (C), wherein the content ratio of the carboxy-modified chloroprene-based copolymer latex (A) to the chloroprene-based polymer latex (B) is 80:20 to 20:80 as solid matter.
RUBBER COMPOSITION, VULCANIZED PRODUCT, AND VULCANIZED MOLDED ARTICLE
A rubber composition containing: 100 parts by mass of a chloroprene-based rubber; 0.50 to 4.0 parts by mass of a maleimide compound; and 0.10 to 2.0 parts by mass of an organic peroxide, a vulcanizate of this rubber composition, and a vulcanized molded article of this rubber composition.
RUBBER COMPOSITION, VULCANIZED PRODUCT, AND VULCANIZED MOLDED ARTICLE
A rubber composition containing: 100 parts by mass of a chloroprene-based rubber; 0.50 to 4.0 parts by mass of a maleimide compound; and 0.10 to 2.0 parts by mass of an organic peroxide, a vulcanizate of this rubber composition, and a vulcanized molded article of this rubber composition.
CHLOROPRENE COPOLYMER LATEX COMPOSITION AND MOLDED PRODUCT THEREOF
There is provided a chloroprene copolymer latex composition capable of obtaining a molded product having excellent mechanical properties and flexibility even when vulcanized and molded under milder conditions than before. A chloroprene copolymer latex composition contains a chloroprene copolymer latex (A), a metal oxide (B), a vulcanization accelerator (C), and an antioxidant (D). The chloroprene copolymer latex (A) is a latex containing particles of a chloroprene copolymer which is a copolymer of chloroprene (A-1), 2,3-dichloro-1,3-butadiene (A-2), and sulfur (A-3). The content of the sulfur (A-3) in the chloroprene copolymer is 0.1 part by mass or more and 1.0 part by mass or less when the total amount of the chloroprene (A-1) and the 2,3-dichloro-1,3-butadiene (A-2) is set to 100 parts by mass.
CHLOROPRENE COPOLYMER LATEX COMPOSITION AND MOLDED PRODUCT THEREOF
There is provided a chloroprene copolymer latex composition capable of obtaining a molded product having excellent mechanical properties and flexibility even when vulcanized and molded under milder conditions than before. A chloroprene copolymer latex composition contains a chloroprene copolymer latex (A), a metal oxide (B), a vulcanization accelerator (C), and an antioxidant (D). The chloroprene copolymer latex (A) is a latex containing particles of a chloroprene copolymer which is a copolymer of chloroprene (A-1), 2,3-dichloro-1,3-butadiene (A-2), and sulfur (A-3). The content of the sulfur (A-3) in the chloroprene copolymer is 0.1 part by mass or more and 1.0 part by mass or less when the total amount of the chloroprene (A-1) and the 2,3-dichloro-1,3-butadiene (A-2) is set to 100 parts by mass.
Chloroprene copolymer latex composition and molded product thereof
There is provided a chloroprene copolymer latex composition capable of obtaining a molded product having excellent mechanical properties and flexibility even when vulcanized and molded under milder conditions than before. A chloroprene copolymer latex composition contains a chloroprene copolymer latex (A), a metal oxide (B), a vulcanization accelerator (C), and an antioxidant (D). The chloroprene copolymer latex (A) is a latex containing particles of a chloroprene copolymer which is a copolymer of chloroprene (A-1), 2,3-dichloro-1,3-butadiene (A-2), and sulfur (A-3). The content of the sulfur (A-3) in the chloroprene copolymer is 0.1 part by mass or more and 1.0 part by mass or less when the total amount of the chloroprene (A-1) and the 2,3-dichloro-1,3-butadiene (A-2) is set to 100 parts by mass.
Chloroprene copolymer latex composition and molded product thereof
There is provided a chloroprene copolymer latex composition capable of obtaining a molded product having excellent mechanical properties and flexibility even when vulcanized and molded under milder conditions than before. A chloroprene copolymer latex composition contains a chloroprene copolymer latex (A), a metal oxide (B), a vulcanization accelerator (C), and an antioxidant (D). The chloroprene copolymer latex (A) is a latex containing particles of a chloroprene copolymer which is a copolymer of chloroprene (A-1), 2,3-dichloro-1,3-butadiene (A-2), and sulfur (A-3). The content of the sulfur (A-3) in the chloroprene copolymer is 0.1 part by mass or more and 1.0 part by mass or less when the total amount of the chloroprene (A-1) and the 2,3-dichloro-1,3-butadiene (A-2) is set to 100 parts by mass.
CHLOROPRENE COPOLYMER LATEX, METHOD FOR PRODUCING SAME, VULCANIZED PRODUCT, DIP MOLDED ARTICLE AND METHOD FOR PRODUCING SAME
A chloroprene copolymer latex containing a chloroprene copolymer having a structural unit derived from chloroprene and a structural unit derived from 2,3-dichloro-1,3-butadiene, in which a toluene insoluble content in the chloroprene copolymer is 50 to 95% by mass, and a modulus at 500% elongation of a film, which is obtained on a base material by dipping the base material in the chloroprene copolymer latex and then performing vulcanization at 100° C. for 30 minutes, according to JIS K 6251 is 4.0 MPa or less.