C08F255/08

Process for preparing crosslinked polyolefin particles

Provided is a method of making a polymeric composition comprising (a) providing a dispersion of initial polyolefin particles in an aqueous medium, wherein the initial polyolefin particles comprise (i) one or more hydrocarbon polyolefin, (ii) one or more non-hydrocarbon polyolefin, and (iii) one or more crosslinking agent; (b) contacting the initial polyolefin particles with a peroxide initiator to form crosslinked polyolefin particles.

FILM AND ELECTRONIC DEVICE COMPRISING SAME
20230103244 · 2023-03-30 ·

Provided are a film and an electric device comprising the same. The film comprises at least one modified polyolefin resin layer. A resin forming the modified polyolefin resin layer comprises 1-100% of modified polyolefin resin. A main chain in the modified polyolefin resin is an ethylene-α-olefin copolymer. A grafted branched chain in the modified polyolefin resin is selected from a compound formed by a vinyl monomer comprising one or more of anhydride group, hydroxyl, ester group, carbonyl, acylamino, pyridyl, epoxy, pyrrolidonyl and glycidyl. A molecular weight of the grafted branched chain is 150-8000 g/mol. The film prepared from the modified POE layer with the main chain and the grafted branched chain has excellent anti-PID performance. The layers have a better adhesive property without a laminated interface therebetween. The co-extruded film further has an excellent water vapor barrier property, a relatively high insulating property and a relatively high light transmittance.

FILM AND ELECTRONIC DEVICE COMPRISING SAME
20230103244 · 2023-03-30 ·

Provided are a film and an electric device comprising the same. The film comprises at least one modified polyolefin resin layer. A resin forming the modified polyolefin resin layer comprises 1-100% of modified polyolefin resin. A main chain in the modified polyolefin resin is an ethylene-α-olefin copolymer. A grafted branched chain in the modified polyolefin resin is selected from a compound formed by a vinyl monomer comprising one or more of anhydride group, hydroxyl, ester group, carbonyl, acylamino, pyridyl, epoxy, pyrrolidonyl and glycidyl. A molecular weight of the grafted branched chain is 150-8000 g/mol. The film prepared from the modified POE layer with the main chain and the grafted branched chain has excellent anti-PID performance. The layers have a better adhesive property without a laminated interface therebetween. The co-extruded film further has an excellent water vapor barrier property, a relatively high insulating property and a relatively high light transmittance.

Molding material and method for producing resin molded body using same

A molding material including a resin material that has a graft chain containing constituent units derived from a fluorine-containing compound and a non-fluorinated compound. The graft chain thereof may be formed, for example, using ionizing radiation.

Molding material and method for producing resin molded body using same

A molding material including a resin material that has a graft chain containing constituent units derived from a fluorine-containing compound and a non-fluorinated compound. The graft chain thereof may be formed, for example, using ionizing radiation.

HIGH SPEED CROSS-LINKING OF GRAFTED PLASTOMERS

The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-α-olefin plastomer having—a density of from 850 kg/m.sup.3 to 900 kg/m.sup.3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-α-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt.-% with respect to the grafted ethylene-α-olefin plastomer; (c) contacting said grafted ethylene-α-olefin plastomer with 2 to 8 wt.-% of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-α-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.

HIGH SPEED CROSS-LINKING OF GRAFTED PLASTOMERS

The present invention discloses a process for providing a cross-linked composition, the process comprising the steps of (a) providing an ethylene-α-olefin plastomer having—a density of from 850 kg/m.sup.3 to 900 kg/m.sup.3; and—an melt flow rate (ISO 1133, 2.16 kg, 190° C.) of 0.3 to 50 g/10 min; (b) grafting the ethylene-α-olefin plastomer with silane crosslinker such that the content of silane crosslinker is in the range of 0.1 to 10.0 wt.-% with respect to the grafted ethylene-α-olefin plastomer; (c) contacting said grafted ethylene-α-olefin plastomer with 2 to 8 wt.-% of a tin-free silane crosslinking catalyst with respect to the resulting mixture of grafted ethylene-α-olefin plastomer and tin-freesilane crosslinking catalyst, wherein said tin-free catalyst comprises a Brönsted acid at 23° C. and 50% relative humidity for at least 15 minutes thus forming a cross-linked composition, wherein gel content of said cross-linked composition after 15 min is at least 60%.

Composition and method for lamination of silicon dominant electrodes

Disclosed are maleic anhydride-grafted cyclic olefin copolymers, methods for preparing maleic anhydride-grafted cyclic olefin copolymers, low temperature methods for laminating anodes comprising the maleic anhydride-grafted cyclic olefin copolymers, and anodes and alkali ion batteries that comprise the maleic anhydride-grafted cyclic olefin copolymers.

Composition and method for lamination of silicon dominant electrodes

Disclosed are maleic anhydride-grafted cyclic olefin copolymers, methods for preparing maleic anhydride-grafted cyclic olefin copolymers, low temperature methods for laminating anodes comprising the maleic anhydride-grafted cyclic olefin copolymers, and anodes and alkali ion batteries that comprise the maleic anhydride-grafted cyclic olefin copolymers.

Synthesis of functional polyisobutylene-containing oligomers and polymers

Disclosed are single step and multi-step methods of making functional polyisobutylene (PIB)-containing oligomers and polymers and the materials made thereby. In the single step method a functional group containing PIB oligomer or polymer is made under cationic polymerization conditions in a direct, one step reaction. In the multi-step method a functional group containing PIB oligomer or polymer is made in a two-step process. The first step is performed under cationic polymerization conditions. The second step is performed under non-cationic polymerization conditions.