A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders.

A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders.

Disclosed is a method of preparing a graft copolymer and a method of preparing a thermoplastic resin composition including the prepared graft copolymer. Also disclosed is a method of preparing a graft copolymer including a process of adding an aromatic vinyl monomer and a vinyl cyanide monomer to a conjugated diene rubber latex that is enlarged with a polymer particle diameter control agent that has a specific glass transition temperature and an average particle diameter in a specific ratio to an average particle diameter of a conjugated diene rubber latex, and graft-polymerizing the same; and a method of preparing a thermoplastic resin composition including the prepared graft copolymer.

Also disclosed is a graft copolymer prepared using the conjugated diene rubber latex enlarged with the polymer particle diameter control agent exhibiting the synergistic effect of improving both impact strength and fluidity.

Disclosed is a method of preparing a graft copolymer and a method of preparing a thermoplastic resin composition including the prepared graft copolymer. Also disclosed is a method of preparing a graft copolymer including a process of adding an aromatic vinyl monomer and a vinyl cyanide monomer to a conjugated diene rubber latex that is enlarged with a polymer particle diameter control agent that has a specific glass transition temperature and an average particle diameter in a specific ratio to an average particle diameter of a conjugated diene rubber latex, and graft-polymerizing the same; and a method of preparing a thermoplastic resin composition including the prepared graft copolymer.

Also disclosed is a graft copolymer prepared using the conjugated diene rubber latex enlarged with the polymer particle diameter control agent exhibiting the synergistic effect of improving both impact strength and fluidity.

Disclosed is a method of preparing a graft copolymer and a method of preparing a thermoplastic resin composition including the prepared graft copolymer. Also disclosed is a method of preparing a graft copolymer including a process of adding an aromatic vinyl monomer and a vinyl cyanide monomer to a conjugated diene rubber latex that is enlarged with a polymer particle diameter control agent that has a specific glass transition temperature and an average particle diameter in a specific ratio to an average particle diameter of a conjugated diene rubber latex, and graft-polymerizing the same; and a method of preparing a thermoplastic resin composition including the prepared graft copolymer.

Also disclosed is a graft copolymer prepared using the conjugated diene rubber latex enlarged with the polymer particle diameter control agent exhibiting the synergistic effect of improving both impact strength and fluidity.

Disclosed is a method of preparing a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer, a method of preparing a thermoplastic resin composition including the same, and a thermoplastic resin composition including the same. More specifically, when a conjugated diene compound and a molecular weight regulator are fed in a split manner during polymerization of conjugated diene rubber, and the content of an emulsifier is reduced, gel content may be reduced. In addition, when enlarged conjugated diene-based rubber latex is prepared by enlarging conjugated diene-based rubber latex using an acid enlarging agent, the enlarged conjugated diene-based rubber latex may have an expanded full width at half maximum in particle size distribution, thereby improving gloss, reflection haze, fluidity, and impact resistance. In addition, deposits may be reduced during injection molding.

Disclosed is a method of preparing a vinyl cyanide compound-conjugated diene rubber-aromatic vinyl compound graft copolymer, a method of preparing a thermoplastic resin composition including the same, and a thermoplastic resin composition including the same. More specifically, when a conjugated diene compound and a molecular weight regulator are fed in a split manner during polymerization of conjugated diene rubber, and the content of an emulsifier is reduced, gel content may be reduced. In addition, when enlarged conjugated diene-based rubber latex is prepared by enlarging conjugated diene-based rubber latex using an acid enlarging agent, the enlarged conjugated diene-based rubber latex may have an expanded full width at half maximum in particle size distribution, thereby improving gloss, reflection haze, fluidity, and impact resistance. In addition, deposits may be reduced during injection molding.

According to an embodiment of the present invention, provided is a process for polymerizing molecular weight—adjustable polymer, comprising: a reactant supply step of supplying a gaseous monomer, a surfactant, and an initiator; a polymerization reaction step of performing a polymerization reaction in which the monomer, the surfactant, and the initiator participate; and a product discharging step of discharging the polymer compound produced by the polymerization reaction, wherein the flow rate of the supplied initiator is inversely proportional to the molecular weight of the polymer compound, and the molecular weight of the polymer compound produced by the polymerization reaction is adjusted by controlling the flow rate of the initiator.

The present disclosure relates to a method for preparing a graft copolymer, a graft copolymer prepared therefrom, and a resin composition including the same. The method includes introducing a polymer coagulant latex including a polymer coagulant to a rubbery polymer latex including a rubbery polymer and coagulating the polymer coagulant latex to prepare an enlarged rubbery polymer latex containing an enlarged rubbery polymer, and introducing an aromatic vinyl-based monomer and a vinyl cyan-based monomer to the prepared enlarged rubbery polymer latex and performing graft polymerization to prepare a graft copolymer latex including a graft copolymer. The polymer coagulant includes an acid group-containing copolymer having a weight average molecular weight of 550,000 g/mol to 750,000 g/mol, and the content of the vinyl cyan-based monomer is 15 wt % to 24 wt % based on the total content of the aromatic vinyl-based monomer and the vinyl cyan-based monomer.

The present disclosure relates to a method for preparing a graft copolymer, a graft copolymer prepared therefrom, and a resin composition including the same. The method includes introducing a polymer coagulant latex including a polymer coagulant to a rubbery polymer latex including a rubbery polymer and coagulating the polymer coagulant latex to prepare an enlarged rubbery polymer latex containing an enlarged rubbery polymer, and introducing an aromatic vinyl-based monomer and a vinyl cyan-based monomer to the prepared enlarged rubbery polymer latex and performing graft polymerization to prepare a graft copolymer latex including a graft copolymer. The polymer coagulant includes an acid group-containing copolymer having a weight average molecular weight of 550,000 g/mol to 750,000 g/mol, and the content of the vinyl cyan-based monomer is 15 wt % to 24 wt % based on the total content of the aromatic vinyl-based monomer and the vinyl cyan-based monomer.