C08F299/06

PREPREG AND MOLDED ARTICLE
20230042045 · 2023-02-09 · ·

Provided is a prepreg containing a urethane (meth)acrylate (A), a polymerization initiator (B), and reinforcement fibers (C), characterized in that the polymerization initiator (B) is an alkyl peroxy ester compound having a 10-hour half-life temperature of 60° C. or higher and lower than 70° C. The prepreg has excellent storage stability and excellent moldability, even under the low-temperature molding condition of 110° C. or lower, and enables to obtain a molded article having excellent physical properties such as interlaminar shear strength. Therefore, the prepreg can be suitably used in automobile components, railway vehicle components, aerospace craft components, ship components, housing equipment components, sporting components, light vehicle components, building and civil engineering components, and casings of OA equipment and the like.

PREPREG AND MOLDED ARTICLE
20230042045 · 2023-02-09 · ·

Provided is a prepreg containing a urethane (meth)acrylate (A), a polymerization initiator (B), and reinforcement fibers (C), characterized in that the polymerization initiator (B) is an alkyl peroxy ester compound having a 10-hour half-life temperature of 60° C. or higher and lower than 70° C. The prepreg has excellent storage stability and excellent moldability, even under the low-temperature molding condition of 110° C. or lower, and enables to obtain a molded article having excellent physical properties such as interlaminar shear strength. Therefore, the prepreg can be suitably used in automobile components, railway vehicle components, aerospace craft components, ship components, housing equipment components, sporting components, light vehicle components, building and civil engineering components, and casings of OA equipment and the like.

WATER DISPERSION OF GEL PARTICLES, PRODUCING METHOD THEREOF, AND IMAGE FORMING METHOD
20180009927 · 2018-01-11 ·

A water dispersion of gel particles, in which the gel particles having a polymerizable group, having a three-dimensional crosslinked structure including at least one bond selected from a urethane bond and a urea bond, and including at least a photopolymerization initiator and a resin are dispersed in water, a method of producing the water dispersion, and an image forming method using the water dispersion.

WATER DISPERSION OF GEL PARTICLES, PRODUCING METHOD THEREOF, AND IMAGE FORMING METHOD
20180009927 · 2018-01-11 ·

A water dispersion of gel particles, in which the gel particles having a polymerizable group, having a three-dimensional crosslinked structure including at least one bond selected from a urethane bond and a urea bond, and including at least a photopolymerization initiator and a resin are dispersed in water, a method of producing the water dispersion, and an image forming method using the water dispersion.

MODIFIED THERMOPLASTIC POLYURETHANES AND METHODS OF EXTRUDING SAME
20230211536 · 2023-07-06 ·

Described herein are modified thermoplastic polyurethanes, methods of reactively extruding the modified thermoplastic polyurethanes, and methods of using the modified thermoplastic polyurethanes. The modified thermoplastic polyurethanes are mi-cro-crosslinked through reaction with a functional polyolefin, have significantly improved tensile strength and elongation compared to unmodified thermoplastic polyurethanes, and may be extruded.

Transparent resin substrate

A transparent resin substrate composed of a light-transmitting resin base sheet, and an underlying layer, a hard coat layer, and an antireflection coating formed sequentially on the base sheet. The antireflection coating includes a medium refractive index layer on the hard coat layer, and a low refractive index layer on the medium refractive index layer. The underlying layer is a cured product of a hexa- or higher functional urethane acrylate monomer. The hard coat layer is a cured product of a hard coat layer composition containing a polymerizable monomer containing 50% by mass or more of a tri- or lower functional urethane acrylate monomer, silica particles, a silane coupling agent, and a metal chelate compound. The medium refractive index layer is a cured product of a medium refractive index layer composition. The low refractive index layer is a particle-free cured product of a low refractive index layer composition.

Transparent resin substrate

A transparent resin substrate composed of a light-transmitting resin base sheet, and an underlying layer, a hard coat layer, and an antireflection coating formed sequentially on the base sheet. The antireflection coating includes a medium refractive index layer on the hard coat layer, and a low refractive index layer on the medium refractive index layer. The underlying layer is a cured product of a hexa- or higher functional urethane acrylate monomer. The hard coat layer is a cured product of a hard coat layer composition containing a polymerizable monomer containing 50% by mass or more of a tri- or lower functional urethane acrylate monomer, silica particles, a silane coupling agent, and a metal chelate compound. The medium refractive index layer is a cured product of a medium refractive index layer composition. The low refractive index layer is a particle-free cured product of a low refractive index layer composition.

Protective graft coating for application onto polyurethane for chemical resistance, stain resistance, abrasion resistance and U.V. resistance

This invention relates to a coating comprising prepolymer and monomers for application onto polyurethane for chemical resistance, abrasion resistance, water proof etc. Usually polyurethane is porous and does not have sufficient stain, abrasion and chemical resistance. The said coatings developed using technology of chemical grafting that involves the use of prepolymers, monomers, catalyst, graft initiator, wetting agents, fillers and other ingredients of the composition. The coating thus obtained when applied on the polyurethane allows obtaining graft polymerization, thereby forming a polymeric film chemically attached to the substrate. The polyurethane substrate is reacted with craft initiator which creates the reaction sites on the substrate via free radical mechanism. This in turn renders the substrate receptive to attachment of monomers/prepolymers forming polymeric film that is chemically bonded to the substrate which has then the desired property in terms of stain resistance, abrasion wear, crock, water, chemical resistance and other properties.

Protective graft coating for application onto polyurethane for chemical resistance, stain resistance, abrasion resistance and U.V. resistance

This invention relates to a coating comprising prepolymer and monomers for application onto polyurethane for chemical resistance, abrasion resistance, water proof etc. Usually polyurethane is porous and does not have sufficient stain, abrasion and chemical resistance. The said coatings developed using technology of chemical grafting that involves the use of prepolymers, monomers, catalyst, graft initiator, wetting agents, fillers and other ingredients of the composition. The coating thus obtained when applied on the polyurethane allows obtaining graft polymerization, thereby forming a polymeric film chemically attached to the substrate. The polyurethane substrate is reacted with craft initiator which creates the reaction sites on the substrate via free radical mechanism. This in turn renders the substrate receptive to attachment of monomers/prepolymers forming polymeric film that is chemically bonded to the substrate which has then the desired property in terms of stain resistance, abrasion wear, crock, water, chemical resistance and other properties.

Photo-curable resin composition for three-dimensional molding, method for three-dimensional molding using the same, and three-dimensional molded product

A photo-curable resin composition for three-dimensional molding which does not require a support material is provided and can be cured by light irradiation while being extruded from a nozzle through a simple FDM method to be stacked and molded in a short period of time. The photo-curable resin composition has a viscosity at 20° C. of 0.2 Pa.Math.s or more and a viscosity at 150° C. of 1000 Pa.Math.s or less.