C08F4/58

Functional initiator for anionic polymerization

An ethylenically unsaturated polymer includes at a terminus the radical of an allylic compound that includes a functional group free of active hydrogen atoms that is bonded to the allylic C atom through a S, P, Si or Sn atom and a vinyl aromatic compound. The polymer can be used as a component of a variety of elastomeric compounds used in the production of vulcanizates.

Cyclic organosilicon compounds as electron donors in Zeigler-Natta catalyst systems for producing propylene polymer having high melt-flowability

Cyclic organosilicon compounds having a structure represented by the general formula ##STR00001##
and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.

CYCLIC ORGANOSILICON COMPOUNDS AS ELECTRON DONORS IN ZEIGLER ?NATTA CATALYST SYSTEMS FOR PRODUCING PROPYLENE POLYMER HAVING HIGH MELT-FLOWABILITY
20230088145 · 2023-03-23 ·

Cyclic organosilicon compounds having a structure represented by the general formula

##STR00001##

and a method for using thereof as a component of catalysts for producing propylene polymer having a very high melt-flowability are disclosed. The cyclic organosilicon compounds are employed as external electron donors in Ziegler-Natta catalyst systems to dramatically improve the hydrogen response, and therefore the catalyst systems can be used to prepare polymer having high melt-flowability and high isotacticity at high yield.

GLASS POWDER AND CHEMICAL POLYMERIZATION INITIATOR
20220332857 · 2022-10-20 ·

One aspect of the invention includes a glass powder for a chemical polymerization initiator, the glass powder including aluminum, silicon, and at least one of copper or vanadium.

GLASS POWDER AND CHEMICAL POLYMERIZATION INITIATOR
20220332857 · 2022-10-20 ·

One aspect of the invention includes a glass powder for a chemical polymerization initiator, the glass powder including aluminum, silicon, and at least one of copper or vanadium.

Organic Borate-Based Catalyst, Method For Preparing Isobutene Oligomer Using The Same And Isobutene Oligomer Prepared Thereby

The present invention relates to an organic borate-based catalyst including a compound represented by the following Formula 1 and a hydroxyl group-containing compound, a method for preparing an isobutene oligomer using the same and an isobutene oligomer prepared thereby:

##STR00001##

wherein R.sub.0, R.sub.1 to R.sub.4, o, p, q and r are described therein.

Organic Borate-Based Catalyst, Method For Preparing Isobutene Oligomer Using The Same And Isobutene Oligomer Prepared Thereby

The present invention relates to an organic borate-based catalyst including a compound represented by the following Formula 1 and a hydroxyl group-containing compound, a method for preparing an isobutene oligomer using the same and an isobutene oligomer prepared thereby:

##STR00001##

wherein R.sub.0, R.sub.1 to R.sub.4, o, p, q and r are described therein.

CATALYST SYSTEM

A catalyst system comprising a combination of a tin-based moisture-cure catalyst, a titanium(IV) compound that is titanium dioxide or a titanium alkoxide, and zinc oxide. A catalyst masterbatch comprising the catalyst system and a carrier resin. A moisture-curable prepolymer formulation comprising the catalyst masterbatch and a (hydrolyzable silyl group)-functional polyolefin prepolymer. Methods of making and using same. Cured polymer products made therefrom. Articles containing or made from same.

CATALYST SYSTEM

A catalyst system comprising a combination of a tin-based moisture-cure catalyst, a titanium(IV) compound that is titanium dioxide or a titanium alkoxide, and zinc oxide. A catalyst masterbatch comprising the catalyst system and a carrier resin. A moisture-curable prepolymer formulation comprising the catalyst masterbatch and a (hydrolyzable silyl group)-functional polyolefin prepolymer. Methods of making and using same. Cured polymer products made therefrom. Articles containing or made from same.

HYDROCARBYL-MODIFIED METHYLALUMINOXANE COCATALYSTS FOR BIS-PHENYLPHENOXY METAL-LIGAND COMPLEXES

Processes of polymerizing olefin monomers. The process comprising reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: an activator; hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum compounds AlR.sup.A1R.sup.B1R.sup.C1 based on the total moles of aluminum, where R.sup.A1, R.sup.B1, and R.sup.C1 are independently linear (C.sub.1-C.sub.40)alkyl, branched (C.sub.1-C.sub.40)alkyl, or (C.sub.6-C.sub.40)aryl; and one or more metal-ligand complexes according to formula (1):

##STR00001##