A process comprising polymerizing olefin monomers and optionally comonomers in a first reactor vessel, thereby forming a raw product stream comprising polymerized solids, unreacted monomer and optionally comonomer, the polymerized solids comprising olefin polymer, volatile organic compounds (VOC) and catalyst system. Then the polymerized solids are contacted with a catalyst poison selected from carbon monoxide, carbon dioxide, oxygen, water, alcohols, amines, or mixtures thereof, thereby forming a passivated stream. The passivated stream is maintained in an agitated state within a second reactor. The passivated stream within the second reactor is then contacted with a circulating gas comprising unreacted monomer for a residence time, thereby reducing the concentration of VOC in the polymerized solids by at least 10 wt % compared to the level before entering the second reactor, thereby forming a purified olefin polymer solids stream.

A process comprising polymerizing olefin monomers and optionally comonomers in a first reactor vessel, thereby forming a raw product stream comprising polymerized solids, unreacted monomer and optionally comonomer, the polymerized solids comprising olefin polymer, volatile organic compounds (VOC) and catalyst system. Then the polymerized solids are contacted with a catalyst poison selected from carbon monoxide, carbon dioxide, oxygen, water, alcohols, amines, or mixtures thereof, thereby forming a passivated stream. The passivated stream is maintained in an agitated state within a second reactor. The passivated stream within the second reactor is then contacted with a circulating gas comprising unreacted monomer for a residence time, thereby reducing the concentration of VOC in the polymerized solids by at least 10 wt % compared to the level before entering the second reactor, thereby forming a purified olefin polymer solids stream.

This disclosure describes polymerization processes and processes for quenching polymerization reactions using reactive particulates, such as amorphous silica, as quenching agents, typically in solution or bulk polymerization processes.

This disclosure describes polymerization processes and processes for quenching polymerization reactions using reactive particulates, such as amorphous silica, as quenching agents, typically in solution or bulk polymerization processes.

Methods for processing LLDPE recyclates including, but not limited to, polyethylene and polypropylene and compositions therefrom are provided. LLDPE recyclate can be visbroken to improve processing characteristics and/or devolatilized to remove waste byproducts to produce processed LLDPE recyclates. Processed LLDPE recyclates are compounded with pre-consumer polyolefins to produce blend compositions having acceptable or even improved processing characteristics. Such pre-consumer polyolefins can also be visbroken to further tailor processing characteristics of such polymer blends. A combination of extruders and/or extruder zones can be used at the same or different locations for visbreaking and/or compounding of both LLDPE recyclate and/or pre-consumer polyolefins.

Methods for processing LLDPE recyclates including, but not limited to, polyethylene and polypropylene and compositions therefrom are provided. LLDPE recyclate can be visbroken to improve processing characteristics and/or devolatilized to remove waste byproducts to produce processed LLDPE recyclates. Processed LLDPE recyclates are compounded with pre-consumer polyolefins to produce blend compositions having acceptable or even improved processing characteristics. Such pre-consumer polyolefins can also be visbroken to further tailor processing characteristics of such polymer blends. A combination of extruders and/or extruder zones can be used at the same or different locations for visbreaking and/or compounding of both LLDPE recyclate and/or pre-consumer polyolefins.

Methods for processing polyolefin recyclates including, but not limited to, polyethylene and polypropylene and compositions therefrom are provided. polyolefin recyclate feedstocks can be visbroken to improve processing characteristics and/or devolatilized to remove waste byproducts to produce processed polyolefin recyclates. Processed polyolefin recyclates are compounded with pre-consumer polyolefins to produce blend compositions having acceptable or even improved processing characteristics. Such pre-consumer polyolefins can also be visbroken to further tailor processing characteristics of such polymer blends. A combination of extruders and/or extruder zones can be used at the same or different locations for visbreaking and/or compounding of both polyolefin recyclate and/or pre-consumer polyolefins.

Provided is a new method that effectively reduces odor components that are present in a hydrogenated petroleum resin, and adjusts a softening point to an appropriate range for exhibiting an adhesive performance. A method for deodorizing a hydrogenated petroleum resin, includes stripping a hydrogenated petroleum resin at a gas flow rate of 1 to 45 VVM.

Provided is a new method that effectively reduces odor components that are present in a hydrogenated petroleum resin, and adjusts a softening point to an appropriate range for exhibiting an adhesive performance. A method for deodorizing a hydrogenated petroleum resin, includes stripping a hydrogenated petroleum resin at a gas flow rate of 1 to 45 VVM.

Disclosed herein is a system for solution polymerization comprising a reactor system that is operative to receive a monomer and to react the monomer to form a polymer; a plurality of devolatilization vessels located downstream of the reactor system, where each devolatilization vessel operates at a lower pressure than the preceding devolatilization vessel; and a heat exchanger disposed between two devolatilization vessels and in fluid communication with them, where the heat exchanger has an inlet port temperature of 100° C. to 230° C., an outlet port temperature of 200° C. to 300° C., an inlet port pressure of 35 to 250 kgf/cm.sup.2 and an outlet port pressure of 20 to 200 kgf/cm.sup.2; and wherein the polymer solution remains in a single phase during its residence in the heat exchanger.