C08F4/629

SOLID CATALYST COMPONENT FOR POLYMERIZATION OF OLEFIN AND METHOD FOR PRODUCING THE SAME, CATALYST FOR POLYMERIZATION OF OLEFIN AND METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING POLYMER OF OLEFIN
20230159671 · 2023-05-25 · ·

The present invention provides a solid catalyst component for polymerization of an olefin, which appropriately suppresses a decrease in polymerization activity per unit time when having been supplied to the polymerization of the olefin, even without using a phthalic acid ester, and can easily prepare a polymer of an olefin, in which drying efficiency is improved, and a content ratio of a remaining volatile organic compound is greatly reduced in a short period of time. The solid catalyst component for polymerization of an olefin includes magnesium, titanium, halogen and a 1,3-diether compound, wherein a ratio of the 1,3-diether compound contained in the solid catalyst component for polymerization of an olefin is 2.50 to 15.00% by mass, and a specific surface area of the solid catalyst component for polymerization of an olefin is 250 m.sup.2/g or larger.

OLEFIN POLYMERIZATION CATALYST CARRIER, SOLID CATALYST COMPONENT AND USE THEREOF

Provided is an olefin polymerization catalyst carrier with a general structure formula of Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, wherein: 0≦n≦2, and R.sup.I and R.sup.II can be the same or different and are each independently selected from a C.sub.1-C.sub.20 hydrocarbon group. In the X-ray diffraction pattern of the catalyst carrier, there are a set of diffraction peaks in the range of a 2θ diffraction angle of 5°-15°, and the set of diffraction peaks contain 1-4 main diffraction peaks. Also disclosed is an olefin polymerization solid catalyst component which is prepared from the carrier Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, a titanium compound, and at least one electron donor compound. In addition, also disclosed is an olefin polymerization catalyst containing the solid catalyst component, at least one organic aluminum compound, and optionally, an external electron donor compound.

Olefin polymerization catalyst carrier, solid catalyst component and use thereof

A method of making an olefin polymerization catalyst carrier with a general structure formula of Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, wherein: 0≤n≤2, and R.sup.I and R.sup.II can be the same or different and are each independently selected from a C.sub.1-C.sub.20 hydrocarbon group by reacting an alcohol with a metal magnesium powder under the protection of nitrogen in the presence of a halogen or a halogen-containing compound to obtain a first product, and subjecting the product to a treatment pressure of from 0.2 to 5.0 MPa at a treatment temperature of from 80 to 200° C. for a duration of between 2 minutes and 6 hours. Also provided is a method of making an olefin polymerization solid catalyst component which includes the catalyst carrier, a titanium compound, and at least one electron donor compound.

OLEFIN POLYMERIZATION CATALYST CARRIER, SOLID CATALYST COMPONENT AND USE THEREOF

A method of making an olefin polymerization catalyst carrier with a general structure formula of Mg(OR.sup.I).sub.n(OR.sup.II).sub.2-n, wherein: 0n2, and R.sup.I and R.sup.II can be the same or different and are each independently selected from a C.sub.1-C.sub.20 hydrocarbon group by reacting an alcohol with a metal magnesium powder under the protection of nitrogen in the presence of a halogen or a halogen-containing compound to obtain a first product, and subjecting the product to a treatment pressure of from 0.2 to 5.0 MPa at a treatment temperature of from 80 to 200 C. for a duration of between 2 minutes and 6 hours. Also provided is a method of making an olefin polymerization solid catalyst component which includes the catalyst carrier, a titanium compound, and at least one electron donor compound.

Method for preparing a solution of a rare-earth alkyl phosphate

Disclosed is a method of preparing a rare-earth alkyl phosphate solution, the method including step (a) of preparing an alkyl phosphate amine salt solution by reacting an organic amine with an alkyl phosphate in a first solvent; step (b) of preparing a rare-earth metal salt solution by reacting a rare-earth metal oxide with an acid in the second solvent; and step (c) of mixing and reacting the alkyl phosphate amine salt solution with the rare-earth metal salt solution.

METHOD FOR PREPARING A SOLUTION OF A RARE-EARTH ALKYL PHOSPHATE
20180134818 · 2018-05-17 ·

Disclosed is a method of preparing a rare-earth alkyl phosphate solution, the method including step (a) of preparing an alkyl phosphate amine salt solution by reacting an organic amine with an alkyl phosphate in a first solvent; step (b) of preparing a rare-earth metal salt solution by reacting a rare-earth metal oxide with an acid in the second solvent; and step (c) of mixing and reacting the alkyl phosphate amine salt solution with the rare-earth metal salt solution.