The invention relates to a process for the polymerization of olefins comprising the comprising the steps of a. Polymerizing olefins in a reaction mixture comprising monomers, diluent, processing as aids to prepare a product stream comprising polyolefins, monomers and diluent; b. Removing the polyolefins from the product stream to obtain a purge stream; c. Removing gaseous components from the purge stream to obtain a liquid fraction; d. Treating the liquid fraction with at least one ionic liquid to obtain a fraction containing unsaturated hydrocarbons; e. Recycling the fraction containing unsaturated hydrocarbons to the reaction mixture, optionally after purification of said fraction containing unsaturated hydrocarbons. The invention also relates to an olefin polymerization system comprising a polymerization reactor, a purge vessel, a vent gas recovery and an ionic liquid separator for separating liquid alkenes from liquid alkanes, wherein the liquid alkenes which are separated from the alkanes in the ionic liquid separator can be recycled to the polymerization reactor.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted α-olefin monomer and an amino-olefin monomer of formula H.sub.2C═CH(CH.sub.2).sub.n(CHR).sub.mNR′.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R′ is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted α-olefin monomer and an amino-olefin monomer of formula H.sub.2C═CH(CH.sub.2).sub.n(CHR).sub.mNR′.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R′ is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.

Processes are provided which include copolymerization using two different metallocene catalysts, one capable of producing high Mooney-viscosity polymers and one suitable for producing lower Mooney-viscosity polymers having at least a portion of vinyl terminations. The two catalysts may be used together in polymerization to produce copolymer compositions of particularly well-tuned properties. For instance, polymerizations are contemplated to produce high-Mooney metallocene polymers that exhibit excellent processability and elasticity, notwithstanding their high Mooney viscosity. Other polymerizations are also contemplated in which lower-Mooney metallocene polymers are produced, which also exhibit excellent processability and elasticity, while furthermore having excellent cure properties suitable in curable elastomer compound applications. Many of the contemplated polymerizations include controlling the ratio of the two metallocene catalysts used in the polymerization so as to obtain the desired Mooney viscosity and desired rheology (indicated by Mooney Relaxation Area) of the copolymer compositions.

A tire having a rubber tread comprises a first radially inner layer C1 and a second radially outer layer C2, the first and second layers being intended to be in contact with a ground on which they are running, in new or worn condition, in which the rubber composition of the first layer C1 comprises more than 50 phr of a copolymer of ethylene and of a 1,3-diene, a reinforcing filler and a plasticizing system, the 1,3-diene being 1,3-butadiene or isoprene and the ethylene units in the copolymer representing more than 50 mol % of all the monomer units of the copolymer.

A tire having a rubber tread comprises a first radially inner layer C1 and a second radially outer layer C2, the first and second layers being intended to be in contact with a ground on which they are running, in new or worn condition, in which the rubber composition of the first layer C1 comprises more than 50 phr of a copolymer of ethylene and of a 1,3-diene, a reinforcing filler and a plasticizing system, the 1,3-diene being 1,3-butadiene or isoprene and the ethylene units in the copolymer representing more than 50 mol % of all the monomer units of the copolymer.

A homopolypropylene has i) a molecular weight distribution of less than 2.4; ii) a melt index (measured at 230° C. under a load of 2.16 kg in accordance with ASTM D1238) of 5 to 3000 g/10 min; iii) a remaining stress ratio of 0.5% or less; and iv) a complex viscosity of 5 to 600 Pa.Math.s at an angular frequency of 1 rad/s and a complex viscosity of 5 to 300 Pa.Math.s at an angular frequency of 100 rad/s. A method for preparing the homopolyproylene is also provided. A molded article and a non-woven fabric are also provided.

This disclosure provides new methods for the design and development of ethylene polymerization catalysts, including Group 4 metallocene catalysts such as zirconocenes, which are based on an improved ability to adjust co-monomer incorporation into the polymer. Computational analyses with and without dispersion corrections revealed that designing catalyst scaffolds which induce stabilizing non-covalent dispersion type interactions with incoming -olefin co-monomers can be used to modulate co-monomer selectivity into the polyethylene chain. Demonstrated herein is a lack of correlation of computed G.sup. values against experimental G.sup. values when the dispersion correction (D3BJ) was disabled, and B3LYP was used in the absence of Grimme's D3 dispersion and Becke-Johnson (BJ) dampening, but a correlation of computed against experimental G.sup. with B3LYP+D3BJ, which are used to design new catalyst scaffolds.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted -olefin monomer and an amino-olefin monomer of formula H.sub.2CCH(CH.sub.2).sub.n(CHR).sub.mNR.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.

A method for forming polar-functionalized polyolefins may comprise contacting an unsubstituted -olefin monomer and an amino-olefin monomer of formula H.sub.2CCH(CH.sub.2).sub.n(CHR).sub.mNR.sub.2, wherein R is H or an unsubstituted linear or branched alkyl group having from 1 to 10 carbons, each R is an independently selected unsubstituted linear or branched alkyl group having from 1 to 10 carbons, m is an integer from 1 to 11, and n is an integer from 1 to 11, in the presence of a rare earth catalyst and a cocatalyst under conditions to induce a heteropolymerization reaction between the unsubstituted oc-olefin and amino-olefin monomers to provide a polar-functionalized poly olefin.