Patent classifications
C08F4/72
Conjugated diene polymer and method for producing same
Conjugated diene polymer comprising at least a conjugated diene monomer unit, the conjugated diene polymer has a number-average molecular weight (Mn) in terms of polystyrene of 1,000 to 1,000,000, a ratio (Mw/Mn) of a weight-average molecular weight (Mw) to the number-average molecular weight (Mn) of lower than 2.0 and the polymer bears a halogen atom at a terminal of the polymer chain. Method for producing the conjugated diene polymer comprises subjecting a monomer containing at least a conjugated diene to living radical polymerization using a polymerization initiator comprising a halogenocyclopentadienyl triorganophosphine η.sup.2-olefin ruthenium complex represented by formula (6) (and an organic halide. ##STR00001##
Organic tellurium compound, method for producing same, living radical polymerization initiator, method for producing vinyl polymer, and vinyl polymer
An organic tellurium compound is disclosed having a versatility that, when used as a living radical polymerization initiator, it is applicable to polymerization of a vinyl monomer in an aqueous vehicle without using any surfactant or dispersant. The organic tellurium compound is represented by a general formula (1), ##STR00001##
where R.sup.1 and R.sup.2 each independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, A represents an alkali metal atom or an alkaline earth metal atom, x=1 when A is monovalent, x=½ when A is divalent, and R.sup.3 is represented by a general formula (2), ##STR00002##
where in the general formula (2) R.sup.4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R.sup.5 and R.sup.6 each independently represent an alkylene group having 2 to 8 carbon atoms, and a represents an integer from 0 to 10.
PERHYDROPOLYSILAZANE COMPOSITIONS AND METHODS FOR FORMING NITRIDE FILMS USING SAME
A Si-containing film forming composition comprising a catalyst and/or a polysilane and a N—H free, C-free, and Si-rich perhydropolysilazane having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton and comprising N—H free repeating units having the formula [—N(SiH.sub.3)×(SiH.sub.2−).sub.y], wherein x=0, 1, or 2 and y=0, 1, or 2 with x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 with x+y=3. Also disclosed are synthesis methods and applications for using the same.
PERHYDROPOLYSILAZANE COMPOSITIONS AND METHODS FOR FORMING NITRIDE FILMS USING SAME
A Si-containing film forming composition comprising a catalyst and/or a polysilane and a N—H free, C-free, and Si-rich perhydropolysilazane having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton and comprising N—H free repeating units having the formula [—N(SiH.sub.3)×(SiH.sub.2−).sub.y], wherein x=0, 1, or 2 and y=0, 1, or 2 with x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 with x+y=3. Also disclosed are synthesis methods and applications for using the same.
Acyl germanium photoinitiators and process for the preparation thereof
Acyl germanium compound according to general formula [R.sub.mAr(CO)].sub.4Ge and process for the preparation thereof. The compound is suitable as initiator for radical polymerization.
Acyl germanium photoinitiators and process for the preparation thereof
Acyl germanium compound according to general formula [R.sub.mAr(CO)].sub.4Ge and process for the preparation thereof. The compound is suitable as initiator for radical polymerization.
Acyl Germanium Photoinitiators And Process For The Preparation Thereof
Acyl germanium compound according to general formula [R.sub.mAr(CO)].sub.4Ge and process for the preparation thereof. The compound is suitable as initiator for radical polymerization.
Acyl Germanium Photoinitiators And Process For The Preparation Thereof
Acyl germanium compound according to general formula [R.sub.mAr(CO)].sub.4Ge and process for the preparation thereof. The compound is suitable as initiator for radical polymerization.
ORGANIC TELLURIUM COMPOUND, METHOD FOR PRODUCING SAME, LIVING RADICAL POLYMERIZATION INITIATOR, METHOD FOR PRODUCING VINYL POLYMER, AND VINYL POLYMER
An organic tellurium compound is disclosed having a versatility that, when used as a living radical polymerization initiator, it is applicable to polymerization of a vinyl monomer in an aqueous vehicle without using any surfactant or dispersant. The organic tellurium compound is represented by a general formula (1),
##STR00001##
where R.sup.1 and R.sup.2 each independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, A represents an alkali metal atom or an alkaline earth metal atom, x=1 when A is monovalent, x= when A is divalent, and R.sup.3 is represented by a general formula (2),
##STR00002##
where in the general formula (2) R.sup.4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R.sup.5 and R.sup.6 each independently represent an alkylene group having 2 to 8 carbon atoms, and a represents an integer from 0 to 10.
POLARIZING FILM ADHESIVE COMPOSITION, MANUFACTURING METHOD OF POLARIZING FILM ADHESIVE LAYER, POLARIZING FILM WITH ADHESIVE LAYER, AND IMAGE DISPLAY DEVICE
The purpose of the present invention is to provide a pressure-sensitive adhesive composition for a polarizing film from which a pressure-sensitive adhesive layer for a polarizing film can be obtained which can suppress separator peeling strength and can specifically suppress increases in separator peeling strength even when stored for a long period of time after production, and further has excellent durability (heat resistance) even when exposed to high temperature heating conditions and heating/humidifying conditions; and to provide a method for a pressure-sensitive adhesive layer for a polarizing film, the pressure-sensitive adhesive layer attached polarizing film polarizing film which includes the pressure-sensitive adhesive layer, and an image display device that includes the pressure-sensitive adhesive layer attached polarizing film. A pressure-sensitive adhesive composition for a polarizing film, which contains an organic tellurium compound, a (meth)acrylic polymer (A), and a compound (B) that generates radicals by heat or active energy rays.