C08F2500/16

STYRENE RESIN, STYRENE RESIN COMPOSITION, MOLDED ARTICLE THEREOF, AND STYRENE RESIN PRODUCTION METHOD
20230056902 · 2023-02-23 · ·

A styrene resin having a syndiotactic structure, with an endothermic amount in a range of 175 to 260° C. of less than 30% based on the total endothermic amount, and a styrene resin composition containing 50 to 95% by mass of a thermoplastic resin composition and 5 to 50% by mass of a glass filler, the thermoplastic resin composition containing 100 parts by mass containing 80 to 100% by mass of a styrene resin having a syndiotactic structure and 0 to 20% by mass of a rubbery elastic material, 0.2 to 2.0 parts by mass of at least one kind of an antioxidant selected from a phenol-based antioxidant and a sulfur antioxidant, 1.5 to 5.0 parts by mass of at least one kind of a compound selected from a polyphenylene ether or a modified polyphenylene ether, and at least one kind selected from a nucleating agent or a release agent.

STYRENE RESIN, STYRENE RESIN COMPOSITION, MOLDED ARTICLE THEREOF, AND STYRENE RESIN PRODUCTION METHOD
20230056902 · 2023-02-23 · ·

A styrene resin having a syndiotactic structure, with an endothermic amount in a range of 175 to 260° C. of less than 30% based on the total endothermic amount, and a styrene resin composition containing 50 to 95% by mass of a thermoplastic resin composition and 5 to 50% by mass of a glass filler, the thermoplastic resin composition containing 100 parts by mass containing 80 to 100% by mass of a styrene resin having a syndiotactic structure and 0 to 20% by mass of a rubbery elastic material, 0.2 to 2.0 parts by mass of at least one kind of an antioxidant selected from a phenol-based antioxidant and a sulfur antioxidant, 1.5 to 5.0 parts by mass of at least one kind of a compound selected from a polyphenylene ether or a modified polyphenylene ether, and at least one kind selected from a nucleating agent or a release agent.

Processes for producing high propylene content PEDM using tetrahydroindacenyl catalyst systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C.sub.3-C.sub.40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for producing high propylene content PEDM using tetrahydroindacenyl catalyst systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C.sub.3-C.sub.40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is −28° C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene-diene terpolymer typically comprising from 30 to 55 mol % ethylene, from 69.09 to 45 mol % C.sub.3 to C.sub.40 comonomer, and from 0.01 to 7 mol % diene wherein the Tg of the terpolymer is −28° C. or less. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.

SYNDIOTACTIC PROPYLENE-BASED ETHYLENE- PROPYLENE COPOLYMERS

Provided is syndiotactic polypropylene-based ethylene-propylene copolymers comprising a) 5 to 15% by weight of ethylene and 85 to 95% by weight of propylene; b) 60 to 90% rr triads; c) Mw (LS) of 10 to 250 kg/mol; and d) no substantial melting peak, wherein the heat of fusion of the peak is 5 J/g or less as determined by differential scanning calorimetry at a scan rate of 10° C./min (ASTM D3418-03).

SYNDIOTACTIC PROPYLENE-BASED ETHYLENE- PROPYLENE COPOLYMERS

Provided is syndiotactic polypropylene-based ethylene-propylene copolymers comprising a) 5 to 15% by weight of ethylene and 85 to 95% by weight of propylene; b) 60 to 90% rr triads; c) Mw (LS) of 10 to 250 kg/mol; and d) no substantial melting peak, wherein the heat of fusion of the peak is 5 J/g or less as determined by differential scanning calorimetry at a scan rate of 10° C./min (ASTM D3418-03).

Metallocene catalyst systems with chemically-treated solid oxides for producing ethylene-based plastomers and elastomers

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.

Metallocene Catalyst Systems With Chemically-Treated Solid Oxides For Producing Ethylene-Based Plastomers And Elastomers
20220356278 · 2022-11-10 ·

Polymerization processes for producing ethylene-based plastomers and elastomers having densities less than 0.91 g/cm.sup.3 utilize a metallocene-based catalyst system containing a chemically-treated solid oxide. These polymerization processes can be conducted in a slurry reactor, a solution reactor, and/or a gas phase reactor. Ethylene polymers produced from the polymerization process can be characterized by a density of less than 0.91 g/cm.sup.3, a CY-a parameter of less than 0.2, and a ratio of HLMI/MI of at least 30, or a density less than 0.91 g/cm.sup.3, a CY-a parameter from 0.25 to 0.75, and a ratio of Mw/Mn from 2 to 3.