Provided are a curable resin composition including a near-ultraviolet light-absorbing organic compound, indium tin oxide particles, and a polymer having a constitutional unit represented by General Formula (P) and having an acidic group at one terminal, in which the near-ultraviolet light-absorbing organic compound is a compound that has a maximal value at 300 to 400 nm in an absorption spectrum in a wavelength region of 300 to 800 nm and does not substantially absorb light at a wavelength of 410 to 800 nm; a cured product formed of the curable resin composition; a diffractive optical element; and a multilayer diffractive optical element.

##STR00001##

Ar.sup.P represents an aryl group and L.sup.P and R.sup.P1 represent a specific group.

A fluorine-containing polymer has a fluorine content of 50% by mass or more, a degree of unsaturation of 0.1 mEq/g or more, and a glass transition temperature of −20° C. or higher, and the relationship between the maximum value E*1 of the complex elastic modulus in the range of from −50° C. to (glass transition temperature−10° C.) and the minimum value E*2 of the complex elastic modulus in the range of from (glass transition temperature+10° C.) to 250° C. satisfies the following inequality: E*2/E*1≤0.01.

A fluorine-containing polymer has a fluorine content of 50% by mass or more, a degree of unsaturation of 0.1 mEq/g or more, and a glass transition temperature of −20° C. or higher, and the relationship between the maximum value E*1 of the complex elastic modulus in the range of from −50° C. to (glass transition temperature−10° C.) and the minimum value E*2 of the complex elastic modulus in the range of from (glass transition temperature+10° C.) to 250° C. satisfies the following inequality: E*2/E*1≤0.01.

To provide a composition having a very low refractive index, an organic photoelectronic element using the composition, and simple methods for producing such a composition and an organic photoelectronic element. A composition comprising a fluorinated polymer, an organic semiconductor material and a dopant.

To provide a composition having a very low refractive index, an organic photoelectronic element using the composition, and simple methods for producing such a composition and an organic photoelectronic element. A composition comprising a fluorinated polymer, an organic semiconductor material and a dopant.

An oligomer, composition, and composite material employing the same are provided. The oligomer can be a reaction product of a reactant (a) and a reactant (b). The reactant (a) is a reaction product of a reactant (c) and a reactant (d). The reactant (b) can be

##STR00001##

or a combination thereof, wherein a is 0 or 1, and R.sup.1 is independently hydrogen

##STR00002##

or and wherein b is 0-6; c is 0 or 1; and, d is 0-6. The reactant (c) is

##STR00003##

wherein R.sup.2 is C.sub.5-10 alkyl group. The reactant (d) is

##STR00004##

wherein e is 0-10.

An unsaturated deoxybenzoin compound has the structure (I)

##STR00001##

wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, and n are defined herein. A polymer including at least one group derived from a deoxybenzoin compound having structure (I), (II), or a combination thereof

##STR00002##

is also described, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, and n are defined herein.

An unsaturated deoxybenzoin compound has the structure (I)

##STR00001##

wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, and n are defined herein. A polymer including at least one group derived from a deoxybenzoin compound having structure (I), (II), or a combination thereof

##STR00002##

is also described, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, and n are defined herein.

In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprise 10-70 wt. % or 20-40 wt. % of a cyclopolymerizable monomer, based on the total weight of the ink. The cyclopolymerizable monomer comprises an acrylate moiety and an ethenyl or ethynyl moiety, and the α-carbon of the acrylate moiety and the α-carbon of the ethenyl or ethynyl moiety may have a 1,5-, 1,6-, 1,7-, or 1,8-relationship. Additionally, an ink described herein can have a viscosity of 1600 centipoise (cP) or less at 30° C., or of 500 cP or less at 30° C. and can be used to print a desired 3D article having mechanical properties similar to those of articles formed from thermoplastic materials.

In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprise 10-70 wt. % or 20-40 wt. % of a cyclopolymerizable monomer, based on the total weight of the ink. The cyclopolymerizable monomer comprises an acrylate moiety and an ethenyl or ethynyl moiety, and the α-carbon of the acrylate moiety and the α-carbon of the ethenyl or ethynyl moiety may have a 1,5-, 1,6-, 1,7-, or 1,8-relationship. Additionally, an ink described herein can have a viscosity of 1600 centipoise (cP) or less at 30° C., or of 500 cP or less at 30° C. and can be used to print a desired 3D article having mechanical properties similar to those of articles formed from thermoplastic materials.