The present invention provides a method for crosslinking an acrylic emulsion with a (meth)acrylate monomer or a (meth)acrylate oligomer including adding a base acrylic emulsion to a vessel, adding at least one (meth)acrylate crosslinker to the vessel, incorporating the at least one (meth)acrylate crosslinker into the base acrylic emulsion to create a two-phase system including water and a phase including crosslinkers of the at least one (meth)acrylate crosslinker inside acrylic emulsion particles of the base acrylic emulsion, applying the two-phase system to a surface, and curing the two-phase system to create a final system including a continuous film and crosslinked crosslinkers.

Polyvinyl alcohol-stabilized (meth)acrylic ester polymers, processes for preparing and uses for the same. Where the polyvinyl alcohol-stabilized (meth)acrylic ester polymers have particle sizes Dw of from 100 to 900 nm in the form of aqueous dispersions or water-redispersible powders. Where the (meth)acrylic ester polymers are based on (a) 1% to 30% by weight of one or more vinyl esters of carboxylic acids having 5 to 15 carbon atoms, (b) 20% to 80% by weight of one or more (meth)acrylic esters, wherein the homopolymer of which has a glass transition temperature Tg of ≤20° C., (c) 10% to 70% by weight of one or more (meth)acrylic esters, wherein the homopolymer of which has a glass transition temperature Tg of ≥50° C., and (d) optionally one or more further ethylenically unsaturated monomers. The percentages by weight are based on the total weight of the (meth)acrylic ester polymers.

Polyvinyl alcohol-stabilized (meth)acrylic ester polymers, processes for preparing and uses for the same. Where the polyvinyl alcohol-stabilized (meth)acrylic ester polymers have particle sizes Dw of from 100 to 900 nm in the form of aqueous dispersions or water-redispersible powders. Where the (meth)acrylic ester polymers are based on (a) 1% to 30% by weight of one or more vinyl esters of carboxylic acids having 5 to 15 carbon atoms, (b) 20% to 80% by weight of one or more (meth)acrylic esters, wherein the homopolymer of which has a glass transition temperature Tg of ≤20° C., (c) 10% to 70% by weight of one or more (meth)acrylic esters, wherein the homopolymer of which has a glass transition temperature Tg of ≥50° C., and (d) optionally one or more further ethylenically unsaturated monomers. The percentages by weight are based on the total weight of the (meth)acrylic ester polymers.

The invention discloses an adhesion agent composition comprising at least one C.sub.3-C.sub.200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

The invention discloses an adhesion agent composition comprising at least one C.sub.3-C.sub.200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.

Described herein are a water-borne core-shell polymer, a method for preparing the same, and the applications thereof. Also described herein is a water-borne styrene/vinyl acetate (St/Vae) core-shell polymer which is suitable for corrugated board ink applications. The water-borne emulsion containing the core-shell polymer shows superior covering property and color strength.

Described herein are a water-borne core-shell polymer, a method for preparing the same, and the applications thereof. Also described herein is a water-borne styrene/vinyl acetate (St/Vae) core-shell polymer which is suitable for corrugated board ink applications. The water-borne emulsion containing the core-shell polymer shows superior covering property and color strength.

An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a vinyl ester of a C.sub.1 to C.sub.18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C.sub.1 to C.sub.18 carboxylic acid and a C.sub.2 to C.sub.8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg≤20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.

An aqueous copolymer dispersion is obtained by a multi-stage emulsion polymerization process comprising polymerizing in a reaction zone in a first polymerization stage a first monomer composition comprising at least 88 wt % of a vinyl ester of a C.sub.1 to C.sub.18 carboxylic acid and up to 12 wt % ethylene to produce a first stage polymer having Tg>20° C.; and polymerizing in the reaction zone, in a second polymerization stage and in the presence of the first stage polymer, a second monomer composition comprising a vinyl ester of a C.sub.1 to C.sub.18 carboxylic acid and a C.sub.2 to C.sub.8 alkyl ester of (meth)acrylic acid to produce a second stage polymer having Tg≤20° C. Each of the polymerization stages is conducted in the presence of a stabilizing system comprising at least 0.1 wt % of a protective colloid and at least 0.05 wt % of an ionic surfactant.

The present invention provides: a novel production technique that enables production of a polymer whose molecular weight and molecular weight distribution are controlled and production of a polymer having a complicated structure in a desirably controlled manner using commercially available materials without using a radical polymerization initiator or a special material for use in living radical polymerization and without the need for strict polymerization conditions; and a radical polymerization initiating group-containing compound for use in the technique. The present invention relates to: a method for producing a polymer, the method including a polymerization step of mixing and warming (1) a radically polymerizable monomer, (2) an organic compound wherein at least one group that functions as a group for initiating polymerization of the monomer and that has a structure represented by formula 1 or formula 2 (X in the formula represents Cl or Br) is introduced in a molecule of the organic compound, and (3) an iodine-containing compound, thereby initiating, from the group having the structure, radical polymerization accompanied by a termination reaction; and the organic compound of (2) for use in the method. ##STR00001##