C08F4/6028

PRODUCTION METHOD OF OLEFIN (CO)POLYMER CONTAINING CONSTITUENT UNIT DERIVED FROM 1-BUTENE

The purpose of the present invention is to provide a method for efficiently producing an olefin (co)polymer containing a constituent unit derived from 1-butene, the (co)polymer having a molecular weight that is sufficiently high even for high temperature conditions that are beneficial for industrial production methods. This purpose can be achieved by means of a method for producing an olefin (co)polymer containing a constituent unit derived from 1-butene, wherein at least 1-butene and, if necessary, an α-olefin having 2 or more carbon atoms (excluding 1-butene) and other monomers are (co)polymerized in the presence of an olefin polymerization catalyst that contains (A) a crosslinked metallocene compound represented by general formula [I] and (B) at least one type of compound selected from among (b-1) an organic aluminum oxy compound, (b-2) a compound that forms an ion pair upon a reaction with the crosslinked metallocene compound (A), and (b-3) an organic aluminum compound, at a polymerization temperature of 55-200° C. and a polymerization pressure of 0.1-5.0 MPaG.

Tires Comprising Rubber Compounds that Comprise Propylene-a-Olefin-Diene Polymers

Rubber compounds that comprise rubber and propylene-a-olefin-diene (PE(D)M) polymers may be useful in tire-related articles (e.g., tire sidewalls, inner tubes, and innerliners). Such a rubber compound may comprise: about 5 phr to about 50 phr of the PE(D)M polymer that comprises about 65 wt % to about 99.5 wt % propylene, about 0.5 wt % to about 35 wt % a-olefin that is not propylene, and 0 wt % to about 20 wt % diene, said wt % based on the weight of the PE(D)M polymer, and about 50 parts per hundred parts rubber (phr) to about 95 phr of a rubber that comprises one selected from the group consisting of the halogenated isobutylene-based rubber is selected from the group consisting of: natural rubber, polyisoprene rubber, poly(styrene-co-butadiene) rubber, polybutadiene rubber, poly(isoprene-co-butadiene) rubber, styrene-isoprene-butadiene rubber, butyl rubber, star branched butyl rubber, isobutylene-isoprene rubber, poly(isobutylene-co-alkylstyrene), a halogenated isobutylene-based rubber, polychloroprene rubber, nitrile rubber, and any combination thereof.

Ethylene-Based Copolymer and Propylene-Alpha-Olefin-Diene Compositions for Use in Layered Articles

An elastomeric composition is provided that includes from 1 to 100 parts by weight per hundred parts by weight rubber (phr) of a first propylene-α-olefin-diene (PEDM) terpolymer comprising 70 wt % to 92.5 wt % propylene, 7.5 wt % to 30 wt % a C2 or C4-C12 α-olefin, and 3.5 wt % to 20 wt % diene, said wt % based on the weight of the PEDM terpolymer. The PEDM terpolymer V may have a Mooney viscosity (ML(1+4)) of 25 MU to 100 MU. The composition may further include from 0 to 99 phr of an ethylene-based copolymer comprising 40 wt % to 95 wt % ethylene.

Ethylene-Based Copolymer and Propylene-Alpha-Olefin-Diene Compositions for Use in Layered Articles

An elastomeric composition suitable for use in belts like transmission belts may comprise: from 5 to 100 phr of a propylene-α-olefin-diene (PEDM) terpolymer comprising 80 wt % to 97.5 wt % propylene, 2.5 wt % to 20 wt % a-olefin, and 0.5 wt % to 10 wt % diene, said wt % based on the weight of the PEDM terpolymer, and wherein the PEDM terpolymer has (a) Mooney viscosity (ML(1+4)) of 1 MU to 60 MU, (b) melt flow rate of 0.5 g/min to 100 g/min, and (c) a weight average molecular weight to n-average molecular weight (Mw/Mn) ratio of 1.5 to 3.0; and from 60 to 95 phr of an ethylene-based copolymer comprising 0 wt % to 95 wt % ethylene, 0 wt % to 10 wt % of one or more dienes, and 5 wt % to 60 wt % C3 to C12 α-olefin, said wt % based on the total weight of the ethylene-based copolymer.

Pressure Sensitive Adhesives Comprising Propylene-Ethylene(-Diene) Copolymers

A pressure-sensitive adhesive may comprise: about 18 wt % to about 90 wt % of a propylene-ethylene(-diene) (PE(D)M) copolymer; about 10 wt % to about 65 wt % of a tackifier; and 0 wt % to about 40 wt % of an oil. The PE(D)M copolymer may comprise: (a) about 60 wt % to about 99 wt % propylene, (b) about 1 wt % to about 40 wt % ethylene or a C4 to C22 alpha-olefin, and (c) 0 wt % to about 20 wt % diene, wherein the PE(D)M copolymer has a heat of fusion of about 15 J/g or less.

Method for Purifying Polyalkylaluminoxane-Containing Solution Using Hydroxy Group-Containing Compound and Catalyst Composition Using the Same

The present invention relates to a method for purifying a polyalkylaluminoxane-containing solution using a hydroxy group-containing compound, a method for producing a catalyst composition using the method, a catalyst composition produced by the production method, and a method for producing an olefin polymer using the catalyst composition.

High Propylene Content EP Having Low Glass Transition Temperatures

The present disclosure provides methods for producing an olefin polymer by contacting a C.sub.3-C.sub.40 olefin and ethylene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted tetrahydro-s-indacenyl group and obtaining a C.sub.3-C.sub.40 olefin-ethylene copolymer typically comprising from 0.5 to 43 wt % ethylene, and from 99.5 to 57 wt % C.sub.3 to C.sub.40 comonomer wherein the Tg of the terpolymer is from 0 to −60° C.

Method for Preparing Liquid Rubber and Liquid Rubber Prepared Therefrom

The present invention relates to a method for preparing a liquid rubber, and relates to a method for preparing a liquid rubber, including performing polymerization reaction of a conjugated diene-based monomer in the presence of an organic solvent and a catalyst composition (S10), wherein the catalyst composition includes a catalyst including a compound represented by the following Formula 1, and a liquid rubber prepared therefrom:

##STR00001## wherein R, R.sub.1 to R.sub.4, and o, p, q and r are described herein.

Mixed Catalyst Systems Containing Iron Tridentate Carbenes and Methods for Making Polymer Products Using Same

Disclosed herein are mixed catalyst systems including iron-containing catalyst compounds having a carbene ligand and another catalyst compound, as well as at least one activator. The iron-containing catalyst compounds can be asymmetric, while the other catalyst compound can be symmetric. In some embodiments, the other catalyst compound can be an iron-containing catalyst with a bisiminopyridyl ligand, which does not typically incorporate comonomers in copolymer synthesis. Processes for production of an ethylene alpha-olefin copolymers using these mixed catalyst systems are also disclosed. Ethylene-alpha-olefin copolymers so formed can have at least a portion of their alpha-olefin comonomer distribution increasing with increasing molecular weight, indication orthogonal compositional distribution.

Toluene Free Silica Supported Single-Site Metallocene Catalysts from In-Situ Supported MAO Formation in Aliphatic Solvents
20190127497 · 2019-05-02 ·

The present disclosure provides a method for preparing a catalyst system comprising contacting in an aliphatic solvent at a temperature of from less than 0 C. to 60 C. at least one support material having absorbed water and at least one hydrocarbyl aluminum compound to form a supported alumoxane (catalyst precursor) and contacting the supported alumoxane with at least one catalyst compound having a Group 3 through Group 12 metal atom or lanthanide metal atom. The supported alumoxane may be heated prior to contact with the catalyst compound.