C08F4/605

SPHERE-LIKE SUPER-MACROPOROUS MESOPOROUS MATERIAL AND POLYOLEFIN CATALYST CONTAINING SAME

Disclosed are a spherelike supermacroporous mesoporous material, a polyolefin catalyst, and a preparation method therefor and an olefin polymerization process. The spherelike supermacroporous mesoporous material has a twodimensional hexagonal ordered pore channel structures. The mesoporous material has an average pore size of 10 nm to 15 nm, a specific surface area of 300 m.sup.2/g to 400 m.sup.2/g, and an average particle size of 1 .Math.m to 3 .Math.m, based on the total mass of the mesoporous material. The mass content of water in the mesoporous material is < 1 ppm. The mass content of oxygen in the mesoporous material is < 1 ppm. When a polyolefin catalyst prepared with the mesoporous material as a carrier is used for an olefin polymerization reaction, the a polyolefin product with a narrow molecular weight distribution and a good melt index can be obtained.

SPHERE-LIKE SUPER-MACROPOROUS MESOPOROUS MATERIAL AND POLYOLEFIN CATALYST CONTAINING SAME

Disclosed are a spherelike supermacroporous mesoporous material, a polyolefin catalyst, and a preparation method therefor and an olefin polymerization process. The spherelike supermacroporous mesoporous material has a twodimensional hexagonal ordered pore channel structures. The mesoporous material has an average pore size of 10 nm to 15 nm, a specific surface area of 300 m.sup.2/g to 400 m.sup.2/g, and an average particle size of 1 .Math.m to 3 .Math.m, based on the total mass of the mesoporous material. The mass content of water in the mesoporous material is < 1 ppm. The mass content of oxygen in the mesoporous material is < 1 ppm. When a polyolefin catalyst prepared with the mesoporous material as a carrier is used for an olefin polymerization reaction, the a polyolefin product with a narrow molecular weight distribution and a good melt index can be obtained.

Catalyst composition for polymerizing conjugated diene monomer

There is provided a catalyst composition for polymerizing a conjugated diene monomer containing a rare earth complex having a specific structure and a specific compound.

Catalyst composition for polymerizing conjugated diene monomer

There is provided a catalyst composition for polymerizing a conjugated diene monomer containing a rare earth complex having a specific structure and a specific compound.

Sphere-like super-macroporous mesoporous material and polyolefin catalyst containing same

Disclosed are a sphere-like super-macroporous mesoporous material, a polyolefin catalyst, and a preparation method therefor and an olefin polymerization process. The sphere-like super-macroporous mesoporous material has a two-dimensional hexagonal ordered pore channel structure. The mesoporous material has an average pore size of 10 nm to 15 nm, a specific surface area of 300 m.sup.2/g to 400 m.sup.2/g, and an average particle size of 1 m to 3 m, based on the total mass of the mesoporous material. The mass content of water in the mesoporous material is <1 ppm. The mass content of oxygen in the mesoporous material is <1 ppm. When a polyolefin catalyst prepared with the mesoporous material as a carrier is used for an olefin polymerization reaction, a polyolefin product with a narrow molecular weight distribution and a good melt index can be obtained.

Sphere-like super-macroporous mesoporous material and polyolefin catalyst containing same

Disclosed are a sphere-like super-macroporous mesoporous material, a polyolefin catalyst, and a preparation method therefor and an olefin polymerization process. The sphere-like super-macroporous mesoporous material has a two-dimensional hexagonal ordered pore channel structure. The mesoporous material has an average pore size of 10 nm to 15 nm, a specific surface area of 300 m.sup.2/g to 400 m.sup.2/g, and an average particle size of 1 m to 3 m, based on the total mass of the mesoporous material. The mass content of water in the mesoporous material is <1 ppm. The mass content of oxygen in the mesoporous material is <1 ppm. When a polyolefin catalyst prepared with the mesoporous material as a carrier is used for an olefin polymerization reaction, a polyolefin product with a narrow molecular weight distribution and a good melt index can be obtained.