The present invention relates to a metallocene compound having novel structure which can provide various selectivity and activity to polyolefin copolymers, a preparation method thereof, and a preparation method of polyolefin using the metallocene compound.

The present invention relates to a metallocene compound having novel structure which can provide various selectivity and activity to polyolefin copolymers, a preparation method thereof, and a preparation method of polyolefin using the metallocene compound.

A door assembly. The door assembly may include at least one door panel and a door frame having a plurality of frame members including a header and a pair of side jambs. The invention may also be considered a frame member. The frame member may include a core; and a two-piece top piece adjoining the core to form a structural member. The core and the top piece may be a composite of cellulosic material and at least one other material. The door assembly may further include at least one adjacent panel. Also disclosed are door jamb frame members and mullion frame members.

Methods for the production of heterophasic polymers in gas and slurry phase polymerization processes, and polymer compositions made therefrom, are disclosed herein.

A styrene resin having a syndiotactic structure, with an endothermic amount in a range of 175 to 260° C. of less than 30% based on the total endothermic amount, and a styrene resin composition containing 50 to 95% by mass of a thermoplastic resin composition and 5 to 50% by mass of a glass filler, the thermoplastic resin composition containing 100 parts by mass containing 80 to 100% by mass of a styrene resin having a syndiotactic structure and 0 to 20% by mass of a rubbery elastic material, 0.2 to 2.0 parts by mass of at least one kind of an antioxidant selected from a phenol-based antioxidant and a sulfur antioxidant, 1.5 to 5.0 parts by mass of at least one kind of a compound selected from a polyphenylene ether or a modified polyphenylene ether, and at least one kind selected from a nucleating agent or a release agent.

A styrene resin having a syndiotactic structure, with an endothermic amount in a range of 175 to 260° C. of less than 30% based on the total endothermic amount, and a styrene resin composition containing 50 to 95% by mass of a thermoplastic resin composition and 5 to 50% by mass of a glass filler, the thermoplastic resin composition containing 100 parts by mass containing 80 to 100% by mass of a styrene resin having a syndiotactic structure and 0 to 20% by mass of a rubbery elastic material, 0.2 to 2.0 parts by mass of at least one kind of an antioxidant selected from a phenol-based antioxidant and a sulfur antioxidant, 1.5 to 5.0 parts by mass of at least one kind of a compound selected from a polyphenylene ether or a modified polyphenylene ether, and at least one kind selected from a nucleating agent or a release agent.

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.

A machine direction oriented film comprising a multimodal copolymer of ethylene and at least two alpha-olefin-comonomers having: a) a density of from 906 to 925 kg/m.sup.3 determined according to ISO 1183, b) an MFR.sub.21 of 10-200 g/10 min determined according to ISO1133, wherein the multimodal copolymer of ethylene comprises c) a first copolymer of ethylene and a first alpha-olefin comonomer having 4 to 10 carbon atoms; and d) a second copolymer of ethylene having an alpha-olefin comonomer different from the first copolymer, said second alpha-olefin comonomer having 6 to 10 carbon atoms.

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.