C08F36/04

Cleaning liquid composition and method for cleaning polymerization apparatus using same
11549084 · 2023-01-10 · ·

A cleaning liquid composition is provided. More particularly, a cleaning liquid composition includes a transition metal compound represented by Chemical Formula 1 (see the detailed description of the present invention); and a hydrocarbon-based solvent, and a cleaning method of a polymerization apparatus using the same.

Modified Conjugated Diene-Based Polymer, Method for Preparing the Same and Rubber Composition Including the Same
20220403068 · 2022-12-22 · ·

The present invention relates to a modified conjugated diene-based polymer, a method for preparing the same and a rubber composition including the same, and relates to a modified conjugated diene-based polymer which is prepared by continuous polymerization and has excellent processability, a mooney large relaxation area of 300 MU-s to 1000 MU-s, and narrow molecular weight distribution, and if compounded into a rubber composition, shows improved tensile properties and viscoelasticity properties, particularly, a tan δ value at a high temperature (60° C.) among viscoelasticity properties, and excellent low hysteresis properties and fuel consumption properties, and a rubber composition including the same.

MODIFIED VINYLAROMATIC COPOLYMER, PRODUCTION METHOD THEREFOR, MODIFIED CONJUGATED DIENE COPOLYMER OBTAINED THEREFROM AND COMPOSITION THEREOF, CROSSLINKED RUBBER OBJECT, AND TIRE MEMBER

To provide a modified vinylaromatic copolymer which can be used in production of copolymer rubber and which has reactivity and solubility, and a copolymer rubber material obtained therefrom, which simultaneously has processability, strength, and homogeneity. The modified vinylaromatic copolymer is a copolymer containing a structural unit (a) derived from a divinylaromatic compound and a structural unit (b) derived from a monovinylaromatic compound, wherein the structural unit (a) at least partially includes the following crosslinked structural unit (a1), and a terminal is modified by a modification group having at least one functional group selected from the group consisting of an amino group, a hydroxyl group, and an alkoxysilyl group.

Polymer manufacturing method

Disclosed are a polymer having a narrow molecular weight distribution prepared by living radical and a polymer manufacturing method comprising a step of performing living radical polymerization using 0.005 to 0.5 parts by mass of an oxygen radical scavenger per 100 parts by mass of a radical polymerizable monomer.

Polymer manufacturing method

Disclosed are a polymer having a narrow molecular weight distribution prepared by living radical and a polymer manufacturing method comprising a step of performing living radical polymerization using 0.005 to 0.5 parts by mass of an oxygen radical scavenger per 100 parts by mass of a radical polymerizable monomer.

Method for functionalising a stereo-regular polydiene

Disclosed is a functionalizing method for the end functionalisation of trans-1,4 stereo-regular polydiene chains obtained by the coordination catalytic polymerisation of at least one conjugated diene monomer. It also relates to a polydiene having a trans-1,4 chain formation rate of at least 85%, preferably at least 90%, and an end functionalisation rate higher than 70%, preferably higher than 80%, and more preferably higher than 90%.

IN-SITU RUBBER MATRIXES FOR ELASTIC AND PHOTO-PATTERNABLE POLYMER SEMICONDUCTORS AND DIELECTRICS

Next-generation wearable electronics require enhanced mechanical robustness and device complexity. Besides previously reported softness and stretchability, desired merits for practical use include elasticity, solvent resistance, photo-patternability and high charge carrier mobility. The present embodiments provide a molecular design concept that simultaneously achieves all these targeted properties in both polymeric semiconductors and dielectrics, without compromising electrical performance. This is enabled by covalently-embedded in-situ rubber matrix (iRUM) formation through good mixing of iRUM precursors with polymer electronic materials, and finely-controlled composite film morphology built on azide crosslinking chemistry which leverages different reactivities with C—H and C═C bonds. The high covalent crosslinking density results in both superior elasticity and solvent resistance. When applied in stretchable transistors, the iRUM-semiconductor film retained its mobility after stretching to 100% strain, and exhibited record-high mobility retention of 1 cm.sup.2 V.sup.−1 s.sup.−1 after 1000 stretching-releasing cycles at 50% strain. The cycling life was stably extended to 5000 cycles, five times longer than all reported semiconductors.

Curable petroleum resin, preparation method therefor, and use thereof

The present invention relates to a curable petroleum resin, a preparation method therefor, and use thereof, wherein the curable petroleum resin comprises a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer and a repeating unit derived from a cyclic anhydride monomer, and wherein the curable petroleum resin is used as an additive for a reactive polyolefin-based adhesive composition to increase the adhesive strength to a polyolefin-based substrate used for various parts.

Lyotropic Gyroid Mesophase Compositions, Polymer Compositions Comprising the Same, Methods of Preparation Thereof, and Methods of Using the Same

The present disclosure relates, in part, to compositions comprising the compound of Formula (I), and polymerized compositions thereof. In certain embodiments, the compositions further comprise at least one compound of Formula (IIa) and Formula (IIb). In another aspect, the present disclosure relates to methods of preparation of the polymer compositions of the present disclosure, the method comprising contacting the compound of Formula (I) and a photoinitiator in the presence of a solvent to form a gyroid mesophase gel and irradiating the gyroid mesophase gel with UV light. In certain embodiments, the contacting further comprises at least one compound of Formula (IIa) and Formula (IIb).

CATALYTIC SYSTEM AND USE THEREOF, AND PREPARATION METHOD OF SYNDIOTACTIC 1,2-POLYBUTADIENE (s-PB)
20230192912 · 2023-06-22 ·

The present disclosure relates to the technical field of preparation of syndiotactic 1,2-polybutadiene (s-PB), in particular to a catalytic system and use thereof, and a preparation method of s-PB. In the present disclosure, the catalytic system includes an iron-containing organic compound, an azodicyano compound, an organoaluminum compound, and a free radical scavenger; where an iron element in the iron-containing organic compound, the azodicyano compound, the organoaluminum compound, and the free radical scavenger have a molar ratio of 1:(0.5-10):(5-100):(1-1000); and the free radical scavenger is selected from the group consisting of a sterically hindered phenol, a sterically hindered amine, and a phosphorus-containing antioxidant. The catalytic system can prepare the s-PB with a high activity at a high temperature, and the s-PB has a melting point of 60° C. to 130° C. with an extremely low gel content or even no gelation.