The present disclosure relates to a process for preparing an olefin-acrylate diblock copolymer, the process comprising: a) performing nitroxide-mediated polymerization (NMP) by combining NMP materials comprising an acrylate monomer and a nitroxide initiator, thereby forming a nitroxide macroinitiator; and b) combining end-capping-reaction materials comprising an alpha-substituted acrylate and the nitroxide macroinitiator, thereby forming the olefin-acrylate diblock copolymer.

Provided herein are antioxidant, thermally-responsive copolymer-based compositions and methods of making and using the compositions, e.g., for treatment of ischemia reperfusion injury in a patient. The copolymer comprises a hydrocarbyl backbone, and a plurality of pendant pyrrolidone, antioxidant radical, polyester oligomer, and N-alkyl amide groups.

The present disclosure provides nanostructure compositions and methods of producing nanostructure compositions. The nanostructure compositions comprise at least one population of nanostructures, at least one reactive diluent, at least one anaerobic stabilizer, and optionally at least one organic resin. The present disclosure also provides nanostructure films comprising a nanostructure layer and methods of making nanostructure films.

A surface modifying composition for modifying a surface of a formed product made of high-density polyethylene or ultra-high molecular weight polyethylene, the composition comprising: a copolymer having a unit of a first monomer having an aliphatic group having 10 or more carbon atoms and a unit of a second monomer having any of an amino group, an epoxy group, and an ether group, and a solvent having a boiling point of 100° C. or more and being at least one selected from the group consisting of a halogen-based solvent, an alkane solvent, a cycloalkane solvent, a dicycloalkane solvent, an aromatic solvent, and a nitro-based solvent.

A holographic recording medium composition comprising component (e): a compound having an isocyanate group or an isocyanate-reactive functional group and further having a nitroxyl radical group, wherein component (e) contains component (e-1) below: component (e-1): a compound having a heterobicyclic ring structure or a heterotricyclic ring structure, the heterobicyclic ring structure or the heterotricyclic ring structure being obtained by replacing a carbon atom in a bicyclic ring structure or a tricyclic ring structure by the nitroxyl radical group.

Processes for producing filled polyol compositions, such as polymer polyol compositions. The processes include reacting a polymerizable composition in the presence of a composition comprising a base polyol and an amine antioxidant, in which the amine antioxidant comprises a secondary diarylamine, a primary aromatic amide, a triazole, or a combination thereof.

A bifunctional catalyst and a preparation method therefor are provided. The bifunctional catalyst is prepared by providing carbon matrix, adding 0.01-10 mol/L platinum containing solution, 0.01-10 mol/L palladium containing solution, 0.01-10 mol/L silver containing solution, and 0.01-15 mol/L sodium citrate trihydrate solution to the carbon matrix for reacting at 20° C. to 80° C. for 0.5 h to 24 h to obtain a mixed solution, and adding reducing agent to the mixed solution for reacting for 0.5 h to 30 h, and centrifuging and drying so as to obtain the bifunctional catalyst.

Filled polyol compositions that include a dispersion of polymer particles in a base polyol, in which the filled polyol composition further includes a triazole antioxidant. Methods for producing such filled polyol compositions are also described, as well as use of such filled polyol compositions in the production of polyurethane foams.

The present invention relates to a polymer composition comprising a polymer comprising methyl methacrylate, (meth)acrylic acid and styrene monomers. In particular, the present invention relates to a polymer composition comprising a polymer comprising methyl methacrylate, (meth)acrylic acid and styrene monomers, said composition having particularly advantageous compromises of heat-resistant, fluidity, scratch-resistant and chemical-resistant properties. The present invention also relates to a molded or extruded object comprising a polymer comprising methyl methacrylate, (meth)acrylic acid and of styrene monomers, and the use of these objects.

Initiator/mediator chemistry for latent imaging polymers for volume Bragg gratings is provided. Light mediated chemistry including the use of nitroxides allows a first step imaging to occur, where a light induced pattern is recorded in the material, without the grating being apparent. A second bleaching/developing step completes the curing process and reveals the grating.